IP Library Granted Patent US 9,828,549
Granted Patent B2
US 9,828,549 · App. 14/768,985 · Granted Nov 28, 2017

Liquid crystal composition, liquid crystal display device, and liquid crystal display

Inventors: Joji Kawamura (Kita-adachi-gun, JP); Makoto Negishi (Kita-adachi-gun, JP); Yoshinori Iwashita (Kita-adachi-gun, JP)
Assignee: DIC CORPORATION
C09K19/3402C09K19/0216C09K19/42C09K2019/0466C09K2019/3009C09K2019/3012C09K2019/3016C09K2019/3019C09K2019/3422
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Quick Facts
Patent No.
US 9,828,549
App. No.
14/768,985
Granted
Nov 28, 2017
Kind
B2
Abstract

There is provided a liquid crystal composition containing any one or two or more of compounds represented by general formula (i) below and any one or two or more of compounds represented by general formula (ii) below.

Claims (41)

1. A liquid crystal composition, comprising:

a compound represented by general formula (X-1-2) below, wherein the compound represented by general formula (X-1-2) is included in the liquid crystal composition, and a content of the compound represented by general formula (X-1-2) is 7% by mass or less;

a compound represented by general formula (ii) below;

a compound represented by general formula (VIII) below,

a compound represented by formula (2.2) below; and

a compound represented by general formula (XI) below:

(in the formula (ii), R 21a represents an alkyl group having 1 to 8 carbon atoms; one or nonadjacent two or more —CH 2 — in the alkyl group may be each independently substituted by —CH═CH—, —C≡C—, —O—, —CO—, —COO—, or —OCO—; one or two or more hydrogen atoms in the alkyl group may be each independently substituted by a fluorine atom or a chlorine atom;

m 21 represents 0 or 1; X 21 , X 22 , X 23 , and X 24 each independently represent a hydrogen atom, a fluorine atom, or a chlorine atom; and X 25 represents a hydrogen atom, a fluorine atom, a chlorine atom, a cyano group, —CF 3 , or —OCF 3 ),

(in the formula (X-1-2), R 10 represents an alkyl group having 1 to 5 carbon atoms, an alkenyl group having 2 to 5 carbon atoms, or an alkoxy group having 1 to 4 carbon atoms),

(in the formula (VIII), R 8 represents an alkyl group having 1 to 5 carbon atoms, an alkenyl group having 2 to 5 carbon atoms, or an alkoxy group having 1 to 4 carbon atoms, X 81 to X 85 each independently represent a hydrogen atom or a fluorine atom, and Y 8 represents a fluorine atom or —OCF 3 ),

(in the formula, X 111 to X 117 each independently represent a fluorine atom or a hydrogen atom, at least one of X 111 to X 117 represents a fluorine atom, R 110 represents an alkyl group having 1 to 5 carbon atoms, an alkenyl group having 2 to 5 carbon atoms, or an alkoxy group having 1 to 4 carbon atoms, and Y 11 represents a fluorine atom or —OCF 3 ).

2. The liquid crystal composition according to claim 1 , further comprising another compound represented by the general formula (X-1-2).

3. The liquid crystal composition according to claim 1 , further comprising another compound represented by the general formula (ii).

4. The liquid crystal composition according to claim 1 , further comprising a compound represented by general formula (L) below,

(in the formula, R L1 and R L2 each independently represent an alkyl group having 1 to 8 carbon atoms; one or nonadjacent two or more —CH 2 — in the alkyl group may be each independently substituted by —CH═CH—, —C≡C—, —O—, —CO—, —COO—, or —OCO—;

OL represents 0, 1, 2, or 3;

B L1 , B L2 , and B L3 each independently represent a group selected from the group consisting of:

(a) a 1,4-cyclohexylene group (one —CH 2 — or nonadjacent two or more —CH 2 — present in the group may be substituted by —O—); and

(b) a 1,4-phenylene group (one —CH═ or nonadjacent two or more —CH═ present in the group may be substituted by —N═), and one and/or two or more hydrogen atoms in the group (a) and the group (b) may be each independently substituted by a cyano group, a fluorine atom, or a chlorine atom;

L L1 and L L2 each independently represent a single bond, —CH 2 CH 2 —, —(CH 2 ) 4 —, —OCH 2 —, —CH 2 O—, —COO—, —OCO—, —OCF 2 —, —CF 2 O—, —CH═N—N═CH—, —CH═CH—, —CF═CF—, or —C≡C—; and

when OL is 2 or 3, and a plurality of L L2 are present, L L2 may be the same or different, and when OL is 2 or 3, and a plurality of B L3 are present, B L3 may be the same or different).

5. The liquid crystal composition according to claim 1 , further comprising a compound represented by general formula (M) below,

(in the formula, R M1 represents an alkyl group having 1 to 8 carbon atoms; one or nonadjacent two or more —CH 2 — in the alkyl group may be each independently substituted by —CH═CH—, —C≡C—, —O—, —CO—, —COO—, or —OCO—;

PM represents 0, 1, 2, 3, or 4;

C M1 and C M2 each independently represent a group selected from the group consisting of:

(d) a 1,4-cyclohexylene group (one —CH 2 — or nonadjacent two or more —CH 2 — present in the group may be substituted by —O— or —S—); and

(e) a 1,4-phenylene group (one —CH═ or nonadjacent two or more —CH═ present in the group may be substituted by —N═), and one and/or two or more hydrogen atoms in the group (d) and the group (e) may be each independently substituted by a cyano group, a fluorine atom, or a chlorine atom;

K M1 and K M2 each independently represent a single bond, —CH 2 CH 2 —, —(CH 2 ) 4 —, —OCH 2 —, —CH 2 O—, —OCF 2 —, —CF 2 O—, —COO—, —OCO—, or —C≡C—;

when PM is 2, 3, or 4, and a plurality of K M1 are present, K M1 may be the same or different, and when PM is 2, 3, or 4, and a plurality of C M2 are present, C M2 may be the same or different;

X M1 and X M3 each independently represent a hydrogen atom, a chlorine atom, or a fluorine atom; and

X M2 represents a hydrogen atom, a fluorine atom, a chlorine atom, a cyano group, a trifluoromethyl group, a fluoromethoxy group, a difluoromethoxy group, a trifluoromethoxy group, or a 2,2,2-trifluoroethyl group, with the compounds represented by the general formula (i) and the general formula (ii) being excluded).

6. A liquid crystal display device comprising the liquid crystal composition according to claim 1 .

7. A liquid crystal display device for an IPS mode, an OCB mode, an ECB mode, a VA mode, or a FFS mode comprising the liquid crystal composition according to claim 1 .

8. A liquid crystal display comprising the liquid crystal display device according to claim 7 .

9. A liquid crystal display comprising the liquid crystal display device according to claim 8 .

10. The liquid crystal composition according to claim 1 , wherein the liquid crystal composition has a rotational viscosity γ1 at 295K of 70 to 90 mPa·s.

11. The liquid crystal composition according to claim 1 , further comprising a compound represented by general formula (IX-2),

wherein R 9 represents an alkyl group having 1 to 5 carbon atoms, an alkenyl group having 2 to 5 carbon atoms, or an alkoxy group having 1 to 4 carbon atoms, X 91 and X 92 each independently represent a hydrogen atom or a fluorine atom, and Y 9 represents a fluorine atom, a chlorine atom, or —OCF 3 .

12. The liquid crystal composition according to claim 1 , wherein the alkyl group of the R 10 has 3 carbon atoms.

13. The liquid crystal composition according to claim 1 , wherein the compound represented by general formula (X-1-2) is included in the liquid crystal composition at a content of 1% by mass or more.

14. The liquid crystal composition according to claim 1 , wherein the compound represented by general formula (X-1-2) is included in the liquid crystal composition at a content of 2% by mass or more.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 24, 2024
From: DIC CORPORATION
To: SHIJIAZHUANG CHENGZHI YONGHUA DISPLAY MATERIAL CO., LTD.
Reel/Frame 067528/0688 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 22, 2015
From: KAWAMURA, JOJI; NEGISHI, MAKOTO; IWASHITA, YOSHINORI
To: DIC CORPORATION
Reel/Frame 036853/0187 →
Continuity (1)
Related Publication 20150376503A1 · Dec 31, 2015