Rubber composition for tire tread, and pneumatic tire
View Patent ↗A rubber composition contains a diene rubber component containing at least 20 mass % of a modified conjugated diene rubber, a silica, and a silane coupling agent; the modified conjugated diene rubber having at least one modified part and at least one conjugated diene rubber part; the conjugated diene rubber part having a conjugated diene copolymer block and an isoprene block containing from 70 mass % to 100 mass % of isoprene units in each conjugated diene rubber part; the modified part bonding to an end of the conjugated diene rubber part and having a functional group which interacts with the silica; a content of the silica being from 60 to 200 parts by mass per 100 parts by mass of the diene rubber component; the silane coupling agent being a polysiloxane represented by formula (1), (A) a (B) b (C) c (D) d (R 1 ) e SiO (4-2a-b-c-d-e)/2 , and having a content from 1.0 to 20 mass % of the content of the silica.
1. A rubber composition for a tire tread containing a diene rubber component containing at least 20 mass % of a modified conjugated diene rubber, a silica, and a silane coupling agent;
the modified conjugated diene rubber having at least one modified part and at least one conjugated diene rubber part;
the conjugated diene rubber part having a conjugated diene copolymer block and an isoprene block containing from 70 mass % to 100 mass % of isoprene units in each conjugated diene rubber part;
the modified part bonding to an end of the conjugated diene rubber part;
the modified part having a functional group which interacts with the silica;
the silane coupling agent being a polysiloxane represented by the following formula (1):
(A) a (B) b (C) c (D) d (R 1 ) e SiO (4-2a-b-c-d-e)/2 (1)
wherein formula (1) is an average composition formula, and in formula (1), A is a divalent organic group containing a sulfide group; B is a monovalent hydrocarbon group having from 5 to 10 carbon atoms; C is a hydrolysable group; D is an organic group containing a mercapto group R 1 is a monovalent hydrocarbon group having from 1 to 4 carbon atoms; and a to e satify the relational expressions 0<a<1, 0≤b<1, 0<c<3, 0<d<1, 0≤e<2, and 0<2a+b+c+d+e<4;
a content of the silica being from 60 to 200 parts by mass per 100 parts by mass of the diene rubber component; and
a content of the silane coupling agent being from 1.0 to 20 mass % of the content of the silica.
2. The rubber composition for a tire tread according to claim 1 , wherein b is greater than 0 in formula (1).
3. The rubber composition for a tire tread according to claim 1 , wherein the skeleton of the modified part is a polyorganosiloxane.
4. The rubber composition for a tire tread according to claim 1 , wherein a weight average molecular weight of the polysiloxane represented by formula (1) is from 500 to 2,300.
5. The rubber composition for a tire tread according to claim 1 , further comprising a terpene resin, wherein an amount of the terpene resin is from 1 to 30 parts by mass per 100 parts by mass of the diene rubber component, and the terpene resin is an aromatic modified terpene resin having a softening point of from 60 to 150° C.
6. The rubber composition for a tire tread according to claim 1 , wherein a vinyl bond content derived from the isoprene units in the isoprene block is from 5 to 85 mass %.
7. The rubber composition for a tire tread according to claim 1 , wherein the conjugated diene copolymer block is obtained using a conjugated diene monomer (d1) and an aromatic vinyl monomer;
an aromatic vinyl unit content derived from the aromatic vinyl monomer is from 38 to 48 mass % of the conjugated diene rubber; and
a vinyl bond content of the conjugated diene rubber part is from 20 to 35 mol % of the conjugated diene units constituting the conjugated diene rubber part.
8. The rubber composition for a tire tread according to claim 1 , wherein a weight average molecular weight of the modified conjugated diene rubber is from 1,000 to 3,000,000.
9. The rubber composition for a tire tread according to claim 1 , wherein the conjugated diene rubber part has a conjugated diene copolymer block on an end other than the end; and
the modified conjugated diene rubber has the isoprene block between the conjugated diene copolymer block and the modified part.
10. The rubber composition for a tire tread according to claim 9 , wherein a weight average molecular weight of the modified conjugated diene rubber is from 600,000 to 1,000,000.
11. The rubber composition for a tire tread according to claim 1 , wherein the conjugated diene rubber part has the isoprene block on an end other than the end; and
the modified conjugated diene rubber has the isoprene block between the conjugated diene copolymer block and the modified part.
12. The rubber composition for a tire tread according to claim 1 , wherein the functional group is at least one selected from the group consisting of an epoxy group and a hydrocarbyloxysilyl group.
13. A pneumatic tire having tire treads formed using the rubber composition for a tire tread described in claim 1 .