Rubber composition for tire tread, and pneumatic tire using same
View Patent ↗A rubber composition for a tire tread comprising: a diene rubber; a silica having an N 2 SA of from 194 to 225 m 2 /g and a CTAB of from 180 to 210 m 2 /g; and a polysiloxane represented by the average composition formula of formula (1) and contained in an amount of from 1 to 20 mass % with respect to the quantity of silica. (A) a (B) b (C) c (D) d (R 1 ) 3 SiO (4-2a-b-c-d-e)/2 . Also provided is a pneumatic tire having tire treads formed using the rubber composition.
1. A rubber composition for a tire tread comprising a diene rubber, silica, and a sulfur-containing silane coupling agent;
a nitrogen adsorption specific surface area of the silica being from 194 to 240 m 2 /g; a CTAB specific surface area of the silica being from 180 to 215 m 2 /g; a content of the silica being from 60 to 200 parts by mass per 100 parts by mass of the diene rubber;
the sulfur-containing silane coupling agent being a polysiloxane represented by the following formula (1); and a content of the sulfur-containing silane coupling agent being from 1 to 20 mass % with respect to the content of the silica;
(A) a (B) b (C) c (D) d (R 1 ) e SiO (4-2a-b-c-d-e)/2 (1)
formula (1) being an average composition formula, wherein A is a divalent organic group containing a sulfide group; B is a monovalent hydrocarbon group having from 5 to 10 carbon atoms; C is a hydrolyzable group; D is an organic group containing a mercapto group; R 1 is a monovalent hydrocarbon group having from 1 to 4 carbon atoms; and a to e satisfy the relational expressions 0≦a<1, 0≦b<1, 0<c<3, 0<d<1, 0≦e<2, and 0<2a+b+c+d+e<4, and at least one of a and b is not 0.
2. The rubber composition for a tire tread according to claim 1 , wherein a DBP absorption number of the silica is at least 190 ml/100 g, and a ratio of the nitrogen adsorption specific surface area and the CTAB specific surface area (nitrogen adsorption specific surface area/CTAB specific surface area) is from 0.9 to 1.33.
3. The rubber composition for a tire tread according to claim 1 further containing a terpene resin, wherein an amount of the terpene resin is from 1 to 30 parts by mass per 100 parts by mass of the diene rubber, and the terpene resin is an aromatic modified terpene resin having a softening point of from 60 to 150° C.
4. The rubber composition for a tire tread according to claim 1 , wherein b is greater than 0 in formula (1).
5. A pneumatic tire comprising tire treads formed using the rubber composition for a tire tread described in claim 1 .
6. The rubber composition for a tire tread according to claim 2 further containing a terpene resin, wherein an amount of the terpene resin is from 1 to 30 parts by mass per 100 parts by mass of the diene rubber, and the terpene resin is an aromatic modified terpene resin having a softening point of from 60 to 150° C.
7. The rubber composition for a tire tread according to claim 2 , wherein b is greater than 0 in formula (1).
8. The rubber composition for a tire tread according to claim 3 , wherein b is greater than 0 in formula (1).