Aqueous coating compositions including phenolic resin(s)
View Patent ↗The present invention relates to strategies by which one or more phenolic resins are provided in aqueous phenolic dispersions in a manner so that the resultant aqueous phenolic dispersions are more easily combined with water-based latex compositions. The principles of the present invention make it much easier to formulate water-based latex compositions in which substantial phenolic resin content can be stably dispersed for long periods of time. In one aspect, the present invention relates to a method of making a coating composition, comprising a) providing an inverted aqueous dispersion comprising i) at least one polymer having one or more polar, hydrophilic groups; and ii) at least one phenolic resin; b) providing a latex composition; and c) blending the latex composition with the aqueous dispersion to form the coating composition.
1. A method of making a coating composition, comprising:
a) providing an inverted aqueous dispersion comprising:
i) at least one resin having one or more polar, hydrophilic groups, wherein the resin having one or more polar, hydrophilic groups has a number average molecular weight in the range from 2000-15000, and
ii) at least one phenolic resin;
b) providing a latex composition; and
c) blending the latex composition with the inverted aqueous dispersion to form the coating composition, wherein the amount in step a) of the one or more resins having one or more polar, hydrophilic groups is in the range from 0.5-25 parts by weight per 100 parts by weight of the inverted aqueous dispersion and the amount in step a) of the one or more phenolic resins is in the range from 0.05-80 parts by weight per 100 parts by weight of the inverted aqueous dispersion.
2. The method of claim 1 , wherein the at least one phenolic resin comprises at least one substituted phenolic resin.
3. The method of claim 1 , wherein the at least one phenolic resin comprises at least one mono-substituted phenolic resin.
4. The method of claim 1 , wherein the at least one resin comprises an acrylic polymeric surfactant.
5. The method of claim 1 , wherein the inverted aqueous dispersion comprises from 2 to 20 parts by weight of one or more phenolic resins per 100 parts by weight of the inverted aqueous dispersion.
6. The method of claim 1 , wherein the one or more polar, hydrophilic groups comprise quaternary ammonium group.
7. The method of claim 1 , wherein the one or more polar, hydrophilic groups comprise carboxylic acid and/or carboxylic acid salt group.
8. The method of claim 1 , wherein the one or more polar, hydrophilic groups comprise epoxide group.
9. The method of claim 1 , wherein at least one of the resins having polar, hydrophilic group in step (a) has a number average molecular weight in the range from 2000 to 6000.
10. The method of claim 1 , wherein at least one of the resins having polar, hydrophilic group in step (a) is derived from ingredients comprising (i) at least one epoxide functional reactant, (ii) at least one acid, acid salt, or acid anhydride functional reactant, and (iii) at least one tertiary amine.
11. The method of claim 1 , wherein at least one of the resins having polar, hydrophilic group in step (a) has an acid number in the range from 15 to 400.
12. The method of claim 1 , wherein at least one of the resins having polar, hydrophilic group in step (a) is derived from one or more ingredients comprising acid anhydride functionality.
13. The method of claim 1 , wherein step (a) comprises (i) providing an organic dispersion and (ii) adding an amount of water to the organic dispersion effective to convert the organic dispersion to the inverted aqueous dispersion.
14. The method of claim 1 , wherein the latex composition in step (b) comprises a resin surfactant.
15. The method of claim 1 , wherein the latex composition in step (b) comprises a free radically polymerized resin surfactant.
16. The method of claim 1 , wherein the latex composition in step (b) comprises a resin surfactant comprising quaternary ammonium group.
17. The method of claim 1 , wherein the latex composition in step (b) comprises a resin surfactant comprising epoxide group.
18. The method of claim 1 , wherein the latex composition in step (b) comprises a resin surfactant comprising acid or acid salt group.
19. The method of claim 1 , wherein the latex composition in step (b) comprises a resin surfactant derived from ingredients comprising an epoxide functional reactant, an acid or acid salt functional reactant, and a tertiary amine.
20. The method of claim 1 , wherein the latex composition in step (b) comprises a resin surfactant derived from one or more ingredients comprising acid anhydride group.
21. The method of claim 1 , wherein the amount in step (b) of the latex composition is about 40 parts by weight per 100 parts by weight of the coating composition.
22. A food or beverage container, comprising:
a) a metallic surface; and
b) at least one coating providing on the surface, said coating derived from a coating composition comprising an inverted aqueous dispersion comprising: i) at least one resin having one or more polar, hydrophilic groups, wherein the resin having one or more polar, hydrophilic groups has a number average molecular weight in the range from 2000-15000; and ii) at least one phenolic resin; and a latex composition blended with the inverted aqueous dispersion, wherein the amount of the one or more resins having one or more polar, hydrophilic groups is in the range from 0.5-25 parts by weight per 100 parts by weight of the inverted aqueous dispersion and the amount of the one or more phenolic resins is in the range from 0.05-80 parts by weight per 100 parts by weight of the inverted aqueous dispersion.
23. A coating composition comprising:
a) an inverted aqueous dispersion comprising:
i) at least one resin having one or more polar, hydrophilic groups, wherein the resin having one or more polar, hydrophilic groups has a number average molecular weight in the range from 2000-15000; and
ii) at least one phenolic resin; and
b) a latex composition, wherein a) and b) are blended in the coating composition, and wherein the amount of the one or more resins having one or more polar, hydrophilic groups is in the range from 0.5-25 parts by weight per 100 parts by weight of the inverted aqueous dispersion and the amount of the one or more phenolic resins is in the range from 0.05-80 parts by weight per 100 parts by weight of the inverted aqueous dispersion.
24. A method of using a coating composition comprising the step of coating the surface of food or beverage container with a coating composition comprising:
a) an inverted aqueous dispersion comprising:
i) at least one resin having one or more polar, hydrophilic groups, wherein the resin having one or more polar, hydrophilic groups has a number average molecular weight in the range from 2000-15000; and
ii) at least one phenolic resin; and
b) a latex composition, wherein a) and b) are blended in the coating composition and wherein the amount of the one or more resins having one or more polar, hydrophilic groups is in the range from 0.5-25 parts by weight per 100 parts by weight of the inverted aqueous dispersion and the amount of the one or more phenolic resins is in the range from 0.05-80 parts by weight per 100 parts by weight of the inverted aqueous dispersion.
25. The method of claim 1 , wherein said resin having one or more polar, hydrophilic groups is prepared from a reaction mixture including at least 20 wt. % unsaturated monomer(s) comprising acid or salt thereof and/or acid anhydride functionality, and the balance other free radically reactive monomer(s).