IP Library Granted Patent US 9,745,471
Granted Patent B2
US 9,745,471 · App. 14/780,283 · Granted Aug 29, 2017

Prepreg, fiber-reinforced composite material, and resin composition containing particles

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Quick Facts
Patent No.
US 9,745,471
App. No.
14/780,283
Granted
Aug 29, 2017
Kind
B2
Abstract

A prepreg 10 comprises: a reinforcing fiber layer 3 including reinforcing fibers 1 and a resin composition 2 with which the space between fibers of the reinforcing fibers 1 is impregnated and which contains (A) a benzoxazine resin, (B) an epoxy resin, and (C) a curing agent having 2 or more phenolic hydroxy groups in a molecule; and a surface layer 6 a or 6 b provided on at least one surface of the reinforcing fiber layer 3 and containing (A) a benzoxazine resin, (B) an epoxy resin, (C) a curing agent having 2 or more phenolic hydroxy groups in a molecule, and (D) polyamide resin particles 4 having an average particle size of 5 to 50 μm, wherein the polyamide resin particles 4 include a particle made of a polyamide 11.

Claims (15)

1. A fiber-reinforced composite material obtained by stacking a prepreg plurally and performing heating under increased pressure, wherein the prepreg comprises:

a reinforcing fiber layer including

reinforcing fibers and

a resin composition with which the space between fibers of the reinforcing fibers is impregnated and which contains

(A) a benzoxazine resin,

(B) an epoxy resin, and

(C) a curing agent having 2 or more phenolic hydroxy groups in a molecule; and

a surface layer provided on at least one surface of the reinforcing fiber layer and containing

(A) a benzoxazine resin,

(B) an epoxy resin,

(C) a curing agent having 2 or more phenolic hydroxy groups in a molecule, and

(D) polyamide resin particles having an average particle size of 5 to 50 μm,

wherein the polyamide resin particles include a particle made of a polyamide 11 ,

wherein the volume proportion of C 1 in the total amount of the C 1 , which is the amount of the polyamide resin contained in a resin cured substance between the reinforcing fiber layers, and C 2 , which is the amount of the polyamide resin contained in the reinforcing fiber layers ({C 1 /(C 1 +C 2 )}×100), is 70 volume % or more, and

wherein the surface layer contains 65 to 80 parts by mass of the (A) component, 20 to 35 parts by mass of the (B) component, 5 to 20 parts by mass of the (C) component, and 15 to 45 parts by mass of the (D) component when it is assumed that the total amount of the (A) component and the (B) component is 100 parts by mass.

Assignments (5)
CHANGE OF NAME Recorded Oct 15, 2024
From: ENEOS CORPORATION
To: ENEOS MATERIALS CORPORATION
Reel/Frame 069167/0100 →
CHANGE OF NAME Recorded Sep 11, 2020
From: JXTG NIPPON OIL & ENERGY CORPORATION
To: ENEOS CORPORATION
Reel/Frame 054295/0001 →
CHANGE OF NAME Recorded Jun 15, 2018
From: JX NIPPON OIL & ENERGY CORPORATION
To: JXTG NIPPON OIL & ENERGY CORPORATION
Reel/Frame 046634/0132 →
CHANGE OF NAME Recorded May 12, 2017
From: FUJI JUKOGYO KABUSHIKI KAISHA
To: SUBARU CORPORATION
Reel/Frame 042624/0886 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 17, 2015
From: FUKUDA, YOSHIHIRO; MATSUMOTO, TAKAYUKI; MINAMI, MASAKI; SEKINE, NAOYUKI; NAKAJIMA, MASANORI
To: JX NIPPON OIL & ENERGY CORPORATION; FUJI JUKOGYO KABUSHIKI KAISHA
Reel/Frame 037060/0841 →