Battery, electrolyte layer, battery pack, electronic apparatus, electric vehicle, power storage device, and electric power system
A gel electrolyte layer is provided between a positive electrode and a second electrode. The gel electrolyte layer is a layer containing particles, a resin material, and a polymer compound for retaining the resin material, and having a heat capacity per unit area of 0.0001 J/Kcm 2 or more and a heat capacity per unit volume of 3.0 J/Kcm 3 or less.
1. A battery comprising:
a positive electrode;
a negative electrode; and
an electrolyte layer disposed between the positive electrode and the negative electrode,
wherein the electrolyte layer is formed from (i) a gel-like electrolyte containing heat absorbent particles, a liquid electrolyte, and a resin material for retaining the liquid electrolyte, or (ii) a solid electrolyte containing the heat absorbent particles,
wherein a mass ratio of the heat absorbent particles and the resin material is in the range of 20:80 to 80:20,
wherein the electrolyte layer has a heat capacity per unit volume of 0.4 J/Kcm 3 or less and a heat capacity per unit area of 0.0002 J/Kcm 2 or more, and
wherein the heat absorbent particles have a specific heat capacity of 0.5 J/gK or more and a melting point of 1000° C. or higher,
wherein the heat absorbent particles comprise a silicic acid salt and wherein the silicic acid salt is at least one selected from a nesosilicate mineral, a sorosilicate mineral, a cyclosilicate mineral, an inosilicate mineral, a tectosilicate mineral, an asbestos, a sepiolite, and an imogolite, and
wherein the heat absorbent particles have an anisotropic shape,
wherein the ratio of the length of the longest part of the heat absorbent particle and the length of the shortest part of the heat absorbent particle in a direction perpendicular to the longest part (“length of the shortest part”/{length of the shortest part}) is 3 times or more.
2. The battery according to claim 1 , further comprising a separator provided between the positive electrode and the negative electrode, wherein the electrolyte layer is disposed at least one of between the positive electrode and the separator, and between the negative electrode and the separator.
3. The battery according to claim 1 , wherein the heat absorbent particles are present in a dispersed state in the electrolyte layer.
4. The battery according to claim 1 , wherein the heat absorbent particles further comprise one or more of alumina, boehmite, yttrium oxide, titanium oxide, magnesium oxide, zirconium oxide, silicon oxide, zinc oxide, aluminum nitride, boron nitride, silicon nitride, titanium nitride, silicon carbide, boron carbide, barium titanate, strontium titanate, barium sulfate, a silicic acid salt, Li 2 O 4 , Li 3 PO 4 , LiF, aluminum hydroxide, graphite, carbon nanotubes, and diamond.
5. The battery according to claim 1 , wherein the tectosilicate mineral is a zeolite.
6. The battery according to claim 1 , wherein at least one of the melting point and the glass transition temperature of the resin material is 180° C. or higher.
7. The battery according to claim 6 , wherein the resin material is polyvinylidene fluoride.
8. The battery according to claim 1 , wherein a negative electrode active material included in the negative electrode is formed from a material containing at least one of a metal element and a semimetal element as a constituent element.
9. A battery pack comprising: the battery according to claim 1 ; a control unit controlling the battery; and an exterior material enclosing the battery.
10. An electronic apparatus comprising the battery according to claim 1 , and receiving the supply of electric power from the battery.
11. An electric vehicle comprising: the battery according to claim 1 , a conversion device receiving the supply of electric power from the battery and converting the electric power to the driving force for the vehicle; and a control device performing information processing in connection with the vehicle control, based on information on the battery.
12. A power storage device comprising the battery according to claim 1 , wherein the power storage device is configured to supply electric power to an electronic apparatus connected to the battery.
13. The power storage device according to claim 12 , comprising an electric power information control device configured to transmit and receive signals to and from another apparatus through a network, and perform charge-discharge control of the battery based on information received by the electric power information control device.
14. An electric power system configured to receive the supply of electric power from the battery according to claim 1 , or supply electric power from a power generation device or an electric power network to the battery.
15. The battery according to claim 1 , wherein the nesosilicate mineral is one or both of olivine and mullite.
16. The battery according to claim 1 , wherein the anisotropic shape comprises one or more of a needle shape particle, a scaly shape particle, and a sheet shape particle.
17. The battery according to claim 1 , wherein the heat absorbent particles comprise primary particles having an average particle size of 0.3 μm or more.
18. The battery according to claim 1 , wherein the heat absorbent particles comprise primary particles having an average particle size of 1.0 μm or less.
19. The battery according to claim 1 , wherein the heat absorbent particles comprise primary particles having an average particle size in the range of 0.3 μm to 0.8 μm.
20. The battery according to claim 1 , wherein the heat absorbent particles comprise first primary particles having an average particle size in the range of 0.3 μm to 0.8 μm, and second primary particles having an average particle size in the range of 1.0 μm to 10 μm.
21. The battery according to claim 1 , wherein the heat absorbent particles comprise first primary particles having an average particle size in the range of 0.3 μm to 0.8 μm, and third primary particles having an average particle size in the range of 0.01 μm to 0.10 μm.
22. The battery according to claim 1 , wherein a heat capacity per unit area of 0.0015 J/Kcm 2 or less.
23. An electrolyte layer formed from (i) a gel-like electrolyte containing heat absorbent particles, a liquid electrolyte, and a resin material for retaining the liquid electrolyte, or from (ii) a solid electrolyte containing the heat absorbent particles,
wherein a mass ratio of the heat absorbent particles and the resin material is in the range of 20:80 to 80:20, the electrolyte layer has a heat capacity per unit volume of 0.4 J/Kcm 3 or less and a heat capacity per unit area of 0.0002 J/Kcm 2 or more, and the heat absorbent particles have a specific heat capacity of 0.5 J/gK or more and a melting point of 1000° C. or higher,
wherein the heat absorbent particles comprise a silicic acid salt and wherein the silicic acid salt is one or more of a nesosilicate mineral, a sorosilicate mineral, a cyclosilicate mineral, an inosilicate mineral, a tectosilicate mineral, an asbestos, a sepiolite, and an imogolite, and
wherein the heat absorbent particles have an anisotropic shape,
wherein the ratio of the length of the longest part of the heat absorbent particle and the length of the shortest part of the heat absorbent particle in a direction perpendicular to the longest part (“length of the shortest part”/{length of the shortest part}) is 3 times or more.