Rubber composition for tire for heavy loads, and pneumatic tire
View Patent ↗A rubber composition for a tire for heavy loads of the present technology comprises: diene rubber containing at least 60% by mass of natural rubber; silica; carbon black; and a silane coupling agent. The silane coupling agent is polysiloxane represented by a specific average compositional formula. The content of the silica is from 5 to 50 parts by mass per 100 parts by mass of the diene rubber. The content of the carbon black is from 5 to 40 parts by mass per 100 parts by mass of the diene rubber. The total content of the silica and the carbon black (R) is from 30 to 70 parts by mass per 100 parts by mass of the diene rubber. The content of the silane coupling agent is from 2 to 20% by mass of the silica content.
1. A rubber composition for a tire for heavy loads comprising: diene rubber (P) containing at least 60% by mass of natural rubber; silica (Q); carbon black (R); and a silane coupling agent (S);
the silane coupling agent (S) being polysiloxane represented by an average compositional formula of formula (1) below;
a content of the silica (Q) being from 5 to 50 parts by mass per 100 parts by mass of the diene rubber (P);
a content of the carbon black (R) being from 5 to 40 parts by mass per 100 parts by mass of the diene rubber (P);
a total content of the silica (Q) and the carbon black (R) being from 30 to 70 parts by mass per 100 parts by mass of the diene rubber (P); and
a content of the silane coupling agent (S) being from 2 to 20% by mass relative to the content of the silica (Q):
(A) a (B) b (C) c (D) d (E) e SiO (4-2a-b-c-d-e)/2 (1)
wherein, A represents a divalent organic group having a sulfide group; B represents a monovalent hydrocarbon group having from 5 to 10 carbons; C represents a hydrolyzable group; D represents an organic group having a mercapto group; E represents a monovalent hydrocarbon group having from 1 to 4 carbons; and a to e satisfy relationships of formulas: 0≦a<1, 0≦b<1, 0<c<3, 0<d<1, 0≦e<2, and 0<2a+b+c+d+e<4; however, one of either a or b is not 0.
2. The rubber composition for a tire for heavy loads according to claim 1 , wherein a nitrogen adsorption specific surface area of the carbon black (R) is from 60 to 150 m 2 /g.
3. The rubber composition for a tire for heavy loads according to claim 1 , wherein, in the formula (1), a is greater than 0.
4. The rubber composition for a tire for heavy loads according to claim 1 , wherein, in the formula (1), b is greater than 0.
5. The rubber composition for a tire for heavy loads according to claim 1 , wherein the rubber composition is used for a tire tread.
6. The rubber composition for a tire for heavy loads according to claim 1 , wherein the rubber composition is used for a bead filler.
7. A pneumatic tire produced by using the rubber composition for a tire for heavy loads described in claim 1 .
8. A pneumatic tire produced by using the rubber composition for a tire for heavy loads described in claim 1 for a tire tread.
9. A pneumatic tire produced by using the rubber composition for a tire for heavy loads described in claim 1 for a bead filler.
10. The rubber composition for a tire for heavy loads according to claim 2 , wherein, in the formula (1), a is greater than 0.
11. The rubber composition for a tire for heavy loads according to claim 2 , wherein, in the formula (1), b is greater than 0.
12. The rubber composition for a tire for heavy loads according to claim 2 , wherein the rubber composition is used for a tire tread.
13. The rubber composition for a tire for heavy loads according to claim 2 , wherein the rubber composition is used for a bead filler.
14. A pneumatic tire produced by using the rubber composition for a tire for heavy loads described in claim 2 .
15. A pneumatic tire produced by using the rubber composition for a tire for heavy loads described in claim 2 for a tire tread.
16. A pneumatic tire produced by using the rubber composition for a tire for heavy loads described in claim 2 for a bead filler.
17. The rubber composition for a tire for heavy loads according to claim 3 , wherein, in the formula (1), b is greater than 0.
18. The rubber composition for a tire for heavy loads according to claim 3 , wherein the rubber composition is used for a tire tread.
19. The rubber composition for a tire for heavy loads according to claim 3 , wherein the rubber composition is used for a bead filler.
20. A pneumatic tire produced by using the rubber composition for a tire for heavy loads described in claim 3 .