IP Library Granted Patent US 9,944,853
Granted Patent B2
US 9,944,853 · App. 14/760,489 · Granted Apr 17, 2018

Color inhibitor for quaternary ammonium hydroxide in non-aqueous solvent

Inventors: Tim Engel (DR Tilburg Noord-brabant, NL); Alfred Van Lier (Zaltbommel, NL)
Assignee: SACHEM, Inc.
C09K15/22C07C209/90C07C211/62C07C211/63C07C211/64C07C213/10C07C215/40C07C215/72C07C215/90
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Quick Facts
Patent No.
US 9,944,853
App. No.
14/760,489
Granted
Apr 17, 2018
Kind
B2
Abstract

A composition including a quaternary onium hydroxide in a non-aqueous solvent, wherein the quaternary ammonium hydroxide has a concentration in the range from about 5% by weight to about 50% by weight of the composition; and imidazolidine-2,4-dione, wherein the imidazolidine-2,4-dione has a concentration in the range from about 10 to about 5000 parts per million of the composition.

Claims (9)

1. A composition comprising:

a quaternary onium hydroxide in a non-aqueous solvent, wherein the quaternary onium hydroxide has a concentration in the range from about 20% by weight to about 50% by weight of the composition;

imidazolidine-2,4-dione, wherein the imidazolidine-2,4-dione has a concentration in the range from about 10 to about 5000 parts per million of the composition, and

a water content of less than 0.5% by weight of the composition by Karl Fischer titration.

2. The composition of claim 1 wherein the quaternary onium hydroxide comprises an onium ion having a general formula (II):

wherein in formula (II), A is a nitrogen or phosphorus atom, R 1 , R 2 , R 3 and R 4 are each independently a branched or unbranched alkyl group containing from 1 to about 20 carbon atoms, a branched or unbranched hydroxyalkyl or an alkoxyalkyl group containing from 1 to about 20 carbon atoms, substituted or unsubstituted aryl groups or hydroxyaryl groups containing from 6 to 18 ring carbon atoms, when substituted, said substitution comprises one or more substituent selected from any of the foregoing alkyl, hydroxyalkyl or alkoxyalkyl groups, or R 1 and R 2 or R 3 together with A may form a heterocyclic group provided that if the heterocyclic group contains a C=A group, R 3 is the second bond.

3. The composition of claim 2 wherein the quaternary onium hydroxide in formula (II) is a quaternary ammonium hydroxide.

4. The composition of claim 2 wherein at least one of the alkyl groups in formula (II) contains 3 or more carbon atoms.

5. The composition of claim 1 wherein the non-aqueous solvent comprises one or more selected from propylene glycol (PG), butylene glycol (BG), ethylene glycol (EG), triethylene glycol (TEG), formamide (FA), and glycerol (GLY).

Assignments (4)
SECURITY INTEREST Recorded Aug 4, 2026
From: SACHEM, INC.
To: FIRST BUSINESS SPECIALTY FINANCE, LLC
Reel/Frame 075521/0429 →
RELEASE OF SECURITY INTEREST Recorded Jun 10, 2025
From: PNC BANK, NATIONAL ASSOCIATION
To: SACHEM, INC.; SACHEM ASIA, INC.
Reel/Frame 071368/0642 →
SECURITY INTEREST Recorded May 6, 2024
From: SACHEM, INC.; SACHEM ASIA, INC.
To: PNC BANK, NATIONAL ASSOCIATION
Reel/Frame 067318/0340 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 6, 2015
From: ENGEL, TIM; VAN LIER, ALFRED
To: SACHEM, INC.
Reel/Frame 036977/0005 →
Continuity (2)
Provisional Application 61751429 · Jan 11, 2013
Related Publication 20150353824A1 · Dec 10, 2015