TREATMENT OF TAILINGS STREAMS
This disclosure relates to a process for treating a tailings stream comprising water and solids. The process involves (a) contacting a gelling agent and an activator with the tailings stream, (b) entrapping the solids within a gel produced from the gelling agent, and (c) depositing the gel into a liquid. This disclosure also relates to a process for treating a tailings stream comprising water and solids beneath a liquid surface. The process involves (a) contacting a gelling agent and an activator with the tailings stream beneath the liquid surface, (b) entrapping the solids within a gel produced from the gelling agent.
1 . A process for treating a tailings stream comprising water and solids, comprising: (a) contacting a gelling agent and an activator with the tailings stream, (b) entrapping the solids within a gel produced from the gelling agent, and (c) depositing the gel into a liquid.
2 . A process according to claim 1 , further comprising contacting a reinforcing agent with the tailings stream in step (a).
3 . A process according to claim 1 , further comprising contacting an accelerator with the tailings stream in step (a).
4 . A process according to claim 1 , wherein the gelling agent is selected from the group consisting of alkali metal silicates, polysilicate microgels, deionized silicate solutions having a molar ratio of Si:M of at least 2.6, wherein M is an alkali metal, colloidal silica, aluminum-modified colloidal silica, de-ionized colloidal silica, polysiloxane, siliconate, acrylamide, acrylate, polyol, phenoplast, aminoplast, vinyl ester-styrene, polyester-styrene, furfuryl alcohol-based furol polymer, epoxy, vulcanized oil, lignin, lignosulfonate, lignosulfite, montan wax, polyvinyl pyrrolidone, and combinations of two or more thereof.
5 . A process according to claim 4 , wherein the gelling agent is an alkali metal silicate.
6 . A process according to claim 1 , wherein the activator is selected from the group consisting of carbon dioxide, acids, bases, alkaline earth metal salts, aluminum salts, organic esters, aldehydes, dialdehydes, organic carbonates, organic phosphates, amides, peroxides, isocyanate, sodium aluminate, aluminum sulfate, and combinations thereof.
7 . A process according to claim 6 , wherein the activator is carbon dioxide or sulfuric acid.
8 . A process according to claim 1 , wherein the depositing is above the layer of the liquid.
9 . A process according to claim 1 , wherein the depositing is sub-surface of the layer to the liquid.
10 . A process according to claim 1 , wherein the gel is partially gelled prior to step (c).
11 . A process according to claim 1 , wherein the gel is fully gelled prior to step (c).
12 . A process according to claim 1 , wherein the gel is allowed to strengthen and solidify prior to step (c).
13 . A process according to claim 1 , further comprising partially or fully dewatering the gel prior to step (c).
14 . A process according to claim 13 , wherein dewatering occurs by air drying (evaporation), water run-off, compression, syneresis, exudation, freeze/thaw, sublimation, or any combination thereof.
15 . A process according to claim 14 , wherein dewatering occurs by evaporation.
16 . A process according to claim 14 , wherein dewatering occurs by water run-off.
17 . A process according to claim 1 , wherein the tailings stream is chemically thickened, mechanically thickened, or both, forming a partially dewatered tailings stream, prior to step (a).
18 . A process according to claim 17 , wherein the chemically thickening is by flocculation.
19 . A process according to claim 17 , wherein the mechanically thickening is by centrifuge.
20 . A process according to claim 1 , wherein the tailings stream is a mature fine tailings.
21 . A process according to claim 1 , wherein the tailings stream is a fresh tailings from a bitumen recovery process.
22 . A process according to claim 1 , further comprising depositing a layer of sand or other solids to the top of the deposited gel.
23 . A process according to claim 1 , further comprising removing the gel from the liquid and allowing the gel to partially or fully dewater.
24 . A process for treating a tailings stream comprising water and solids beneath a liquid surface, comprising (a) contacting a gelling agent and an activator with the tailings stream beneath the liquid surface, (b) entrapping the solids within a gel produced from the gelling agent.
25 . A process according to claim 24 , further comprising contacting a reinforcing agent, an accelerator, or any of their combinations with the tailings stream in step (a).
26 . A process according to claim 24 , further comprising depositing a layer of sand or other solids to the top of the gel.
27 . A process according to claim 24 , further comprising removing the gel from the liquid and allowing the gel to partially or fully dewater.