Styrene acrylate hybrid toner process utilizing a low VOC (volatile organic compound) coalescent agent in toner shells
Disclosed herein include processes of preparing hybrid toner compositions with toner particles having a core-shell type structure, where the shell contains a non-volatile coalescent agent. More particularly, embodiments relate to processes of preparing styrene acrylate hybrid toner compositions.
1. A process for preparing a hybrid toner having a core and a shell, comprising:
mixing a first latex comprising a styrene acrylate polymer resin, a latex of an amorphous polyester wherein the amorphous polyester forming the latex obtained by reacting a diol with a diacid, a latex of a crystalline polyester, a wax, and an optional colorant to form a core mixture;
optionally adding a coagulant to the core mixture;
heating the core mixture to a temperature below the glass transition temperature of the styrene acrylate polymer resin to aggregate the core mixture to form aggregated core particles;
mixing a second latex comprising a second styrene acrylate polymer resin and a coalescent agent to form a shell mixture;
coating the shell mixture onto the aggregated core particles;
heating the shell mixture and the aggregated core particles to a temperature above the glass transition temperature of the second styrene acrylate polymer resin to coalesce the aggregated core particles to form toner particles;
and isolating the toner particles.
2. The process of claim 1 , wherein the coalescent agent has a boiling point at atmospheric pressure of from about 250° C. to about 450° C.
3. The process of claim 1 , wherein the coalescent agent has a volatility of from about 10 −8 to about 10 −2 mm Hg at 20° C.
4. The process of claim 1 , wherein the coalescent agent has solubility in water of below about 0.5 weight percent.
5. The process of claim 1 , wherein the coalescent agent contains at least one ester linkage.
6. The process of claim 1 , wherein the coalescent agent is selected from the group consisting of 2, 2, 4-trimethyl-1,3-pentanediol monoisobutyrate, 2,2,4-trimethyl-1 ,3-pentanediol diisobutyrate, triethylene glycol di-2-ethylhexanoate, benzyl benzoate, diethylene glycol dibenzoate, 3-phenylpropyl benzoate, dipropylene glycol dibenzoate, propylene glycol dibenzoate and mixtures thereof.
7. The process of claim 1 , wherein the coalescent agent comprises 2,2,4-trimethyl-1 ,3-pentanediol monoisobutyrate.
8. The process of claim 1 , wherein the coalescent agent is added in an amount of from about 0.1 to about 5.0 percent by weight, based on the solid content in the shell mixture.
9. The process of claim 1 , wherein the coalescent agent is only present in the shell of the hybrid toner.
10. The process of claim 1 , wherein the coalescent agent does not evaporate during subsequent processing, such that the coalescent agent is present in the hybrid toner particles in an amount of about 0.01 to about 2.0 percent by weight, based on the final dry weight of the hybrid toner particles.
11. The process of claim 1 , wherein the styrene acrylate polymer resin of the first latex and the styrene second acrylate polymer resin of the second latex are independently selected from the group consisting of poly(styrene-alkyl acrylate), poly(styrene-alkyl methacrylate), poly(styrene-alkyl acrylate-acrylic acid), poly(styrene-alkyl methacrylate-acrylic acid), poly(styrene-propyl acrylate), poly( styrene-butyl acrylate), poly(styrene-butyl acrylate-acrylic acid), poly(styrene-butyl acrylate-methacrylic acid), poly(styrene-butyl acrylate-acrylonitrile), poly(styrene-butyl acrylate-acrylonitrile-acrylic acid), and combinations thereof.
12. The process of claim 1 , wherein the heating of the core mixture is at a temperature from about 40° c to about 60° C.
13. The process of claim 1 , wherein the heating of the core mixture is conducted for about 15 minutes to about 2 hours.
14. The process of claim 1 , wherein the heating of the shell mixture and the aggregated core particles is at a temperature from about 65° C. to about 90° C.
15. The process of claim 1 , wherein the heating of the shell mixture and the aggregated core particles is conducted for about 15 minutes to about 4 hours.
16. The process of claim 1 , wherein the coagulant is present in the hybrid toner particles, and on a dry weight basis, in an amount of from 0 to about 5% by weight of the hybrid toner particles and is selected from the group consisting of polyaluminum halides, polyaluminum silicates, polyaluminum hydroxides, and polyaluminum phosphate.
17. The process of claim 1 , wherein the toner particles have a surface area of about 1.3 to about 6.5 m2/g.
18. The process of claim 1 , wherein the coalescent agent is only present in the shell of the hybrid toner.
19. A process for preparing a hybrid toner having a core and a shell, comprising:
mixing a first latex comprising a styrene acrylate polymer resin, a latex of an amorphous polyester wherein the amorphous polyester forming the latex is obtained by reacting a diol with a diacid, a crystalline polyester latex, an optional colorant and an optional wax to form a core mixture;
optionally adding a coagulant to the core mixture;
heating the core mixture to a temperature below the glass transition temperature of the styrene acrylate polymer resin to aggregate the core mixture to form aggregated core particles;
mixing a second latex comprising a second styrene acrylate polymer resin and 2,2,4-trimethyl-1 ,3-pentanediol monoisobutyrate to form a shell mixture;
coating the shell mixture onto the aggregated core particles;
heating the shell mixture and the aggregated core particles to a temperature above the glass transition temperature of the second styrene acrylate polymer resin to coalesce the aggregated core particles to form toner particles; and
isolating the toner particles.
20. The process of claim 19 , wherein the coalescent agent is added in an amount of from about 0.1 to about 5.0 percent by weight, based on the solid content in the shell mixture.