Rosin ester tackifiers for pressure-sensitive adhesives
View Patent ↗Water-dispersible adducted rosin esters, a process for making them, and their use in aqueous tackifier dispersions for pressure-sensitive adhesives are disclosed. Reaction of a rosin with a polyol gives a rosin ester intermediate, which is then reacted with a dienophile to produce an adducted rosin ester. The adducted rosin ester is further esterified with a polyethylene glycol having an Mw<700 to produce the water-dispersible adducted rosin ester. Esterification with the low-molecular-weight PEG imparts good water dispersibility to the adducted rosin ester while maintaining compatibility with other tackifier components. Combination of the aqueous tackifier dispersions with polymer emulsions, particularly acrylics, gives pressure-sensitive adhesives that deliver good loop tack and peel properties compared with commercial alternatives, even when the coat weight is reduced by 20%.
1. A rosin ester dispersion composition comprising:
(a) an adducted rosin ester produced by:
reacting a rosin with a polyol to provide a rosin ester intermediate; and
reacting the rosin ester intermediate with a dienophile to provide an adducted rosin ester; and
(b) water;
wherein said adducted rosin ester is esterified with a polyethylene glycol having a weight-average molecular weight less than 700.
2. The rosin ester dispersion composition of claim 1 wherein the polyethylene glycol has a weight-average molecular weight within the range of 200 to 400.
3. The rosin ester dispersion composition of claim 1 wherein the adducted rosin ester has an acid value within the range of 45 to 55 mg KOH/g.
4. The rosin ester dispersion composition of claim 1 wherein the adducted rosin ester has a ring-and-ball softening point within the range of 65 to 72° C.
5. The rosin ester dispersion composition of claim 1 wherein the adducted rosin ester comprises at least 5 wt. % of adducted itaconic acid.
6. The rosin ester dispersion composition of claim 1 further comprising a surfactant and a tackifier.
7. The rosin ester dispersion composition of claim 6 comprising 35 to 60 wt. % of water, 0.1 to 10 wt. % of the surfactant, and 40 to 65 wt. % of the tackifier.
8. The rosin ester dispersion composition of claim 6 wherein the tackifier further comprises a resin selected from the group consisting of polyterpenes, terpene-phenol resins, aromatic-terpene resins, aromatic-terpene-phenol resins, rosin esters, hydrocarbon resins, liquid hydrocarbon resins, aromatic resins, and mixtures thereof.
9. The rosin ester dispersion composition of claim 6 wherein the surfactant comprises a sulfate or phosphate of an ethoxylated fatty alcohol or an ethoxylated fatty acid.
10. The rosin ester dispersion composition of claim 1 further comprising a polymer emulsion.
11. The rosin ester dispersion composition of claim 10 wherein the polymer emulsion is selected from the group consisting of acrylic polymers, natural rubbers, and styrene-butadiene polymers.
12. The rosin ester dispersion composition of claim 1 , wherein the adducted rosin ester esterified with the polyethylene glycol is insoluble in water.
13. The rosin ester dispersion composition of claim 1 , wherein the polyol is selected from the group consisting of glycerin, pentaerythritol, trimethylolpropane, trimethylolethane, ethylene glycol, propylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, dipentaerythritol, and sorbitol 1,3-propanediol, 2-methyl-1,3-propanediol, 1,4-butanediol, 1,6-hexanediol, 1,4-cyclohexanedimethanol, diglycerol, dipentaerythritol, mannitol, sorbitol, hexitol, and mixtures thereof.