Organic light-emitting element

1. An organic light-emitting element comprising:

an anode;

a cathode; and

an organic compound layer placed between the anode and the cathode,

wherein the organic compound layer includes an iridium complex represented by the following general formula [1] and a metal complex represented by the following general formula [9]:

Ir(L 1 )(L 2 )(L 3 )  [1]

in the formula [1], a partial structure IrL 1 comprises a partial structure represented by the following general formula [2]:

in the formula [2]:

a ring A 1 represents an aromatic ring or an aromatic heterocycle, and the aromatic ring and aromatic heterocycle each represented by the ring A 1 may each further have a substituent selected from an alkyl group having 1 or more and 4 or less carbon atoms, an aralkyl group, an aryl group, a heterocyclic group, a substituted amino group, an alkoxy group, an aryloxy group, a halogen atom, and a cyano group; and

R 1 to R 8 each represent a hydrogen atom, an alkyl group having 1 or more and 4 or less carbon atoms, an aralkyl group, an aryl group, a heterocyclic group, a substituted amino group, an alkoxy group, an aryloxy group, a halogen atom, or a cyano group, and may be identical to or different from one another, and when any one of substituents represented by the R 1 to R 8 is an alkyl group having 1 or more and 4 or less carbon atoms, an aralkyl group, an aryl group, a heterocyclic group, a substituted amino group, an alkoxy group, or an aryloxy group, the substituent may further have any substituent selected from an alkyl group having 1 or more and 4 or less carbon atoms, an aralkyl group, an aryl group, a heterocyclic group, a substituted amino group, an alkoxy group, an aryloxy group, a halogen atom, and a cyano group;

in the formula [1], a partial structure IrL 2 comprises a partial structure represented by the following general formula [3]:

in the formula [3]:

a ring A 2 represents an aromatic ring or an aromatic heterocycle, and the aromatic ring and aromatic heterocycle each represented by the ring A 2 may each further have any substituent selected from an alkyl group having 1 or more and 4 or less carbon atoms, an aralkyl group, an aryl group, a heterocyclic group, a substituted amino group, an alkoxy group, an aryloxy group, a halogen atom, and a cyano group; and

a ring B represents a nitrogen-containing aromatic heterocycle, and the nitrogen-containing aromatic heterocycle represented by the ring B may further have any substituent selected from an alkyl group having 1 or more and 4 or less carbon atoms, an aralkyl group, an aryl group, a heterocyclic group, a substituted amino group, an alkoxy group, an aryloxy group, a halogen atom, and a cyano group;

L 1 and L 2 represent ligands that are different from each other and are not identical to each other;

in the formula [1], L 3 represents a monovalent bidentate ligand having an atom that forms a covalent bond with iridium and is selected from N, O, S, and P, and an atom that forms a coordinate bond with iridium and is selected from N, O, S, and P, and the atom that forms the covalent bond with iridium and the atom that forms the coordinate bond with iridium may be identical to or different from each other;

MLL′  [9]

in the formula [9], M represents a divalent metal atom selected from Zn, Be, Mg, Ca, Co, and Ni, L and L′ each represent a bidentate ligand, and L and L′ may be identical to or different from each other, and ML and ML′ each represent any one of partial structures represented by the following general formulae [10] to [15]:

in the formulae [10] to [15], R 30 to R 57 each represent a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, an alkoxy group, a substituted amino group, a substituted or unsubstituted aromatic hydrocarbon group, or a substituted or unsubstituted heteroaromatic group;

in the formulae [12] to [15]:

a ring B comprises any one of cyclic structures represented by the following general formulae [16] to [18]; and

*1 represents a bonding position with an oxygen atom and *2 represents a bonding position with a carbon atom in a five-membered heterocyclic skeleton:

in the formulae [16] to [18], R 60 to R 73 each represent a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, an alkoxy group, a substituted amino group, a substituted or unsubstituted aromatic hydrocarbon group, or a substituted or unsubstituted heteroaromatic group.

2. The organic light-emitting element according to claim 1 , wherein the ring A 1 is a benzene ring, a naphthalene ring, a fluorene ring, a phenanthrene ring, a carbazole ring, a dibenzofuran ring, or a dibenzothiophene ring; and

the ring A 1 may further have any substituent selected from an alkyl group having 1 or more and 4 or less carbon atoms, an aralkyl group, an aryl group, a heterocyclic group, a substituted amino group, an alkoxy group, an aryloxy group, a halogen atom, and a cyano group.

3. The organic light-emitting element according to claim 1 , wherein the partial structure represented by the general formula [2] comprises a partial structure represented by the following general formula [4]:

in the general formula [4]:

a ring A 3 is a benzene ring, a naphthalene ring, a fluorene ring, a phenanthrene ring, a carbazole ring, a dibenzofuran ring, or a dibenzothiophene ring, and the ring A 3 may further have any substituent selected from an alkyl group having 1 or more and 4 or less carbon atoms, an aralkyl group, an aryl group, a heterocyclic group, a substituted amino group, an alkoxy group, an aryloxy group, a halogen atom, and a cyano group; and

R 9 to R 12 each represent a hydrogen atom, an alkyl group having 1 or more and 4 or less carbon atoms, or a phenyl group, and when any one of substituents represented by R 9 to R 12 is an alkyl group having 1 or more and 4 or less carbon atoms, or a phenyl group, the substituent may further have any substituent selected from an alkyl group having 1 or more and 4 or less carbon atoms, an aralkyl group, an aryl group, a heterocyclic group, a substituted amino group, an alkoxy group, an aryloxy group, a halogen atom, and a cyano group, and R 9 to R 12 may be identical to or different from one another.

4. The organic light-emitting element according claim 1 , wherein the ring A 2 is a benzene ring, a naphthalene ring, a fluorene ring, a phenanthrene ring, a carbazole ring, a dibenzofuran ring, or a dibenzothiophene ring;

the ring A 2 may further have any substituent selected from an alkyl group having 1 or more and 4 or less carbon atoms, an aralkyl group, an aryl group, a heterocyclic group, a substituted amino group, an alkoxy group, an aryloxy group, a halogen atom, and a cyano group;

the ring B is a pyridine ring, a quinoline ring, an isoquinoline ring, a benzo[f]quinoline ring, a benzo[h]quinoline ring, a benzo[f]isoquinoline ring, a benzo[h]isoquinoline ring, an oxazole ring, a benzo[d]oxazole ring, a benzo[d]thiazole ring, or an imidazole ring; and

the ring B may further have any substituent selected from an alkyl group having 1 or more and 4 or less carbon atoms, an aralkyl group, an aryl group, a heterocyclic group, a substituted amino group, an alkoxy group, an aryloxy group, a halogen atom, and a cyano group.

5. The organic light-emitting element according to claim 1 , wherein the partial structure represented by the general formula [3] comprises a partial structure represented by the following general formula [5]:

in the formula [5], R 13 to R 20 each represent a hydrogen atom, an alkyl group having 1 or more and 4 or less carbon atoms, an aralkyl group, an aryl group, a heterocyclic group, a substituted amino group, an alkoxy group, an aryloxy group, a halogen atom, or a cyano group, and may be identical to or different from one another, and when any one of substituents represented by R 13 to R 20 is an alkyl group having 1 or more and 4 or less carbon atoms, an aralkyl group, an aryl group, a heterocyclic group, a substituted amino group, an alkoxy group, or an aryloxy group, the substituent may further have any substituent selected from an alkyl group having 1 or more and 4 or less carbon atoms, an aralkyl group, an aryl group, a heterocyclic group, a substituted amino group, an alkoxy group, an aryloxy group, a halogen atom, and a cyano group.

6. The organic light-emitting element according to claim 5 , wherein the R 13 to R 20 each represent a hydrogen atom, an alkyl group having 1 or more and 4 or less carbon atoms, or a phenyl group; and

the R 13 to R 20 may be identical to or different from one another, and when any one of the substituents represented by the R 13 to R 20 is an alkyl group having 1 or more and 4 or less carbon atoms, or a phenyl group, the substituent may further have any substituent selected from an alkyl group having 1 or more and 4 or less carbon atoms, an aralkyl group, an aryl group, a heterocyclic group, a substituted amino group, an alkoxy group, an aryloxy group, a halogen atom, and a cyano group.

7. The organic light-emitting element according claim 1 , wherein in the general formula [1], a partial structure IrL 3 comprises a partial structure represented by the following general formula [6]:

in the formula [6], R 21 to R 23 each represent a hydrogen atom, an alkyl group having 1 or more and 4 or less carbon atoms, an aralkyl group, an aryl group, a heterocyclic group, a substituted amino group, an alkoxy group, an aryloxy group, a halogen atom, or a cyano group, and may be identical to or different from one another, and when any one of substituents represented by R 21 to R 23 is an alkyl group having 1 or more and 4 or less carbon atoms, an aralkyl group, an aryl group, a heterocyclic group, a substituted amino group, an alkoxy group, or an aryloxy group, the substituent may further have any substituent selected from an alkyl group having 1 or more and 4 or less carbon atoms, an aralkyl group, an aryl group, a heterocyclic group, a substituted amino group, an alkoxy group, an aryloxy group, a halogen atom, and a cyano group.

8. The organic light-emitting element according to claim 7 , wherein the R 21 to R 23 each represent a hydrogen atom or an alkyl group having 1 or more and 4 or less carbon atoms; and

when any one of the substituents represented by the R 21 to R 23 is an alkyl group having 1 or more and 4 or less carbon atoms, the substituent may further have any substituent selected from an alkyl group having 1 or more and 4 or less carbon atoms, an aralkyl group, an aryl group, a heterocyclic group, a substituted amino group, an alkoxy group, an aryloxy group, a halogen atom, and a cyano group.

9. A display apparatus comprising multiple pixels, wherein the pixels each have the organic light-emitting element according claim 1 and an active element connected to the organic light-emitting element.

10. The display apparatus according to claim 9 , wherein an electrode of the active element is formed of a transparent oxide semiconductor.

11. The display apparatus according to claim 9 , further comprising a color filter.

12. A display apparatus, which is formed by laminating the organic light-emitting element according to claim 1 to thereby output white light as a whole.

13. A lighting apparatus comprising:

the organic light-emitting element according to claim 1 ; and

an inverter circuit connected to the organic light-emitting element.