Method for recovering heavy rare earth element
View Patent ↗An object of the present invention is to provide a method for recovering a heavy rare earth element from a workpiece containing at least a heavy rare earth element and an iron group element, which can be put into practical use as a low-cost, simple recycling system. The method for recovering a heavy rare earth element from a workpiece containing at least a heavy rare earth element and an iron group element of the present invention as a means for resolution is characterized by including at least the following step: a workpiece is subjected to an oxidation treatment or mixed with an oxidation-treated R—Fe—B based magnet alloy, and then subjected to a heat treatment in the presence of carbon at a temperature of 1000° C. or more, thereby separating a heavy rare earth element in the form of an oxide from an iron group element.
1. A method for recovering a heavy rare earth element from a workpiece containing at least a heavy rare earth element and an iron group element, characterized by including at least the following step: a workpiece is subjected to an oxidation treatment such that as a result of the oxidation treatment the molar ratio of oxygen to the heavy rare earth element in the workpiece becomes 2.0 times or more, and then subjected to a heat treatment in the presence of carbon at a temperature of 1000° C. or more, thereby separating a heavy rare earth element in the form of an oxide from an iron group element.
2. A method according to claim 1 , characterized in that the heat treatment temperature is 1300° C. or more.
3. A method according to claim 2 , characterized in that the heat treatment of the oxidation-treated workpiece is performed using a carbon crucible as a treatment container and also as a carbon supply source.
4. A method according to claim 2 , characterized in that the heat treatment of the oxidation-treated workpiece is performed in the presence of carbon and boron.
5. A method according to claim 4 , characterized in that the heat treatment of the oxidation-treated workpiece is performed using boron oxide as a boron supply source.
6. A method according to claim 2 , characterized in that at least part of the workpiece is in granular or powder form having a particle size of 5 mm or less.
7. A method according to claim 2 , characterized in that the workpiece has an iron group element content of 30 mass % or more.
8. A method according to claim 2 , characterized in that the workpiece is a heavy rare earth element diffusion source made of an alloy of a heavy rare earth element and iron for diffusing a heavy rare earth element into an R—Fe—B based permanent magnet, the heavy rare earth element diffusion source having been used and thus further containing a component derived from the magnet.