Granted Patent B2

US 9,822,275 · App. 14/770,123 · Granted Nov 21, 2017

Abstract

Claims (46)

1. A method of preparing a water-based composition, the method comprising:

providing an aqueous polymer comprising a latex or water-dispersible polymer in water;

providing an additive package comprising at least one of a pigment, a thickener, a mildewcide, a biocide, a defoamer, a surfactant, a dispersant, a filler, and combinations thereof;

providing one or more water-insoluble UV-VIS absorbers capable of absorbing radiation within a range of 240-465 nm;

providing one or more low VOC coalescents having a volatile organic content of 30% or less according to ASTM D2369-90, or that elute from a GC column at the same time or after methyl palmitate under the same conditions according to ASTM D6886-12;

mixing the one or more water-insoluble UV-VIS absorbers in the one or more low VOC coalescents to form an absorber-coalescent mixture; and

combining the aqueous polymer, the additive package, and the absorber-coalescent to form a water-based composition;

wherein the water-based composition comprises a sufficient amount of the one or more water-insoluble UV-VIS absorbers to improve dirt pick-up resistance by at least 10%, relative to the same water-based composition without the UV-VIS absorber, based on a change in ΔE values.

2. The method of claim 1 wherein combining the aqueous polymer, the additive package, and the absorber-coalescent to form a water-based coating comprises mixing the absorber-coalescent mixture with the aqueous polymer, additive package, or both, and subsequently mixing the aqueous polymer with the additive package.

3. The method of claim 1 wherein combining the aqueous polymer, the additive package, and the absorber-coalescent to form a water-based coating comprises mixing the absorber-coalescent mixture with the aqueous polymer, and subsequently mixing the aqueous polymer having the absorber-coalescent therein with the additive package.

4. The method of claim 1 wherein mixing the one or more water-insoluble ultraviolet absorbers in the one or more low VOC coalescents to form an absorber-coalescent mixture comprises dissolving the one or more water-insoluble ultraviolet absorbers in the one or more low VOC coalescents to form an absorber-coalescent solution.

5. The method of claim 1 wherein the water-based composition comprises a sufficient amount of the one or more coalescents to facilitate coalescence of the aqueous polymer.

6. The method of claim 1 wherein the water-based composition comprises a sufficient amount of the one or more water-insoluble UV-VIS absorbers to improve dirt pick-up resistance of the water-based composition by at least 50%, relative to the same water-based composition without the UV-VIS absorber, based on a change in ΔE values.

7. The method of claim 1 wherein the water-based composition comprises at least 0.1 wt-% of the one or more UV-VIS absorbers, based on the weight of the polymer solids.

8. The method of claim 1 wherein the water-based composition comprises up to 5.0 wt-% of the one or more UV-VIS absorbers, based on the weight of the polymer solids.

9. The method of claim 1 wherein the one or more water-insoluble ultraviolet absorbers are capable of absorbing UV radiation within a range of 315-375 nm.

10. The method of claim 1 wherein the one or more water-insoluble ultraviolet absorbers is selected from the group of benzophenone, polymeric benzophenone, phenylbis(2,4,6-trimethylbenzoyl)phosphine oxide, ethyl-2,4,6-trimethylbenzoylphenylphosphinate, 2,4,6-trimethylbenzophenone, 4-methylbenzophenone, 2,2-dimethoxy-1,2-diphenylethanone, 1-hydroxycyclohexyl phenyl ketone, 2-hydroxy-2-methyl-1-phenyl-1-propanone, isopropylthioxanthone, methyl-o-benzoyl-benzoate, methylbenzoylformate, benzoin ethyl ether, 4′-ethoxyacetophenone, and combinations thereof.

11. The method of claim 10 wherein the one or more water-insoluble ultraviolet absorbers is benzophenone.

12. The method of claim 1 wherein the water-based composition is a paint, a sealer, a caulk, or a sealant.

13. The method of claim 1 wherein the aqueous polymer comprises a latex polymer having at least one Tg within a range of −20° C. to 70° C.

14. The method of claim 13 wherein the latex polymer comprises the polymerization product of ethylenically unsaturated monomers selected from the group of alkyl acrylates, alkoxy acrylates, alkyl methacrylates, alkoxy methacrylates, vinyl esters of saturated carboxylic acids, monoolefins, and conjugated dienes optionally with one or more monomers, selected from the group of styrene, methyl methacrylate, butyl acrylate, 2-ethylhexyl acrylate, vinyl acetate, acrylonitrile, and vinyl chloride.

15. The method of claim 14 wherein the latex polymer comprises a surfactant and polymer particles comprising a homopolymer or copolymer including at least one of an acrylate or a methacrylate.

16. The method of claim 1 wherein the one or more coalescents are present in a sufficient amount to facilitate the formation of a polymer film of a latex polymer at a temperature of less than 25° C.

17. The method of claim 1 wherein the one or more coalescents has a volatile organic content of 15% or less.

18. The method of claim 1 wherein at least one coalescent is selected from the group of bis(2-ethylhexyl) maleate, bis(2-ethylhexyl) adipate, bis(2-ethylhexyl) azelate, isodecyl benzoate, tri(ethylene glycol)bis(2-ethylhexanoate), tetra(ethylene glycol)bis(2-ethylhexanoate), tributyl citrate, octyl benzoate, di(ethylene glycol)dibenzoate, octadecenoic acid methyl ester, and oleic acid monoester of propylene glycol.

19. A method of preparing a water-based composition, the method comprising:

providing an aqueous polymer comprising a latex polymer in water;

providing an additive package comprising at least one of a pigment, a thickener, a mildewcide, a biocide, a defoamer, a surfactant, a dispersant, a filler, and combinations thereof;

providing one or more water-insoluble UV-VIS absorbers capable of absorbing radiation within a range of 240-465 nm;

providing one or more low VOC coalescents having a volatile organic content of 30% or less according to ASTM D2369-90, or that elute from a GC column at the same time or after methyl palmitate under the same conditions according to ASTM D6886-12;

dissolving the one or more water-insoluble UV-VIS absorbers in the one or more low VOC coalescents to form an absorber-coalescent solution;

mixing the absorber-coalescent solution with the aqueous polymer; and

subsequently mixing the aqueous polymer having the absorber-coalescent therein with the additive package;

wherein the water-based composition comprises a sufficient amount of the one or more water-insoluble UV-VIS absorbers to improve dirt pick-up resistance by at least 10%, relative to the same water-based composition without the UV-VIS absorber, based on a change in ΔE values.

20. A water-based composition prepared by a method of claim 1 .

21. A water-based composition prepared by a method of claim 19 .

22. A method of preparing a water-based composition, the method comprising:

providing an aqueous polymer comprising a latex or water-dispersible polymer in water;

providing an additive package comprising at least one of a pigment, a thickener, a mildewcide, a biocide, a defoamer, a surfactant, a dispersant, a filler, and combinations thereof;

providing one or more water-insoluble UV-VIS absorbers capable of absorbing radiation within a range of 240-465 nm;

providing one or more low VOC coalescents having a volatile organic content of 30% or less according to ASTM D2369-90, or that elute from a GC column at the same time or after methyl palmitate under the same conditions according to ASTM D6886-12;

mixing the one or more water-insoluble UV-VIS absorbers in the one or more low VOC coalescents to form an absorber-coalescent mixture; and

combining the aqueous polymer, the additive package, and the absorber-coalescent to form a water-based composition having a VOC of no more than 200 grams/liter;

wherein the water-based composition comprises a sufficient amount of the one or more water-insoluble UV-VIS absorbers to improve dirt pick-up resistance by at least 10%, relative to the same water-based composition without the UV-VIS absorber, based on a change in ΔE values.

23. The method of claim 1 wherein providing one or more low VOC coalescents comprises providing one or more low VOC coalescents having a volatile organic content of 30% or less according to ASTM D2369-90, and that elute from a GC column at the same time or after methyl palmitate under the same conditions according to ASTM D6886-12.

24. A water-based composition prepared by a method of claim 22 .

Assignments (9)