Reactive hot melt adhesive
The present disclosure relates to silane reactive hot melt adhesive compositions including acid functional wax and basic functional wax; the production of such adhesives; and the use of such adhesives. The silane reactive hot melt adhesive compositions have improved green strength as compared to silane reactive hot melt adhesive compositions without the acid functional wax and basic functional wax.
1. A silane reactive hot melt adhesive composition comprising: a silane modified polymer; 0.1 wt % to 15 wt % of acidic functional wax based on weight of the adhesive composition; and 0.05 wt % to 8 wt % of basic functional wax based on weight of the adhesive composition.
2. The silane reactive hot melt adhesive composition of claim 1 , comprising 0.1 wt % to 2 wt % of basic functional wax based on weight of the adhesive composition.
3. The silane reactive hot melt adhesive composition of claim 1 wherein the ratio of acidic functional wax to basic functional wax (R A B ) is in the range of 1:80 to 300:1.
4. The silane reactive hot melt adhesive composition of claim 1 further comprising an aminosilane adhesion promoter.
5. The silane reactive hot melt adhesive composition of claim 1 further comprising an aminosilane adhesion promoter wherein the molar ratio of acid functionality from the acidic functional wax and amino functionality of the aminosilane (R) is equal to or less than 1.2.
6. The silane reactive hot melt adhesive composition of claim 1 wherein the silane reactive hot melt adhesive composition is free of isocyanate functionality.
7. The silane reactive hot melt adhesive composition of claim 1 further comprising one or more of a tackifier selected from the group consisting of rosin ester, hydrogenated hydrocarbon, aromatic tackifier or mixtures thereof; an acrylic polymer; and a catalyst.
8. The silane reactive hot melt adhesive composition of claim 1 , wherein the silane modified polymer comprises a plurality of terminal silyl groups each independently having a formula of
A-Si(C x H 2x+1 ) n (OC y H 2y+1 ) 3-n ,
wherein
A is a linkage to the polymer backbone;
x is 1 to 12;
y is 1 to 12; and
n is 0, 1 or 2; and
the silyl group of the silane modified polymer is end-functionalized.
9. The silane reactive hot melt adhesive composition of claim 1 , wherein the silane modified polymer has a backbone structure selected from the group consisting of polyurethane, polyether, polyester, polyacrylate and GP polyolefin.
10. The silane reactive hot melt adhesive composition of claim 1 , wherein the silane modified polymer has a formula
R-[A-Si(C x H 2x+1 ) n (OC y H 2y+1 ) 3-n ] z
wherein
R is an organic backbone of the silane modified polymer without silicon atoms,
A is a linkage that links the silane group to the polymer backbone R,
n=0, 1 or 2;
x and y are, independently a number from 1 to 12; and
z is at least one.
11. The silane reactive hot melt adhesive composition of claim 1 , wherein the silane modified polymer comprises a plurality of telechelic silyl groups each independently having a formula of
A-Si(C x H 2x+1 ) n (OC y H 2y+1 ) 3-n ,
wherein
A is a linkage to the polymer backbone;
x is 1 to 12;
y is 1 to 12; and
n is 0, 1 or 2.
12. The silane reactive hot melt adhesive composition of claim 1 , wherein the silane reactive hot melt adhesive composition is free of water and solvent.
13. A method of applying a silane reactive hot melt adhesive composition comprising:
providing the silane reactive hot melt adhesive composition of claim 1 in solid form at room temperature;
heating the silane reactive hot melt adhesive composition to a molten state at the point of use;
applying the molten silane reactive hot melt adhesive composition to a first substrate;
bringing a second substrate in contact with the molten adhesive composition applied to the first substrate;
cooling the applied molten adhesive composition to, a solid state;
subjecting the cooled adhesive composition to conditions sufficient to irreversibly cure the cooled adhesive composition to form a bond between the first and second substrates.
14. The method of claim 13 wherein the step of applying the molten silane reactive hot melt adhesive composition is selected from the group consisting of spray application, extrusion, and roll coating.
15. An article of manufacture comprising cured reaction products of the silane reactive hot melt adhesive composition of claim 1 .