Method for producing base oil for lubricant oils
View Patent ↗A method for producing a base oil for lubricant oils comprising: a first step of hydrocracking a stock oil having a content percentage of a heavy matter of 80% by mass or more so that a crack per mass of the heavy matter is 20 to 85% by mass, to obtain a hydrocracked oil comprising the heavy matter and a hydrocracked product thereof, a second step of fractionating the hydrocracked oil into a base oil fraction comprising the hydrocracked product and a heavy fraction comprising the heavy matter and being heavier than the base oil fraction, respectively, a third step of isomerization dewaxing the base oil fraction from the fractionation in the second step to obtain a dewaxed oil, wherein the heavy fraction from the fractionation in the second step is returned to the first step as a part of the stock oil.
1. A method for producing a base oil for lubricant oils comprising:
a first step of hydrocracking, on a hydrocracking catalyst containing at least two metals selected from the group consisting of cobalt, molybdenum, nickel, and tungsten, a stock oil having a content percentage of sulfur of 0.001 to 3.0% by mass and a heavy matter having 30 or more carbon atoms of 80% by mass or more under a condition of a partial pressure of hydrogen of 5 to 20 MPa so that a crack per mass of the heavy matter is 20 to 85% by mass, to obtain a hydrocracked oil comprising the heavy matter and a hydrocracked product thereof,
a second step of fractionating the hydrocracked oil into a base oil fraction comprising the hydrocracked product and a heavy fraction comprising the heavy matter and being heavier than the base oil fraction,
a third step of isomerization dewaxing the base oil fraction from the fractionation in the second step to obtain a dewaxed oil,
wherein the heavy fraction from the fractionation in the second step is returned to the first step as a part of the stock oil;
wherein
the third step is a step of obtaining the dewaxed oil by allowing the base oil fraction to contact a hydroisomerization dewaxing catalyst,
the hydroisomerization dewaxing catalyst containing a carrier comprising zeolite having a 10-membered ring one dimensional pore structure and a binder, and platinum and/or palladium supported on the carrier, and having a carbon content of 0.4 to 3.5% by mass, and
the zeolite derived from an ion-exchanged zeolite obtained by ion exchanging an organic template-containing zeolite containing an organic template and having a 10-membered ring one dimensional pore structure in a solution comprising ammonium ion and/or proton.
2. The production method according to claim 1 , wherein a content percentage of sulfur in the stock oil is 0.01 to 0.5% by mass.
3. The production method according to claim 1 , further comprising:
a fourth step of obtaining a hydrorefined oil by hydrorefining the dewaxed oil obtained in the third step, and
a fifth step of fractionating the hydrorefined oil obtained in the fourth step to obtain a base oil for lubricant oils.
4. The production method according to claim 3 , comprising obtaining, in the fifth step, a base oil for lubricant oils having a kinematic viscosity at 100° C. of 3.5 mm 2 /s or more and 4.5 mm 2 /s or less and a viscosity index of 120 or more.
5. The production method according to claim 1 , wherein the stock oil comprises a slack wax having a 10% by volume distillation temperature of 500 to 600° C. and a 90% by volume distillation temperature of 600 to 700° C., and
the hydrocracking is carried out so that a crack per mass of the heavy matter in the first step is 25 to 85% by mass.
6. The production method according to claim 1 , wherein the stock oil comprises a slack wax having a 10% by volume distillation temperature of 400 to 500° C. and a 90% by volume distillation temperature of 500 to 600° C., and
the hydrocracking is carried out so that a crack per mass of the heavy matter in the first step is 20 to 80% by mass.
7. The production method according to claim 1 , wherein the hydrocracking is carried out, in the presence of hydrogen, by allowing the stock oil to contact a hydrocracking catalyst containing a porous inorganic oxide composed of 2 or more elements selected from aluminium, silicon, zirconium, boron, titanium and magnesium and at least 1 metal selected from elements belonging to the Group 6 and the Groups 8 to 10 in the periodic table supported on the porous inorganic oxide.
8. The method for producing a base oil for lubricant oils according to claim 1 , wherein
the third step is a step of obtaining the dewaxed oil by allowing the base oil fraction to contact a hydroisomerization dewaxing catalyst,
the hydroisomerization dewaxing catalyst containing a carrier comprising zeolite having a 10-membered ring one dimensional pore structure and a binder, and platinum and/or palladium supported on the carrier, and having a micro pore volume of 0.02 to 0.12 ml/g,
the zeolite derived from an ion-exchanged zeolite obtained by ion exchanging an organic template-containing zeolite containing an organic template and having a 10-membered ring one dimensional pore structure in a solution comprising ammonium ion and/or proton, and having a micro pore volume per unit mass of 0.01 to 0.12 ml/g.