Polyhydroxy curable fluoroelastomer composition
View Patent ↗The invention disclosed herein is a curable fluoroelastomer composition comprising i) a fluoroelastomer, ii) a polyhydroxy curative and iii) a mixture of anion trappers comprising γ-aluminum oxide hydroxide and magnesium oxide. Cured articles made therefrom are resistant to volume swell in carboxylic acids.
1. A curable fluoroelastomer composition comprising:
A) a polyhydroxy curable fluoroelastomer;
B) a polyhydroxy curative; and
C) a mixture of anion trappers comprising γ-aluminum oxide hydroxide and magnesium oxide.
2. The curable fluoroelastomer composition of claim 1 wherein said polyhydroxy curable fluoroelastomer is selected from the group consisting of copolymers of i) vinylidene fluoride with hexafluoropropylene and, optionally, tetrafluoroethylene; ii) vinylidene fluoride with a perfluoro(alkyl vinyl ether), 2-hydropentafluoropropylene and optionally, tetrafluoroethylene; iii) tetrafluoroethylene with propylene and 3,3,3-trifluoropropene; iv) tetrafluoroethylene, perfluoro(methyl vinyl ether) and hexafluoro-2-(pentafluorophenoxy)-1-(trifluorovinyloxy) propane, and v) ethylene with tetrafluoroethylene, perfluoro(methyl vinyl ether) and 3,3,3-trifluoropropylene.
3. The curable fluoroelastomer composition of claim 1 wherein said mixture of anion trappers is present in an amount between 1 and 25 parts by weight per hundred parts by weight fluoroelastomer.
4. The curable fluoroelastomer composition of claim 3 wherein said mixture of anion trappers comprises 0.75 to 20 parts by weight γ-aluminum oxide hydroxide, per hundred parts by weight fluoroelastomer.
5. A polyhydroxy cured fluoroelastomer article comprising:
A) a fluoroelastomer; and
B) a mixture of anion trappers comprising y-aluminum oxide hydroxide and magnesium oxide.
6. The polyhydroxy cured fluoroelastomer article of claim 5 wherein said mixture of anion trappers is present in an amount between 1 and 25 parts by weight per hundred parts by weight fluoroelastomer.
7. The polyhydroxy cured fluoroelastomer article of claim 6 wherein said mixture of anion trappers comprises 0.75 to 20 parts by weight γ-aluminum oxide hydroxide, per hundred parts by weight fluoroelastomer.
8. The polyhydroxy cured fluoroelastomer article of claim 5 wherein said fluoroelastomer is selected from the group consisting of copolymers of i) vinylidene fluoride with hexafluoropropylene and, optionally, tetrafluoroethylene; ii) vinylidene fluoride with a perfluoro(alkyl vinyl ether), 2-hydropentafluoropropylene and optionally, tetrafluoroethylene; iii) tetrafluoroethylene with propylene and 3,3,3-trifluoropropene; iv) tetrafluoroethylene, perfluoro(methyl vinyl ether) and hexafluoro-2-(pentafluorophenoxy)-1-(trifluorovinyloxy) propane, and v) ethylene with tetrafluoroethylene, perfluoro(methyl vinyl ether) and 3,3,3-trifluoropropylene.
9. The polyhydroxy cured fluoroelastomer article of claim 5 wherein said article has a volume swell less than 10 vol % after exposure to an acid condensate of sulfuric acid/nitric acid/acetic acid/formic acid in the ratio of 2500ppm/50ppm/10ppm/1000ppm/300ppm at 60° C. for 336 hours.