Electrode active material having improved energy density and lithium secondary battery including the same
View Patent ↗Disclosed are an electrode active material having improved energy density and a lithium secondary battery including the same. More particularly, provided is an electrode active material including a first electrode active material and a second electrode active material, each of the first electrode active material and the second electrode active material having a composition represented by Formula (1) below, a ratio of lithium to metals in the first electrode active material being 1.4 to 1.7, and a ratio of lithium to metals in the second electrode active material being 1.2 or more and less than 1.4: (1− x )LiM′O 2−y A y −x Li 2 MnO 3−y′ A y′ (1) wherein M′ is Mn a M b ; M is at least one selected from the group consisting of Ni, Ti, Co, Al, Cu, Fe, Mg, B, Cr, Zr, Zn and Period II transition metals; A is at least one selected from the group consisting of anions such as PO 4 , BO 3 , CO 3 , F and NO 3 ; 0<x<1; 0<y≤0.02; 0<y′≤0.02; 0.5≤a≤1.0; 0≤b≤0.5; and a+b=1.
1. An electrode active material comprising a first electrode active material and a second electrode active material, wherein each of the first electrode active material and the second electrode active material has a composition represented by Formula (1) below, a molar ratio of lithium to metals in the first electrode active material is 1.4:1 to 1.7:1, and a molar ratio of lithium to metals in the second electrode active material is 1.2:1 or more and less than 1.4:1:
(1− x )LiM′O 2−y A y −x Li 2 MnO 3−y′ A y′ (1)
wherein M′ is Mn a M b ;
M is at least one selected from the group consisting of Ni, Ti, Co, Al, Cu, Fe, Mg, B, Cr, Zr, Zn and Period II transition metals;
A is at least one selected from the group consisting of anions such as PO 4 , BO 3 , CO 3 , F and NO 3 ;
0<x<1; 0<y≤0.02; 0<y′≤0.02; 0.5≤a≤1.0; 0≤b≤0.5; and a+b=1.
2. The electrode active material according to claim 1 , wherein a molar amount of manganese (Mn) in the first electrode active material is 60 mol % to 80 mol % with respect to a total molar amount of the metals in the first electrode active material, and a molar amount of manganese (Mn) in the second electrode active material is greater than 30 mol % and less than 60 mol % with respect to a total molar amount of the metals in the second electrode active material.
3. The electrode active material according to claim 2 , wherein, in LiM′O 2−y A y of the second electrode active material, a molar amount of manganese (Mn) is greater than 40 mol % and less than 60 mol % with respect to a total molar amount of M′ in LiM′O 2−y A y of the second electrode active material.
4. The electrode active material according to claim 2 , wherein a weight ratio of Li 2 MnO 3−y′ A y′ to the LiM′O 2−y A y in the second electrode active material being 5:95 to 95:5.
5. The electrode active material according to claim 1 , wherein a weight ratio of the first electrode active material to the second electrode active material is 5:95 to 95:5.
6. The electrode active material according to claim 1 , wherein an average particle diameter (D50) of the first electrode active material is 3 μm to 20 μm.
7. The electrode active material according to claim 1 , wherein an average particle diameter (D50) of the second electrode active material is 3 μm to 20 μm.
8. The electrode active material according to claim 4 , wherein an average particle diameter (D50) of Li 2 MnO 3−y′ A y′ of the second electrode active material is 3 μm to 20 μm, and an average particle diameter (D50) of LiM′O 2−y A y of the second electrode active material is 3 μm to 20 μm.
9. The electrode active material according to claim 1 , wherein the first electrode active material has a globular shape, an oval shape, a spindle shape, a scale shape, a fiber shape, a stick shape, a core-shell shape or an amorphous shape.
10. The electrode active material according to claim 1 , wherein the second electrode active material is a globular shape, an oval shape, a spindle shape, a scale shape, a fiber shape, a stick shape, a core-shell shape or an amorphous shape.
11. The electrode active material according to claim 1 , wherein the first electrode active material further comprises a conductive coating layer present in a surface, a thickness of the conductive coating layer being 0.1 nm to 100 nm.
12. The electrode active material according to claim 1 , wherein the second electrode active material further comprises a conductive coating layer present in a surface, a thickness of the conductive coating layer being 0.1 nm to 100 nm.
13. The electrode active material according to claim 4 , wherein Li 2 MnO 3−y′ A y′ of the second electrode active material further comprises a conductive coating layer present in a surface, a thickness of the conductive coating layer being 0.1 nm to 100 nm.
14. The electrode active material according to claim 4 , wherein LiM′O 2−y A y of the second electrode active material further comprises a conductive coating layer present in a surface, a thickness of the conductive coating layer being 0.1 nm to 100 nm.
15. The electrode active material according to claim 1 , wherein the first electrode active material is in the form of secondary particles composed of primary particles, porosity of the secondary particles being 1% to 50%.
16. The electrode active material according to claim 1 , wherein the second electrode active material is in the form of secondary particles composed of primary particles, porosity of the secondary particles being 1% to 50%.
17. The electrode active material according to claim 4 , wherein Li 2 MnO 3−y′ A y′ of the second electrode active material is in the form of secondary particles composed of primary particles, porosity of the secondary particles being 1% to 50%.
18. The electrode active material according to claim 4 , wherein LiM′O 2−y A y of the second electrode active material is in the form of secondary particles composed of primary particles, porosity of the secondary particles being 1% to 50%.
19. The electrode active material according to claim 11 , wherein the conductive coating layer comprises one or more conductive particles.
20. The electrode active material according to claim 19 , wherein the conductive coating layer comprises conductive carbon black.
21. The electrode active material according to claim 20 , wherein the conductive carbon black is at least one selected from the group consisting of acetylene black, Ketjen black, furnace black, oil-furnace black, Columbia carbon, channel black, lamp black and thermal black.
22. A lithium secondary battery comprising the electrode active material according to claim 1 as a positive electrode active material.
23. The lithium secondary battery according to claim 22 , comprising a carbon based material and/or Si as a negative electrode active material.
24. The lithium secondary battery according to claim 22 , wherein the lithium secondary battery is one selected from the group consisting of a lithium ion battery, a lithium ion polymer battery and a lithium polymer battery.
25. A battery pack comprising the lithium secondary battery according to claim 22 .
26. A device using the battery pack according to claim 25 as an energy source.
27. The electrode active material of claim 1 , wherein the molar ratio of lithium to metals in the second electrode active material is 1.2:1 or more 1.25:1.