IP Library Granted Patent US 10,323,175
Granted Patent B2
US 10,323,175 · App. 14/783,727 · Granted Jun 18, 2019

Fracturing fluids based on associative polymers and on labile surfactants

Inventors: Arnaud Cadix (Saint Ouen, FR); James Wilson (Coye la Foret, FR)
Assignee: RHODIA OPERATIONS
C09K8/602C09K8/68C09K8/88C09K8/882E21B43/26
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Quick Facts
Patent No.
US 10,323,175
App. No.
14/783,727
Granted
Jun 18, 2019
Kind
B2
Abstract

The present invention relates to a fracturing fluid comprising, in an aqueous medium: an associative polymer; and a labile surfactant, in an amount sufficient to reduce or inhibit the effect of increasing the viscosity induced by said associative polymer.

Claims (14)

1. A process for recovery of hydrocarbons in a hydrocarbon reservoir, comprising a step where a fracturing fluid comprising, in an aqueous medium:

an associative polymer suitable for increasing the viscosity of the aqueous medium; and

a labile surfactant, wherein the labile surfactant comprises an ethoxylated fatty acid ester, in an amount sufficient to reduce or inhibit the effect of increasing the viscosity induced by said associative polymer; is injected into a hydrocarbon reservoir where the temperature and/or pH conditions are suitable for lyzing all or some of the labile surfactant;

wherein the associative polymer is made by micellar radical polymerization in which the following are placed in contact, in an aqueous medium:

hydrophilic monomers, dissolved or dispersed in said aqueous medium;

hydrophobic monomers, in the form of a micellar solution that comprises micelles of such hydrophobic monomers dispersed in the aqueous medium;

at least one radical polymerization initiator; and

at least one radical polymerization control agent.

2. The process according to claim 1 , wherein the labile surfactant comprises an ethoxylated fatty acid ester of formula R—COO—(CH 2 —CH 2 —O—) n —H, where R is a linear or branched hydrocarbon chain.

3. The process according to claim 1 , wherein the associative polymer is present in an amount of 0.1% to 3% by weight relative to the total weight of the fracturing fluid.

4. The process according to claim 1 , wherein the micelles further comprise at least one surfactant.

5. The process according to claim 1 , wherein the initiator comprises a water-soluble or water-dispersible initiator.

6. The process according to claim 1 , wherein the radical polymerization control agent comprises a thiocarbonylthio group.

7. The process according to claim 6 , wherein the radical polymerization control agent is a xanthate compound.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 23, 2023
From: RHODIA OPERATIONS
To: ENERGY SOLUTIONS (US) LLC
Reel/Frame 063149/0540 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 19, 2016
From: CADIX, ARNAUD; WILSON, JAMES
To: RHODIA OPERATIONS
Reel/Frame 037519/0156 →
Priority Claims (1)
FR 13 00864 · Apr 11, 2013 · national
Continuity (1)
Related Publication 20160298023A1 · Oct 13, 2016