Polymer composition, crosslinked polymer, tire, and polymer
Provided is a polymer composition for use in the production of a crosslinked polymer having excellent tensile strength and abrasion resistance. A polymer composition comprising a polymer having multiple anionic functional groups and a polymer having multiple nitrogenated functional groups each represented by formula (1). The anionic functional groups are at least one group selected from a carboxy group, a sulfo group and a phosphate group. In one embodiment, each of the nitrogenated functional groups represented by formula (1) is bound to a structure derived from a conjugated diene compound or a structure derived from an aromatic vinyl compound.
1. A polymer composition comprising:
a polymer that comprises a plurality of anionic functional groups; and
a polymer that comprises a plurality of structures represented by formula (1),
wherein * represents a site at which C or N is bonded to another atom, and
wherein the polymer that comprises a plurality of anionic functional groups comprises a structural unit derived from a conjugated diene compound.
2. The polymer composition according to claim 1 , wherein the plurality of anionic functional groups are one or more anionic functional groups selected from the group consisting of a carboxyl group, a sulfo group, and a phosphoric acid group.
3. The polymer composition according to claim 1 , wherein the polymer that comprises the plurality of structures represented by the formula (1) comprises a structural unit derived from a conjugated diene compound.
4. The polymer composition according to claim 3 , wherein the polymer that comprises the plurality of structures represented by the formula (1) has a structure in which the structure represented by the formula (1) is bonded to a vinyl group comprised in the structural unit derived from the conjugated diene compound.
5. The polymer composition according to claim 3 , wherein the polymer that comprises the plurality of structures represented by the formula (1) comprises a structural unit derived from an aromatic vinyl compound, and has a structure in which the structure represented by the formula (1) is bonded to a benzylic position of an aromatic ring comprised in the structural unit derived from the aromatic vinyl compound.
6. The polymer composition according to claim 1 , further comprising silica and a crosslinking agent.
7. A crosslinked polymer obtained by crosslinking the polymer composition according to claim 6 .
8. A tire, obtained by employing the crosslinked polymer according to claim 7 as at least either a tread material or a sidewall material.
9. The polymer composition according to claim 3 , wherein the structure represented by the formula (1) is included in a group represented by formula (1-1),
wherein R 1 and R 2 are independently represents a hydrocarbyl group or a group in which —NR 3 — is inserted between two carbon atoms in a hydrocarbyl group, wherein R 3 is a hydrocarbyl group, and * represents a site at which C is bonded to a carbon atom included in the main chain of the polymer that comprises the plurality of structures represented by the formula (1), or is bonded to a linking group that is bonded to the main chain of the polymer that comprises the plurality of structures represented by the formula (1).
10. The polymer composition according to claim 9 , wherein in the formula (1-1), R 1 and R 2 are independently represents a linear or branched alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, an aryl group having 5 to 20 carbon atoms, or a group in which —NR 3 — is inserted between two carbon atoms in a linear or branched alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, or an aryl group having 5 to 20 carbon atoms, wherein R 3 is a linear or branched alkyl group having 1 to 6 carbon atoms, a cyclohexyl group, or a phenyl group.
11. The polymer composition according to claim 3 , wherein a content of the structure represented by the formula (1) in the polymer that comprises the plurality of structures represented by the formula (1) is from 0.3 to 5 mol %, based on total structural units derived from monomers included in the polymer that comprises the plurality of structures represented by the formula (1).
12. The polymer composition according to claim 2 , wherein the polymer that comprises the plurality of structures represented by the formula (1) comprises a structural unit derived from a conjugated diene compound.
13. The polymer composition according to claim 12 , wherein the polymer that comprises the plurality of structures represented by the formula (1) has a structure in which the structure represented by the formula (1) is bonded to a vinyl group comprised in the structural unit derived from the conjugated diene compound.
14. The polymer composition according to claim 12 wherein the polymer that comprises the plurality of structures represented by the formula (1) comprises a structural unit derived from an aromatic vinyl compound, and has a structure in which the structure represented by the formula (1) is bonded to a benzylic position of an aromatic ring comprised in the structural unit derived from the aromatic vinyl compound.
15. The polymer composition according to claim 2 , further comprising silica and a crosslinking agent.
16. A crosslinked polymer obtained by crosslinking the polymer composition according to claim 15 .
17. A tire, obtained by employing the crosslinked polymer according to claim 16 as at least either a tread material or a sidewall material.
18. The polymer composition according to claim 12 , wherein the structure represented by the formula (1) is included in a group represented by formula (1-1),
wherein R 1 and R 2 are independently represents a hydrocarbyl group or a group in which —NR 3 — is inserted between two carbon atoms in a hydrocarbyl group, wherein R 3 is a hydrocarbyl group, and * represents a site at which C is bonded to a carbon atom included in the main chain of the polymer that comprises the plurality of structures represented by the formula (1), or is bonded to a linking group that is bonded to the main chain of the polymer that comprises the plurality of structures represented by the formula (1).
19. The polymer composition according to claim 18 , wherein in the formula (1-1), R 1 and R 2 are independently represents a linear or branched alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, an aryl group having 5 to 20 carbon atoms, or a group in which —NR 3 — is inserted between two carbon atoms in a linear or branched alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, or an aryl group having 5 to 20 carbon atoms, wherein R 3 is a linear or branched alkyl group having 1 to 6 carbon atoms, a cyclohexyl group, or a phenyl group.
20. The polymer composition according to claim 12 , wherein a content of the structure represented by the formula (1) in the polymer that comprises the plurality of structures represented by the formula (1) is from 0.3 to 5 mol %, based on total structural units derived from monomers included in the polymer that comprises the plurality of structures represented by the formula (1).