RFeB system magnet production method, RFeB system magnet, and coating material for grain boundary diffusion treatment

1. An RFeB system magnet production method for producing an R L 2 Fe 14 B system magnet which is a sintered magnet or a hot-deformed magnet containing, as a main rare-earth element, a light rare-earth element R L which is at least one of two elements of Nd and Pr, the method comprising steps of:

applying, to a surface of a base material of the R L 2 Fe 14 B system magnet, a coating material prepared by mixing a silicone grease and an R H -containing powder containing a heavy rare-earth element R H composed of at least one element selected from a group of Dy, Tb and Ho; and

heating the base material together with the coating material, wherein: the RFeB system magnet has a thickness of 5.5 mm or less; Tb content at a position in the RFeB system magnet is higher as the position is closer to a surface of the RFeB system magnet; and a difference between the maximum and the minimum in a coercivity at positions in the RFeB system magnet is 1 kOe or less.

2. The RFeB system magnet production method according to claim 1 , wherein a dispersant for enhancing dispersibility of the R H -containing powder is added to the coating material.

3. The RFeB system magnet production method according to claim 2 , wherein the dispersant contains fatty ester as a main component.

4. The RFeB system magnet production method according to claim 3 , wherein the dispersant contains at least one of following compounds as the main component: methyl caprylate, methyl caprate, methyl laurate, methyl myristate, ethyl caprylate, ethyl caprate, ethyl laurate, and ethyl myristate.

5. The RFeB system magnet production method according to claim 1 , wherein a silicone oil having a lower viscosity than the silicone grease is added to the coating material.

6. The RFeB system magnet production method according to claim 1 , wherein the R H -containing powder is a powder of R H —Ni—Al alloy.

7. The RFeB system magnet production method according to claim 1 , wherein a screen having a permeable area for allowing the coating material to pass through is brought into contact with the surface of the base material and the coating material is applied through the permeable area to the surface of the base material.

8. An RFeB system magnet having a main phase made of R 2 Fe 14 B containing a rare-earth R, iron Fe and boron B, satisfying a following relationship:

0<x 1≤ 0.5, 0≤x 2 , and

H cJ≥ 20.8 ×x 1 +2 ×x 2 +14.7  (1)

where x 1 and x 2 respectively represent weight percentages of Tb and Dy, and H cJ represents coercivity in kOe at room temperature, wherein:

the RFeB system magnet has a thickness of 5.5 mm or less;

Tb content at a position in the RFeB system magnet is higher as the position is closer to a surface of the RFeB system magnet; and

a difference between the maximum and the minimum in a coercivity at positions in the RFeB system magnet is 1 kOe or less.

9. An RFeB system magnet having a main phase made of R 2 Fe 14 B containing a rare-earth R, iron Fe and boron B, satisfying a following relationship:

when 0<x 2≤ 0.7

H cJ ≥8.6 ×x 2 +14  (2)

and when 0.7<x 2

H cJ ≥2 ×x 2 +18.6  (3)

where x 2 represents a weight percentage of Dy, and H cJ represents coercivity in kOe at room temperature, wherein: the RFeB system magnet has a thickness of 5.5 mm or less; Tb content at a position in the RFeB system magnet is higher as the position is closer to a surface of the RFeB system magnet; and a difference between the maximum and the minimum in a coercivity at positions in the RFeB system magnet is 1 kOe or less.