Tinting enhancers for hard coat tinting
View Patent ↗The invention pertains to a tintable hard coat composition for forming a film on an optical article, the composition comprising at least one tinting enhancer, and at least two polymerizable monomers, a first monomer being an hydrolysat of an alkoxysilane comprising at least two alkoxy groups and one epoxy group, and a second monomer having at least two functional groups reacting with the first monomer, at least one of the two monomers having three functional groups of the same kind; the tinting enhancer being preferably chosen from the group consisting of 4-(methyl mercapto) phenol, 4,4′ thiodiphenol,4,4′-Sulfonyldiphenol, and 3,3′-(Ethylenedioxy)diphenol or a mix thereof: Formulas (I), (II), (III), (IV).
1. A tintable hard coat composition capable of forming a film on an optical article, the composition comprising at least one tinting enhancer and at least two polymerizable monomers, further defined as a first monomer that is a hydrolysat of an alkoxysilane comprising at least two alkoxy groups and one epoxy group, and a second monomer that comprises at least two functional groups capable of reacting with the first monomer, at least one of the two monomers having three functional groups of the same kind; wherein the tinting enhancer comprises 4-(methyl mercapto) phenol, and/or 3,3′-(Ethylenedioxy)diphenol; and
wherein the tinting enhancer is comprised in an amount in a range of 0.01 mol/100 g of solid content to 0.05 mol/100 g of solid content.
2. The composition of claim 1 , wherein the first monomer is a hydrolysat further defined as 3-glycidoxypropyltrimethoxysilane or glycidoxypropylmethyldiethoxysilane.
3. The composition of claim 1 , wherein the second monomer is a polyglycidylether, a hydrolysat of a poly alkoxysilane, or a mixture thereof.
4. The composition of claim 3 , wherein the second monomer is dimethyl-diethoxy-silane, tetraethoxy-silane, trimethylolpropane triglycidyl ether, or a mixture thereof.
5. The composition of claim 1 , further comprising at least one oxidized metal compound further defined as a cerium oxide, silicon oxide, tantalum oxide, tin oxide, titanium oxide, titanium alkoxide, or zirconium oxide.
6. The composition of claim 1 , wherein the tinting enhancer comprises between 3% and 8% by weight of solid content of the composition.
7. An optical article comprising a hard coat layer formed by the tintable hard coat composition of claim 1 .
8. The optical article of claim 7 , further defined as an ophthalmic lens.
9. The optical article of claim 7 , wherein the hard coat layer is further defined as tinted.
10. The optical article of claim 9 , further comprising at least one anti-reflective stack on top of the tinted hard coat layer.