Secondary battery charge status estimation device and secondary battery charge status estimation method
Charge state estimation device includes: current/voltage acquiring unit for acquiring a charge/discharge current value and inter-terminal voltage value of secondary battery; combined current calculating unit for calculating a combined current value from the charge/discharge current value acquired at a time t; estimation time setting unit for setting, as an estimation time for charge state estimation, the time at which the combined current value exists within a predetermined threshold range; internal resistance estimating unit for estimating the internal resistance value of secondary battery on the basis of the inter-terminal voltage values and charge/discharge current values of secondary battery at the estimation time T and at sampling time before the estimation time; and charge state estimating unit for estimating the open circuit voltage value and charge state value of the secondary battery on the basis of the inter-terminal voltage value of secondary battery at the estimation time and the internal resistance value.
1. A charge state estimation device of a secondary battery for estimating a charge state value SOC of the secondary battery repeatedly charged and discharged in a short time, the charge state estimation device comprising:
a current/voltage acquiring unit for acquiring a charge or discharge current value and an inter-terminal voltage value of the secondary battery at a predetermined sampling time interval;
a combined current calculating unit for calculating, by a predetermined current combining method, a combined current value Iw(t) from the charge or discharge current value I(t) acquired at a time t in consideration of a charge or discharge state before the time t;
an estimation time setting unit for setting, as an estimation time for charge state estimation, a time t=T at which the combined current value Iw(t) exists within a predetermined threshold range;
an internal resistance estimating unit for estimating an internal resistance value R of the secondary battery based on the inter-terminal voltage value V(T) and the charge or discharge current value I(T) of the secondary battery at the estimation time T and the inter-terminal voltage value V(T−n) and the charge or discharge current value I(T−n) of the secondary battery at a sampling time (T−n) before the estimation time T, the n being a natural number of 1 or more; and
a charge state estimating unit for estimating an open circuit voltage value Voc of the secondary battery based on the inter-terminal voltage value V(T) of the secondary battery at the estimation time T and the internal resistance value R, and estimating the charge state value SOC of the secondary battery based on a Voc-SOC relation showing a relationship between the previously determined open circuit voltage value Voc and the charge state value SOC.
2. The charge state estimation device of the secondary battery according to claim 1 , wherein
the combined current calculating unit calculates the combined current value from Iw(t)=αI(t)+(1−α)Iw(T−n) using a predetermined combination coefficient α, the Iw(t) shows the combined current value at the time t, and the Iw(T−n) shows the combined current value at the sampling time (T−n) before the estimation time T.
3. The charge state estimation device of the secondary battery according to claim 2 , wherein
the combination coefficient α is set based on a charge or discharge characteristic of the secondary battery.
4. The charge state estimation device of the secondary battery according to claim 1 , further comprising
a capacity variation estimating unit for estimating a capacity variation value from a charge or discharge state value in an initial state of the secondary battery based on the plurality of charge state values SOC at different charge or discharge operation times.