IP Library Granted Patent US 9,724,678
Granted Patent B2
US 9,724,678 · App. 14/786,209 · Granted Aug 8, 2017

Process for preparing a sulphided catalyst

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Quick Facts
Patent No.
US 9,724,678
App. No.
14/786,209
Granted
Aug 8, 2017
Kind
B2
Abstract

The invention provides a process for preparing a sulphided catalyst comprising the steps of (a) treating a catalyst carrier with one or more Group VIB metal components, one or more Group VIII metal components and a glycolic acid ethoxylate ether compound according to the formula (I) R—(CH 2 ) x —CH 2 —O—[—(CH 2 ) 2 —O—] m —CH 2 —COOH (I) wherein R is a hydrocarbyl group containing of from 5 to 20 carbon atoms, x is in the range of from 1 to 15, and m is in the range of from 1 to 10, and wherein the molar ratio of compound (I) to the Group VIB and Group VIII metal content is at least 0.01:1 to 1:0.01; (b) drying the treated catalyst carrier at a temperature of at most 200° C. to form a dried impregnated carrier; and (c) sulphiding the dried impregnated carrier to obtain a sulphided catalyst.

Claims (12)

1. The process for preparing a sulphided catalyst comprising the steps of

(a) treating a catalyst carrier with one or more Group VIB metal components, one or more Group VIII metal components and a glycolic acid ethoxylate ether compound according to the formula (I)

R—(CH 2 ) x —CH 2 —O—[—(CH 2 ) 2 —O—] m —CH 2 —COOH  (I)

wherein R is a hydrocarbyl group containing from 5 to 20 carbon atoms, x is in the range of from 1 to 15, and m is in the range of from 1 to 10, and wherein the molar ratio of compound (I) to the Group VIB and Group VIII metal content is at least 0.01:1 to 1:0.01;

(b) drying the treated catalyst carrier at a temperature of at most 200° C. to form a dried impregnated carrier; and

(c) sulphiding the dried impregnated carrier to obtain a sulphided catalyst.

2. The process according to claim 1 , in which the compound according to formula (I) has a molecular weight of from 250 to 1500.

3. The process according to claim 1 , in R is a hydrocarbyl group containing of from 6 to 15 carbon atoms, x is in the range of from 1 to 10 and m is of from 1 to 5.

4. The process according to claim 1 , in which the carrier is alumina.

5. The process according to claim 4 , in which the carrier is gamma alumina.

6. The process according to claim 1 , in which the compound according to formula (I) is chosen from the group consisting of glycolic acid ethoxylate oleyl ether, glycolic acid ethoxylate nonylphenyl ether and glycolic acid ethoxylate lauryl ether.

7. The process for hydrotreating a sulphur-containing hydrocarbon feedstock which process comprises contacting the hydrocarbon feedstock at a hydrogen partial pressure from 1 to 70 bar and a temperature of from 200 to 420° C. with a catalyst prepared according to claim 1 .

Assignments (2)
CHANGE OF NAME Recorded Mar 7, 2022
From: SHELL OIL COMPANY
To: SHELL USA, INC.
Reel/Frame 059694/0819 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 22, 2015
From: AZGHAY, ALI; RIGUTTO, MARCELLO STEFANO
To: SHELL OIL COMPANY
Reel/Frame 036854/0573 →