Method and device for producing polychlorosilanes

1. A process for preparing polychlorosilanes, comprising:

subjecting chlorosilanes to a thermal plasma and converting the chlorosilanes to the polychlorosilanes;

wherein the chlorosilanes comprise at least one monomeric chlorosilane of the formula I:

H x SiCl 4−x   (I),

where x is independently selected from 0, 1, 2 and 3,

wherein the process is performed in an apparatus comprising a gas discharge reactor having two columns,

wherein

a first column has a first column inlet for removing the polychlorosilanes upstream of the gas discharge reactor, and

a second column has a second column inlet for removing low boilers downstream

of the gas discharge reactor, and

wherein

a second column outlet of the second column has a condenser for condensation of the low boilers, and

the condenser has a recycle line that feeds the low boilers to the first column or the gas discharge reactor,

wherein the process further comprises:

removing, the polychlorosilanes upstream of the gas discharge reactor via the first column inlet of the first column;

removing low boilers downstream of the gas discharge reactor via the second column inlet of the second column;

condensing the low boilers via the condenser of second column outlet of the second column; and

feeding the low boilers to the first column or the gas discharge reactor via the recycle line of the condenser,

and wherein the process does not comprise addition of hydrogen.

2. The process according to claim 1 , wherein the prepared polychlorosilanes are polyperchlorosilanes having from 2 to 8 silicon atoms and are essentially free of hydrogen.

3. The process according to claim 1 , wherein the prepared polychlorosilanes are selected from the group consisting of an ultrahigh-purity hexachlorodisilane, an ultrahigh-purity octachlrotrisilane, an ultrahigh-purity decachlorotetrasilane, an ultrahigh-purity dodecachloropentasilane and a mixture thereof comprising at least two members.

4. The process according to claim 1 , wherein the prepared polychlorosilanes are at least one selected from the group consisting of an ultrahigh-purity hexachlorodisilane, an ultrahigh-purity octachlorotrisilane, an ultrahigh-purity decachlorotetrasilane and an ultrahigh-purity dodecachloropentasilane, wherein each of the group member has a titanium content of below 10 ppm.

5. The process according to claim 1 , wherein the chlorosilanes are one or more selected from the group consisting of an ultrahigh-purity tetrachlorosilane, an ultrahigh-purity trichlorosilane and an ultrahigh-purity dichlorosilane.

6. The process according to claim 1 , wherein the chlorosilane of the formula I that is optionally in a mixture with hexachlorodisilane is introduced into the gas discharge reactor or supplied to the first column.

7. The process according to claim 1 , wherein:

the chlorosilane of the formula I and hexachlorodisilane leave the gas discharge reactor via the second column and are condensed in the apparatus using the condenser;

the chlorosilane of the formula I and the hexachlorodisilane are recycled via the recycle line into the first column;

the chlorosilane of the general formula I, optionally in a mixture with hexachlorodisilane, is conducted through the gas discharge reactor; and

the polychlorosilanes having at least two silicon atoms are obtained at a first column outlet of the first column.

8. The process according to claim 1 ,

wherein:

the chlorosilane of the formula I that is in a mixture with hexachlorodisilane leaves the gas discharge reactor via the second column and is separated from the hexachlorodisilane in the apparatus using the condenser by condensing the hexachlorodisilane;

the chlorosilane of the formula I is recycled via the recycle line into the first column;

the chlorosilane of the formula I is conducted through the gas discharge reactor; and

the polychlorosilanes are obtained at a first column outlet of the first column.

9. The process according to claim 1 , wherein a pressure of from 300 to 800 mbar abs exists in the gas discharge reactor.