Hydrocarbon reforming/trapping material and method for removing hydrocarbon
To provide a hydrocarbon reforming/trapping material which is capable of adsorbing and reforming a hydrocarbon. A hydrocarbon reforming/trapping material of the present invention has an SiO 2 /Al2O 3 ratio of from 7 to 12, and contains an Fe(II)-substituted beta zeolite which is ion-exchanged by Fe(II) ions. The amount of supported Fe(II) is preferably 0.001-0.5 mmol/g with respect to the Fe(II)-substituted beta zeolite. This Fe(II)-substituted beta zeolite is suitably produced by dispersing and mixing a beta zeolite having an SiO 2 /Al 2 O 3 ratio of from 7 to 12 in an aqueous solution of a water-soluble compound of divalent iron, and mixing and stirring the solution, so that Fe(II) ions are supported on the beta zeolite.
1. A hydrocarbon reforming/trapping material comprising an Fe(II)-substituted beta zeolite which is produced by a method comprising the step of ion-exchanging a beta zeolite with Fe(II) ions alone, where an SiO 2 /Al 2 O 3 ratio is from 7 to 12,
wherein the Fe(II)-substituted beta zeolite has a BET specific surface area of 300 to 600 m 2 /g, a micropore specific surface area of 270 to 500 m 2 /g, and a micropore volume of 0.14 to 0.25 cm 3 /g, the Fe(II)-substituted beta zeolite comprises ferric oxide (III) on the surface thereof, and
the Fe(II)-substituted beta zeolite is a beta zeolite obtained by ion exchanging with Fe(II) ions a beta zeolite produced by using a reaction mixture which does not include a structure-directing agent.
2. A hydrocarbon reforming/trapping material according to claim 1 , wherein a supported amount of Fe(II) is 0.001 to 0.5 mmol/g with respect to the Fe(II)-substituted beta zeolite.
3. A hydrocarbon reforming/trapping material according to claim 1 , wherein, as a beta zeolite before being ion-exchanged with Fe(II) ions, a beta zeolite having a SiO 2 /Al 2 O 3 ratio from 7 to 12 is used.
4. A hydrocarbon reforming/trapping material according to claim 2 , wherein, as a beta zeolite before being ion-exchanged with Fe(II) ions, a beta zeolite having a SiO 2 /Al 2 O 3 ratio from 7 to 12 is used.
5. A hydrocarbon reforming/trapping material according to claim 1 , comprising lithium ions.
6. A hydrocarbon reforming/trapping material according to claim 2 , comprising lithium ions.
7. A hydrocarbon reforming/trapping material according to claim 3 , comprising lithium ions.
8. A hydrocarbon reforming/trapping material according to claim 4 , comprising lithium ions.
9. A method of removing a hydrocarbon, comprising contacting an Fe(II)-substituted beta zeolite which has been ion-exchanged with Fe(II) ions and where an SiO 2 /Al 2 O 3 ratio is from 7 to 12, with a hydrocarbon or a gas comprising a hydrocarbon, so that the hydrocarbon is adsorbed on the Fe(II)-substituted beta zeolite, and
heating the Fe(II)-substituted beta zeolite on which the hydrocarbon is adsorbed under the presence of oxygen, so that the Fe(II)-substituted beta zeolite reforms and removes the hydrocarbon.
10. A method of removing a hydrocarbon according to claim 9 , wherein the hydrocarbon is emitted from an internal combustion engine.
11. A method of removing a hydrocarbon according to claim 10 , wherein the hydrocarbon comprises toluene, and the toluene is reformed to carbon dioxide and removed.