Laminated porous membrane, process for manufacturing same and separator for battery
View Patent ↗A laminated porous membrane includes a polyolefin porous membrane, on one surface of which projections that are made of a polyolefin and satisfy 5 μm≤W≤50 μm (W: projection size) and 0.5 μm≤H (H: projection height) are irregularly scattered at a density of 3/cm 2 to 200/cm 2 , and a modifying porous layer laminated on the surface of the polyolefin porous membrane having the projections, wherein the modifying porous layer includes a binder with a tensile strength of at least 5 N/mm 2 and inorganic particles.
1. A laminated porous membrane, comprising:
a polyolefin porous membrane, on one surface of which projections that are made of a polyolefin and satisfy 5 μm≤W≤50 μm (W: projection size) and 0.5 μm≤H≤3.0 μm (H: projection height) are irregularly and without periodicity scattered at a density of 3/cm 2 to 200/cm 2 , wherein the projections are not formed by embossing, and
a modifying porous layer laminated on the surface of the polyolefin porous membrane having the projections, wherein the modifying porous layer comprises a binder with a tensile strength of at least 5 N/mm 2 and inorganic particles.
2. The laminated porous membrane according to claim 1 , wherein the binder is polyvinyl alcohol or an acrylic resin.
3. The laminated porous membrane according to claim 1 , wherein the inorganic particles comprise at least one selected from the group consisting of calcium carbonate, alumina, titania, barium sulfate, and boehmite.
4. A battery separator comprising the laminated porous membrane according to claim 1 .
5. A method of producing the laminated porous membrane according to claim 1 , comprising:
(a) adding a molding solvent to a polyethylene resin, and then performing melt blending to prepare a polyethylene resin solution;
(b) extruding the polyethylene resin solution through a die, and cooling the extruded polyethylene resin solution with a chill roll having a surface from which the molding solvent has been removed to form a gel-like molding;
(c) stretching the gel-like molding in the machine direction and the transverse direction to provide a stretched molding;
(d) extracting the molding solvent away from the stretched molding, followed by drying to provide a porous molding;
(e) heat-treating the porous molding to provide a polyolefin porous membrane; and,
(f) forming a laminated membrane on a surface that has been in contact with the chill roll using a coating liquid comprising a binder with a tensile strength of at least 5 N/mm 2 , inorganic particles, and a solvent that is capable of dissolving or dispersing the binder, followed by drying.
6. The method of producing the laminated porous membrane according to claim 5 , wherein the means for removing the molding solvent in the step (b) is a doctor blade.