Rapid setting material for improved processing and performance of carbonating metal silicate cement
View Patent ↗Cementitious compositions and methods for producing the cementitious compositions are described herein. The methods can include mixing a compound of the general formula M a Si b X c O d , M a Si b X c O d (OH) e , M a Si b X c (OH) e , or M a Si b X c (OH) e .(H 2 O) f , wherein M comprises a metal that can react with carbon dioxide in a carbonation reaction to form a carbonate, Si forms an oxide during the carbonation reaction, X is an element other than M or Si, a, b, d, e, and f are greater than zero, and c is zero or greater, with a rapid setting hydraulic cement to produce a cementitious mixture. The methods can further include hydrating the cementitious mixture and carbonating the cementitious mixture. Carbonating the cementitious mixture can occur simultaneously with hydrating the cementitious mixture or subsequent to hydrating the cementitious mixture. In some embodiments, the non-hydraulic cement can comprise wollastonite. The hydraulic cement can be in an amount of from 5 wt % to 80 wt % of the cementitious composition.
1. A method for producing a cementitious composition comprising:
(i) mixing
from 30 wt % to 85 wt %, based on the weight of the cementitious composition, of a compound of the general formula M a Si b X c O d , M a Si b X c O d (OH) e , M a Si b X c (OH) e , or M a Si b X c (OH) e (H 2 O) f , wherein M comprises a metal that can react with carbon dioxide in a carbonation reaction to form a carbonate, Si forms an oxide during the carbonation reaction, X is an element other than M or Si, a, b, d, e, and f are greater than zero, and c is zero or greater with
from 15 wt % to 70 wt %, based on the weight of the cementitious composition, of a rapid setting hydraulic cement to produce a cementitious mixture;
(ii) hydrating the cementitious mixture to react the rapid setting hydraulic cement with water; and
(iii) carbonating the cementitious mixture.
2. The method of claim 1 , wherein M includes an alkaline earth metal selected from the group consisting of calcium, magnesium, sodium, or a combination thereof.
3. The method of claim 1 , wherein the compound of general formula M a Si b X c O d includes wollastonite.
4. The method of claim 1 , wherein the rapid setting hydraulic cement includes a hydraulic cement selected from the group consisting of calcium aluminate cement (CAC), calcium phosphate cement, calcium sulfate hydrate, calcium aluminate sulfonate (CAS) cement, magnesium oxychloride cement, magnesium oxysulfate cement, magnesium phosphate cement, and combinations thereof.
5. The method of claim 1 , wherein the hydraulic cement is in an amount of from 20 wt % to 70 wt % of the cementitious composition.
6. The method of claim 1 , wherein carbonating the cementitious mixture occurs simultaneously with hydrating the cementitious mixture.
7. The method of claim 1 , wherein carbonating the cementitious mixture occurs 15 minutes to 60 minutes after hydrating the cementitious mixture.
8. The method of claim 1 , wherein the hydraulic cement provides a compressive strength of at least about 1,000 lbs/in 2 in less than 15 minutes after hydration.
9. The method of claim 1 , wherein the hydraulic cement provides a compressive strength of at least about 2,000 lbs/in 2 in less than 60 minutes after hydration.
10. The method of claim 1 , further comprising removing the cementitious mixture from a mold before carbonating the cementitious mixture.
11. The method of claim 1 , wherein carbonating the cementitious mixture comprises using carbon dioxide dissolved in water.
12. The method of claim 1 , further comprising mixing an aggregate in the cementitious mixture.
13. The method of claim 1 , further comprising mixing Ca(OH) 2 in the cementitious mixture.
14. A cementitious product formed by:
(i) mixing
from 30 wt % to 85 wt %, based on the weight of the cementitious product, of a compound of the general formula M a Si b X c O d , M a Si b X c O d (OH) e , M a Si b X c (OH) e , or M a Si b X c (OH) e (H 2 O) f , wherein M comprises a metal that can react with carbon dioxide in a carbonation reaction to form a carbonate, Si forms an oxide during the carbonation reaction, X is an element other than M or Si, a, b, d, e, and f are greater than zero, and c is zero or greater, with
from 15 wt % to 70 wt %, based on the weight of the cementitious product of rapid setting hydraulic cement to produce a cementitious mixture;
(ii) hydrating the cementitious mixture to react the rapid setting hydraulic cement with water; and
(iii) carbonating the cementitious mixture.
15. The cementitious product of claim 14 , wherein M is an alkaline earth metal selected from the group consisting of calcium, magnesium, and a combination thereof.
16. The cementitious product of claim 14 , wherein the rapid setting hydraulic cement includes a hydraulic cement selected from the group consisting of calcium aluminate cement, calcium phosphate cement, calcium sulfate hydrate, calcium aluminate sulfonate cement, magnesium oxychloride cement, magnesium oxysulfate cement, magnesium phosphate cement, and combinations thereof.
17. The cementitious product of claim 14 , wherein the hydraulic cement is in an amount of from 20 wt % to 70 wt % of the product.
18. The cementitious product of claim 14 , wherein the cementitious product has a compressive strength of at least 1000 lbs/in 2 .
19. The cementitious product of claim 14 , wherein the cementitious mixture further comprises aggregate.
20. A building material comprising the cementitious product of claim 14 , wherein the building material is selected from the group consisting of a tile, a brick, a paver, a panel, a synthetic stone, or an underlay.