Method for producing lubricant oil base oil
View Patent ↗A method for producing a lubricating base oil, comprising: performing a 13 C-NMR analysis regarding an oil to be treated and selecting the oil based on a value for dividing an integrated value of a peak for a tertiary carbon atom by an integrated value of all peaks at 0 to 50 ppm, a value for dividing an integrated value of a peak for a carbon atom constituting a main chain by the integrated value of all peaks at 0 to 50 ppm, and a value for dividing an integrated value of a peak for a branched CH 3 bonded to a fifth or the following carbon atom from a terminal carbon atom in the main chain by an integrated value of all peaks at 10 to 25 ppm, and obtaining a dewaxed oil by isomerization dewaxing of the oil selected in the first step, is disclosed.
1. A method for producing a lubricating base oil, the method comprising:
a first step of performing a 13 C-NMR analysis with respect to an oil to be treated containing a normal paraffin and an isoparaffin, and selecting the oil to be treated based on the following index values (1), (2) and (3) in an obtained 13 C-NMR spectrum,
index value (1): a value obtained by dividing an integrated value of a peak assigned to a tertiary carbon atom by an integrated value of all peaks at 0 to 50 ppm,
index value (2): a value obtained by dividing an integrated value of a peak assigned to a carbon atom constituting a hydrocarbon main chain by the integrated value of all peaks at 0 to 50 ppm, and
index value (3): a value obtained by dividing an integrated value of a peak assigned to a branched CH 3 bonded to a fifth carbon atom or a carbon atom on an inner side thereof from a terminal carbon atom in the hydrocarbon main chain by an integrated value of all peaks at 10 to 25 ppm; and
a second step of obtaining a dewaxed oil by isomerization dewaxing of the oil to be treated selected in the first step, wherein
the first step is a step of selecting the oil to be treated having the index value (1) of 0.01 to 0.1, the index value (2) of 0.2 to 0.6, and the index value (3) of 0.05 to 0.2, and
the second step is a step of performing isomerization dewaxing of the oil to be treated selected in the first step at a reaction temperature of 280 to 360° C.
2. The method according to claim 1 , wherein
the first step is a step of selecting the oil to be treated having the index value (1) of 0.01 to 0.08, the index value (2) of 0.25 to 0.55, and the index value (3) of 0.05 to 0.18.
3. The method according to claim 1 , wherein
the second step is a step of performing isomerization dewaxing of the oil to be treated selected in the first step at a reaction temperature of 300 to 340° C.
4. The method according to claim 1 , wherein
the oil to be treated is selected based on additional index values (4) and (5):
index value (4): an average carbon number determined from a gas chromatography analysis of the oil to be treated, and
index value (5): a product of the index value (2) and the index value (4) of the oil to be treated,
wherein the oil to be treated selected in the first step has the index value (4) of from 23 to less than 29, and the index value (5) of from 5 to 19.
5. The method according to claim 1 , wherein
the oil to be treated is selected based on additional index values (4) and (5):
index value (4): an average carbon number determined from a gas chromatography analysis of the oil to be treated, and
index value (5): a product of the index value (2) and the index value (4) of the oil to be treated,
wherein the oil to be treated selected in the first step has the index value (4) of from 31 to less than 35, and the index value (5) of from 8 to 25.