Adamantane compound for organic electroluminescent elements, and organic electroluminescent element
View Patent ↗Provided are an organic EL device practically satisfactory in terms of its light-emitting characteristics, driving voltage, and durability, and a compound for an organic EL device to be used in the device. The organic EL device has a structure in which an anode, a plurality of organic layers including a light-emitting layer, and a cathode are laminated on a substrate, and the organic EL device contains, in at least one organic layer selected from the light-emitting layer, a hole-transporting layer, an electron-transporting layer, a hole-blocking layer, and an electron-blocking layer, an adamantane compound having at least one triarylborane structure in a molecule thereof as the compound for an organic EL device.
1. A compound for an organic electroluminescent device, which is represented by the following general formula (1):
wherein,
L and L 1 each independently represent a monovalent or divalent group selected from a substituted or unsubstituted aromatic hydrocarbon group, a substituted or unsubstituted aromatic heterocyclic group, or a linked aromatic group formed by linking two to four of aromatic rings of the substituted or unsubstituted aromatic hydrocarbon groups and the substituted or unsubstituted aromatic heterocyclic groups, the linked aromatic group may be linear or branched, and the aromatic rings to be linked may be identical to or different from each other; and
Ar 1 's each independently represent a substituted or unsubstituted aromatic hydrocarbon group or a substituted or unsubstituted aromatic heterocyclic group.
2. A compound for an organic electroluminescent device according to claim wherein the compound is represented by the following general formula (2):
wherein,
L 2 represents a single bond or a divalent group selected from a substituted or unsubstituted aromatic hydrocarbon group, a substituted or unsubstituted aromatic heterocyclic group, or a linked aromatic group formed by linking two or three of aromatic rings of the substituted or unsubstituted aromatic hydrocarbon groups and the substituted or unsubstituted aromatic heterocyclic groups, the linked aromatic group may be linear or branched, and the aromatic rings to be linked may be identical to or different from each other;
Ar 2 's each independently represent a substituted or unsubstituted aromatic hydrocarbon group or a substituted or unsubstituted aromatic heterocyclic group; and
X represents hydrogen, a cyano group, an alkyl group, a diarylamino group, a triarylsilyl group, a diarylphosphinyl group, a diarylphosphine oxide group, a diarylboranyl group, a substituted or unsubstituted aromatic hydrocarbon group, or a substituted or unsubstituted aromatic heterocyclic group.
3. A compound for an organic electroluminescent device according to claim 2 , wherein the compound is represented by the following general formula (3):
wherein,
L 2 and Ar 2 have the same meanings as L 2 and Ar 2 in the general formula (2), respectively;
L 3 represents a single bond or a divalent group selected from a substituted or unsubstituted aromatic hydrocarbon group, a substituted or unsubstituted aromatic heterocyclic group, or a linked aromatic group formed by linking two or three of aromatic rings of the substituted or unsubstituted aromatic hydrocarbon groups and the substituted or unsubstituted aromatic heterocyclic groups, the linked aromatic group may be linear or branched, and the aromatic rings to be linked may be identical to or different from each other;
Y represents B, N, P, or P═O; and
Ar 3 's each independently represent a substituted or unsubstituted aromatic hydrocarbon group or a substituted or unsubstituted aromatic heterocyclic group, and two Ar 3 's may be bonded to each other to form a fused heterocycle.
4. An organic electroluminescent device, comprising an organic layer containing the compound for an organic electroluminescent device of claim 1 .
5. An organic electroluminescent device according to claim 4 , wherein the organic layer containing the compound for an organic electroluminescent device is a light-emitting layer.
6. An organic electroluminescent device according to claim 5 , wherein the light-emitting layer contains the compound for an organic electroluminescent device as a dopant material.
7. An organic electroluminescent device according to claim 5 , wherein the light-emitting layer contains a phosphorescent light-emitting dopant and the compound for an organic electroluminescent device as a host material.
8. An organic electroluminescent device, comprising an organic layer containing compound for an organic electroluminescent device of claim 2 .
9. An organic electroluminescent device, comprising an organic layer containing the compound for an organic electroluminescent device of claim 3 .
10. An organic electroluminescent device according to claim 8 , wherein the organic layer containing the compound for an organic electroluminescent device is a light-emitting layer.
11. An organic electroluminescent device according to claim 9 , wherein the organic layer containing the compound for an organic electroluminescent device is a light-emitting layer.