Method of manufacturing secondary battery and secondary battery using the same
View Patent ↗Disclosed are a method of manufacturing a secondary battery having an electrode assembly sealed therein including: (a) sealing a battery case after introducing an electrode assembly having a structure, in which a separator is interposed between a positive electrode and a negative electrode, and an electrolyte thereinto; and (b) removing gases generated at an abnormal operation state of a battery or high temperature from an internal battery environment by pressing both sides of the battery case having the electrode assembly embedded therein in the sealing (a) to increase internal pressure of the battery case in the sealing, wherein the electrode assembly includes a spinel-structure lithium nickel manganese composite oxide as a positive electrode active material and a lithium metal oxide as a negative electrode active material.
1. A method of manufacturing a secondary battery having an electrode assembly sealed therein, the method comprising:
sealing a battery case composed of a rectangular or cylindrical metal can after introducing an electrode assembly having a structure, in which a separator is interposed between a positive electrode and a negative electrode, and an electrolyte thereinto; and
removing gases generated at an abnormal operation state of a battery or high temperature from an internal battery environment by pressing both sides of the battery case having the electrode assembly embedded therein in the sealing to increase internal pressure of the battery,
wherein the electrode assembly comprises a spinel-structure lithium nickel manganese composite oxide represented by Formula 1 below as a positive electrode active material and a lithium metal oxide represented by Formula 2 below as a negative electrode active material:
LixM y Mn 2−y O 4−z A z (1)
wherein 0.9≤x≤1.2, 0<y<2, and 0≤z<0.2,
M is at least one element selected from the group consisting of Al, Mg, Ni, Co, Fe, Cr, V, Ti, Cu, B, Ca, Zn, Zr, Nb, Mo, Sr, Sb, W, Ti, and Bi;
A is at least one monovalent or divalent anion;
Li a M′ b O 4−c A c (2)
wherein M′ is at least one element selected from the group consisting of Ti, Sn, Cu, Pb, Sb, Zn, Fe, In, Al and Zr;
0.1≤a≤4 and 0.2≤b≤4, wherein a and b are determined according to oxidation number of M′;
0≤c<0.2, wherein c is determined according to oxidation number of A; and
A is at least one monovalent or divalent anion,
wherein, in the removing, the pressing of the battery case is performed by pressing the both sides of the battery case using a compression plate.
2. The method according to claim 1 , wherein pressure applied in the removing is 2 atm to 10 atm.
3. The method according to claim 1 , wherein the pressure applied in the removing is 3 atm to 8 atm.
4. The method according to claim 1 , wherein the battery case can be used under a pressure of 10 atm.
5. The method according to claim 1 , wherein the gases are consumed by being reduced at a negative electrode through applied pressure.
6. The method according to claim 1 , wherein the oxide of Formula 1 is represented by Formula 3 below:
Li x Ni y Mn 2−y O 4 (3)
wherein 0.9≤x≤1.2 and 0.4≤y≤0.5.
7. The method according to claim 1 , wherein the oxide of Formula 1 is LiNi 0.5 Mn 1.5 O 4 or LiNi 0.4 Mn 1.6 O 4 .
8. The method according to claim 1 , wherein the oxide of Formula 2 is represented by Formula 4 below:
Li a Ti b O 4 (4)
wherein 0.5≤a≤3 and 1≤b≤2.5.
9. The method according to claim 1 , wherein the oxide of Formula 2 is Li 1.33 Ti 1.67 O 4 or LiTi 2 O 4 .