IP Library Granted Patent US 10,535,443
Granted Patent B2
US 10,535,443 · App. 14/773,013 · Granted Jan 14, 2020

Graphene entrainment in a host

Inventors: Richard Stoltz (Plano, TX); Jeff Bullington (Orlando, FL)
Assignee: Garmor Inc.
H01B1/04C01B32/182
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Quick Facts
Patent No.
US 10,535,443
App. No.
14/773,013
Granted
Jan 14, 2020
Kind
B2
Abstract

This is generally a method of producing graphene-containing suspensions of flakes of high quality graphene/graphite oxides and method of producing graphene/graphite oxides. Both the exfoliating graphite into flakes and oxidizing the graphite flakes and the preparation and suspension of the flakes can be done with high volume production and at a low cost.

Claims (15)

1. A method of making a graphene suspension, comprising:

preparing graphene flakes with a surface area to thickness ratio greater than 300 Angstroms, and thickness of less than 160 Angstroms, without concentrated acid, wherein the graphene flakes are planar, have no physical distortions or corrugations, have only edge oxidation, and have a surface polarity;

suspending said graphene flakes in a fluid by mixing until the suspension is substantially uniform; and

wherein the graphene flakes have an oxidization greater than or equal to 1% and less than 5%.

2. The method of claim 1 , wherein 95% of the flakes are from about 0.8 to 16 nanometers in thickness.

3. The method of claim 1 , wherein 95% of the flakes have the surface area to thickness ratio greater than 300 Angstroms.

4. The method of claim 1 , wherein a maximum dimension of the graphene flakes is between 220 Angstroms and 100 microns.

5. The method of claim 1 , wherein the method outputs are substantially limited to flat graphene flakes and water.

6. A graphene suspension made by a method comprising:

preparing graphene flakes with a surface area to thickness ratio greater than 300 Angstroms, and thickness of less than 160 Angstroms, without concentrated acid, wherein the graphene flakes are planar, have no physical distortions or corrugations, have only edge oxidation, and have a surface polarity;

suspending said graphene flakes in a fluid by mixing until the suspension is substantially uniform; and

wherein the graphene flakes have an oxidization of greater than or equal to 1% and less than 5%.

7. The method of claim 6 , wherein 95% of the flakes are from about 0.8 to 16 nanometers in thickness.

8. The method of claim 6 , wherein 95% of the flakes have the surface area to thickness ratio greater than 300 Angstroms.

9. The method of claim 6 , wherein a maximum dimension of the graphene flakes is between 220 Angstroms and 100 microns.

Assignments (6)
SECURITY AGREEMENT Recorded Mar 27, 2023
From: ASBURY GRAPHITE OF NORTH CAROLINA, INC.; ASBURY CARBONS, INC.; PEC FRICTION FIGHTERS CORPORATION
To: PNC BANK, NATIONAL ASSOCIATION, AS AGENT
Reel/Frame 063169/0025 →
CORRECTIVE ASSIGNMENT TO CORRECT THE DELETE PATENT APPLICATIONS 15554974, 62899396, & 17012913 (974 ONLY LICENSED & 396 & 913 JIONLY OWNED WITH ANOTHER). PREVIOUSLY RECORDED AT REEL: 057306 FRAME: 0139. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Dec 15, 2022
From: GARMOR, INC.
To: ASBURY GRAPHITE OF NORTH CAROLINA, INC.
Reel/Frame 062248/0807 →
RELEASE OF SECURITY INTEREST Recorded Oct 12, 2021
From: ASBURY CARBONS, INC.
To: GARMOR, INC.
Reel/Frame 057763/0871 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 27, 2021
From: GARMOR, INC.
To: ASBURY GRAPHITE OF NORTH CAROLINA, INC.
Reel/Frame 057306/0139 →
SECURITY INTEREST Recorded Mar 29, 2021
From: GARMOR, INC.
To: ASBURY CARBONS, INC.
Reel/Frame 055757/0308 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 17, 2015
From: BULLINGTON, JEFF; STOLTZ, RICHARD
To: GARMOR, INC.
Reel/Frame 036629/0814 →
Continuity (8)
Provisional Application 61775024 · Mar 8, 2013
Provisional Application 61775071 · Mar 8, 2013
Provisional Application 61775087 · Mar 8, 2013
Provisional Application 61775099 · Mar 8, 2013
Provisional Application 61775113 · Mar 8, 2013
Provisional Application 61788247 · Mar 15, 2013
Related Publication 20160016803A1 · Jan 21, 2016
Related Publication 20170152147A9 · Jun 1, 2017