Positive electrode for non-aqueous electrolyte secondary battery and non-aqueous electrolyte secondary battery using the same
View Patent ↗[Object] Provided is a means for improving cycle characteristics by suppressing electrode deterioration resulting from non-uniformity of voltage across an electrode plane in a high-capacity and large-area non-aqueous electrolyte secondary battery that includes lithium nickel-based composite oxide as a positive electrode active substance. [Solving Means] Disclosed is a positive electrode for a non-aqueous electrolyte secondary battery used in a non-aqueous electrolyte secondary battery in which the ratio value of battery area (projected area of the battery including the battery outer casing body) to rated capacity is 5 cm 2 /Ah or more and the rated capacity is 3 Ah or more, the positive electrode comprising a positive electrode current collector and a positive electrode active substance layer that is formed on a surface of the positive electrode current collector and has a positive electrode active substance containing a lithium nickel-based composite oxide and a spinel type lithium manganese composite oxide, in which, when the average secondary particle diameter (D50) of the lithium nickel-based composite oxide is D50(A) [μm], the content ratio of the lithium nickel-based composite oxide in the positive electrode active substance layer is A [% by mass], the average secondary particle diameter (D50) of the spinel type lithium manganese composite oxide is D50(B) [μm], and the content ratio of the spinel type lithium manganese composite oxide in the positive electrode active substance layer is B [% by mass], the positive electrode satisfies the following Mathematical Formula 1 and Mathematical Formula 2: [Math. 1] 2.0< D 50( A )/ D 50( B )≦15 Mathematical Formula 1 B /( A+B )≧0.05 Mathematical Formula 2.
1. A non-aqueous electrolyte secondary battery comprising:
a power generating element including a positive electrode, a negative electrode, and a separator, the positive electrode comprising:
a positive electrode current collector; and
a positive electrode active substance layer that is formed on a surface of the positive electrode current collector and has a positive electrode active substance containing a lithium nickel-based composite oxide and a spinel type lithium manganese composite oxide,
wherein the positive electrode satisfies the following:
2.0 <D 50( A )/ D 50( B )≦15, and
B /( A+B )≧0.05,
where an average secondary particle diameter of the lithium nickel-based composite oxide is D50(A) [μm], a content ratio of the lithium nickel-based composite oxide in the positive electrode active substance layer is A [% by mass], an average secondary particle diameter of the spinel type lithium manganese composite oxide is D50(B) [μm], and a content ratio of the spinel type lithium manganese composite oxide in the positive electrode active substance layer is B [% by mass];
wherein a ratio value of a battery area to a rated capacity of the non-aqueous electrolyte secondary battery is 5 cm 2 /Ah or more, the battery area being a projected area of the non-aqueous electrolyte secondary battery including a battery outer casing body, and the rated capacity of the non-aqueous electrolyte secondary battery is 3 Ah or more; and
wherein the spinel type lithium manganese composite oxide is LiMn 2 O 4 .
2. The non-aqueous electrolyte secondary battery according to claim 1 , wherein the lithium nickel-based composite oxide has a composition represented by a general formula Li a Ni b Mn c Co d M x O 2 ,
wherein a, b, c, d, and x satisfy the following:
0.9≦a≦1.2,
0<b<1,
0<c≦0.5,
0<d≦0.5,
0≦x≦0.3, and
b+c+d =1, and
wherein M represents at least one element selected from the group consisting of Ti, Zr, Nb, W, P, Al, Mg, V, Ca, Sr, and Cr.
3. The non-aqueous electrolyte secondary battery according to claim 2 , wherein b, c and d satisfy the following:
0.44≦b≦0.51,
0.27≦c≦0.31, and
0.19≦d≦0.26.
4. The non-aqueous electrolyte secondary battery according to claim 1 , wherein the positive electrode active substance layer has a rectangular shape and an aspect ratio of an electrode defined as a longitudinal/transversal ratio of a rectangular-shaped positive electrode active substance layer is 1 to 3.
5. The non-aqueous electrolyte secondary battery according to claim 1 , wherein the separator has a heat resistant insulating layer.
6. The non-aqueous electrolyte secondary battery according to claim 1 , wherein the non-aqueous electrolyte secondary battery is a flat stack type laminate battery in which the power generating element is enclosed in the battery outer casing body which is formed of a laminate film containing aluminum.