IP Library Granted Patent US 11,326,115
Granted Patent B2
US 11,326,115 · App. 14/809,472 · Granted May 10, 2022

Biodiesel cold filtration process

Inventors: Myron Francis Danzer (Glidden, IA); Timothy L Ely (Jefferson, IA); Scott Alan Kingery (Jefferson, IA); John Mostek (Carroll, IA); Matthew Leonard Schultes (Carroll, IA); Wayne William McCalley (Andover, MN); William Michael McDonald (Maplewood, MN)
Assignee: Renewable Energy Group, Inc.
C10L1/026B01D15/08B01D17/00B01D21/0012B01D29/56C07C67/56C10G31/09C11C1/08C11C3/003C10G2300/1011C10G2400/04C10L2200/0476C10L2270/026C10L2290/542C10L2290/547Y02E50/10Y02P30/20
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Quick Facts
Patent No.
US 11,326,115
App. No.
14/809,472
Granted
May 10, 2022
Kind
B2
Abstract

An improved biodiesel production process includes the steps of processing a feedstock to produce biodiesel, cooling the biodiesel so as to form sediment, and filtering the biodiesel to remove the sediment. The resulting biodiesel from the cold filtration process avoids problems of sediment formation during storage and transportation.

Claims (25)

1. A method for removing impurities from biodiesel, comprising: producing biodiesel from a feedstock using a process with temperatures exceeding 380° C.; cooling the biodiesel to a temperature of between about 4-24° C. using at least one heat exchanger; directing the cooled biodiesel to a tank to allow impurities to precipitate as particulates in the biodiesel; and removing the precipitated particulates from the cooled biodiesel by passing the cooled biodiesel through a first filtering stage having a first filter and a second filtering stage having a second filter; wherein the first filter and the second filter are selected from a pressure filter and a sock filter.

2. The method of claim 1 whereby the biodiesel is cooled to a temperature of between about 4-22° C.

3. A method for removing impurities from biodiesel, comprising:

producing biodiesel from a feedstock using a process with temperatures exceeding 38° C.;

cooling the biodiesel in multiple stages using a series of heat exchangers to form particulates of impurities; and

filtering the cooled biodiesel to remove the particulates.

4. The method of claim 3 further comprising periodically cleaning the heat exchangers by running un-cooled biodiesel through the heat exchangers without supplying cooling fluid to the exchangers.

5. The method of claim 3 wherein a first cooling stage reduces the biodiesel temperature to approximately between 93-105° C., a second cooling stage further reduces the biodiesel temperature to approximately between 26-33° C., and a third cooling stage further reduces the biodiesel temperature to at least between 18-24° C.

6. The method of claim 1 wherein a first filtering stage includes the addition of a filter aid to the biodiesel.

7. The method of claim 6 whereby the filter aid is selected from the group consisting of diatomaceous earth, silica, sand, clay, cellulose, minerals, and mixtures thereof.

8. The method of claim 7 wherein the filter aid is diatomaceous earth.

9. The method of claim 8 wherein the diatomaceous earth is between 0.1% to 0.25% by weight of the biodiesel.

10. The method of claim 6 wherein the first filter is a leaf filter.

11. The method of claim 6 wherein a second filter is a sock filter.

12. A method for improving the quality of biodiesel fuel, comprising: producing biodiesel which conforms to the requirements of ASTM D6751-06 using a biodiesel manufacturing process; cooling the biodiesel to a temperature of less than 380° C. using at least one heat exchanger so as to precipitate out particles containing components other than methyl esters; and passing the biodiesel through at least a first filtering stage having a first physical filter and a second filter stage having a second physical filter to remove the particles containing components other than methyl esters and thereby produce improved biodiesel fuel; wherein the first physical filter and the second physical filter are selected from a pressure filter and a sock filter.

13. The method of claim 12 whereby the biodiesel is cooled to a temperature of between about 4-38° C.

14. The method of claim 12 wherein a first filtering stage includes the addition of a filter aid to the biodiesel.

15. The method of claim 14 whereby the filter aid is selected from the group consisting of diatomaceous earth, silica, sand, clay, cellulose, minerals, and mixtures thereof.

16. The method of claim 15 wherein the filter aid is diatomaceous earth.

17. The method of claim 16 wherein the diatomaceous earth is between 0.1% to 0.25% by weight of the biodiesel.

18. The method of claim 12 wherein the first physical filter is a leaf filter.

19. The method of claim 12 wherein the second physical filter is a sock filter.

20. The method of claim 12 whereby the biodiesel is cooled to a temperature of between about 4-22° C.

21. The method of claim 1 wherein the pressure filter is one of a leaf filter, a tube filter, a candle filter, a horizontal pressure filter, and a filter press.

22. The method of claim 12 wherein the pressure filter is one of a leaf filter, a tube filter, a candle filter, a horizontal pressure filter, and a filter press.

Assignments (12)
PARTIAL RELEASE Recorded Jan 23, 2023
From: JEFFERIES FINANCE LLC, AS COLLATERAL AGENT
To: CROWN IRON WORKS COMPANY
Reel/Frame 063403/0634 →
PARTIAL RELEASE Recorded Jan 23, 2023
From: JEFFERIES FINANCE LLC, AS COLLATERAL AGENT
To: CROWN IRON WORKS COMPANY
Reel/Frame 062462/0260 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 10, 2023
From: CROWN IRON WORKS COMPANY
To: REG BIOFUELS, LLC
Reel/Frame 062328/0595 →
RELEASE OF SECURITY INTEREST Recorded Jul 1, 2022
From: UMB BANK, N.A., AS COLLATERAL TRUSTEE
To: REG SYNTHETIC FUELS, LLC; RENEWABLE ENERGY GROUP, INC.; REG SENECA, LLC; REG BIOFUELS, LLC
Reel/Frame 060562/0428 →
PATENT SECURITY AGREEMENT Recorded Jun 19, 2021
From: REG BIOFUELS, LLC
To: UMB BANK, N.A., AS COLLATERAL TRUSTEE
Reel/Frame 056629/0546 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 17, 2019
From: MCCALLEY, WAYNE; MCDONALD, WILLIAM
To: CROWN IRON WORKS COMPANY
Reel/Frame 050744/0092 →
CORRECTIVE ASSIGNMENT TO CORRECT THE CONVEYING PARTY NAME ALSO RECEIVING PARTY NAME PREVIOUSLY RECORDED AT REEL: 47200 FRAME: 681. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Oct 17, 2019
From: REG BIOFUELS, INC
To: REG BIOFUELS, LLC
Reel/Frame 050743/0193 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 5, 2018
From: DANZER, MYRON FRANCIS; ELY, TIMOTHY L.; KINGERY, SCOTT ALAN; MOSTEK, JOHN; SCHULTES, MATTHEW LEONARD
To: RENEWABLE ENERGY GROUP, LLC
Reel/Frame 047079/0442 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 5, 2018
From: RENEWABLE ENERGY GROUP, LLC; CROWN IRON WORKS COMPANY
To: RENEWABLE ENERGY GROUP, LLC; CROWN IRON WORKS COMPANY
Reel/Frame 047082/0480 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 5, 2018
From: REG, LLC
To: REG BIOFUELS, INC,
Reel/Frame 047083/0044 →
CHANGE OF NAME Recorded Oct 5, 2018
From: RENEWABLE ENERGY GROUP, LLC
To: REG, LLC
Reel/Frame 047199/0697 →
CHANGE OF NAME Recorded Oct 5, 2018
From: REG BIOFUELS, LLC
To: REG BIOFUELS, INC
Reel/Frame 047200/0681 →
Continuity (3)
Continuation 11670153 · Feb 1, 2007
Provisional Application 60764440 · Feb 2, 2006
Related Publication 20150329791A1 · Nov 19, 2015