Rubber composition, vulcanized rubber, and tire
The invention relates to a rubber composition having a good processability, and simultaneously having a rolling resistance performance and hardness after vulcanization at high levels, with which the contamination of the mold for processing due to the bleeding-out of the plasticizer can be suppressed, and in which the migration of the plasticizer and so on is suppressed to a low level; a vulcanized rubber obtained by vulcanizing the rubber composition; and to a tire including the rubber composition as at least a part thereof. The rubber composition contains 100 parts by mass of rubber component (A) composed of at least one of a synthetic rubber and a natural rubber, 0.1 to 50 parts by mass of a diene polymer (B), 20 to 150 parts by mass of a filler (C), 0.1 to 10 parts by mass of a vulcanizing agent (D), 0.1 to 15 parts by mass of a vulcanization accelerator (E) and 0.1 to 15 parts by mass of vulcanization aid (F).
1. A vulcanized rubber obtained by vulvanizing a rubber composition, comprising:
100 parts by mass of rubber component (A) comprising at least one of a synthetic rubber and a natural rubber;
0.1 to 50 parts by mass of a diene polymer (B);
20 to 150 parts by mass of a filler (C) which comprises silica;
0.1 to 10 parts by mass of a vulcanizing agent (D);
0.1 to 15 parts by mass of a vulcanization accelerator (E); and
0.1 to 15 parts by mass of vulcanization aid (F),
wherein
the polymer (B) is a polyisoprene having no functional group,
a melt viscosity of the diene polymer (B) at 38° C. is from 0.1 Pa·s to 3,000 Pa·s,
a vulcanization rate (t90) of the diene polymer (B) measured under the measuring conditions below is 25 minutes or less:
the measuring conditions being:
To 100 parts by mass of the diene polymer (B), 70 parts by mass of carbon black of ASTM N330, 3.5 parts by mass of zinc oxide, 2 parts by mass of stearic acid, 1.5 parts by mass of sulfur, 1.2 parts by mass of N-(tert-butyl)-2-benzothiazole sulfenamide and 1 part by mass of N-phenyl-N′-(1,3-dimethylbutyl)-p-phenylenediamine are added, and a torque at 140° C. is measured using an oscillating type curemeter and vulcanization time to reach 90% vulcanization degree is measured, and
wherein an extraction ratio of the polymer (B) contained in the vulcanized rubber when 2 g of the vulcanized rubber is extracted with 400 mL of toluene at 23° C. for 48 hours is 20% by mass or less.
2. The vulcanized rubber according to claim 1 , wherein the diene polymer (B) has a weight average molecular weight (Mw) of 2,000 to 100,000.
3. The vulcanized rubber according to claim 1 , wherein the diene polymer (B) has a glass transition temperature of −100 to 0° C.
4. The vulcanized rubber according to claim 1 , wherein the filler (C) further comprises carbon black.
5. The vulcanized rubber according to claim 1 , wherein the rubber component (A) comprises at least one synthetic rubber selected from the group consisting of a styrene butadiene rubber, a butadiene rubber and an isoprene rubber.
6. The vulcanized rubber according to claim 5 , wherein the rubber component (A) comprises a styrene butadiene rubber having a weight average molecular weight (Mw) of 100,000 to 2,500,000.
7. The vulcanized rubber according to claim 5 , wherein the rubber component (A) comprises a styrene butadiene rubber having a styrene content of 0.1 to 70% by mass.
8. The vulcanized rubber according to claim 5 , wherein the rubber component (A) comprises a butadiene rubber which has a weight average molecular weight (Mw) of 90,000 to 2,000,000.
9. The vulcanized rubber according to claim 5 , wherein the rubber component (A) comprises a butadiene rubber which has a vinyl content of 50% by mass or less.
10. A tire, comprising the vulcanized rubber of claim 1 .
11. The vulcanized rubber according to claim 1 , wherein the diene polymer (B) is a liquid polymer.