Lithium manganese-based oxide and cathode active material including the same
View Patent ↗Disclosed is a lithium manganese (Mn)-based oxide including Mn as an essential transition metal and having a layered crystal structure, in which the amount of Mn is greater than that of other transition metal(s), the lithium manganese-based oxide exhibits flat level section characteristics in which release of oxygen occurs together with lithium deintercalation during first charging in a high voltage range of 4.4 V or higher, and at least one of a transition metal layer including Mn and an oxygen layer is substituted or doped with a pillar element.
1. A lithium manganese (Mn)-based oxide comprising Mn as an essential transition metal and having a layered crystal structure,
wherein an amount of Mn is greater than that of other transition metal(s),
the lithium manganese-based oxide exhibits flat level section characteristics in which release of oxygen occurs together with lithium deintercalation during first charging in a high voltage range of 4.4 V or higher,
wherein the lithium manganese-based oxide has a layered structure comprising at least one transition metal layer including Mn and at least one oxygen layer and is represented by Formula 1 below:
x Li 2 MnO 3 .(1 −x )LiMO 2 (1)
wherein 0<x<1; and
M is at least one element selected from the group consisting of nickel (Ni), cobalt (Co), and Mn
wherein the at least one transition metal layer including Mn and/or the at least one oxygen layer is substituted or doped with a pillar element; and the pillar element is at least one selected from the group consisting of vanadium (V), sodium (Na), iron (Fe), barium (Ba), strontium (Sr), zirconium (Zr), and calcium (Ca).
2. The lithium manganese-based oxide according to claim 1 , wherein an amount of the pillar element is 0.02 mol % to 0.1 mol % based on a total amount of the lithium manganese-based oxide.
3. The lithium manganese-based oxide according to claim 1 , wherein an amount of Mn is 50 mol % or more based on a total amount of the transition metals.
4. The lithium manganese-based oxide according to claim 1 , wherein the lithium manganese-based oxide is prepared by dry-mixing a compound comprising the pillar element with a transition metal precursor and a lithium precursor and heat-treating the mixture.
5. The lithium manganese-based oxide according to claim 4 , wherein the heat-treating is performed at a temperature of 800° C. to 1000° C.
6. The lithium manganese-based oxide according to claim 4 , wherein the heat-treating is performed in air.
7. A cathode active material for secondary batteries, comprising the lithium manganese-based oxide according to claim 1 .
8. A cathode mixture for secondary batteries, comprising the cathode active material according to claim 7 .
9. A cathode for secondary batteries, in which the cathode mixture according to claim 8 is coated on a current collector.
10. A lithium secondary battery comprising the cathode according to claim 9 .
11. A battery module comprising the lithium secondary battery according to claim 10 as a unit cell.
12. A battery pack comprising the battery module according to claim 11 .
13. A device using the battery pack according to claim 12 as a power source.
14. A cathode active material for secondary batteries, comprising the lithium manganese-based oxide according to claim 2 .
15. A cathode active material for secondary batteries, comprising the lithium manganese-based oxide according to claim 3 .
16. A cathode active material for secondary batteries, comprising the lithium manganese-based oxide according to claim 4 .
17. A cathode active material for secondary batteries, comprising the lithium manganese-based oxide according to claim 5 .
18. A cathode active material for secondary batteries, comprising the lithium manganese-based oxide according to claim 6 .