Molecules having certain pesticidal utilities, and intermediates, compositions, and processes related thereto

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Quick Facts

Patent No.: US 9,550,739
App. No.: 14/810,775
Granted: Jan 24, 2017
Kind: B2

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Abstract

This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Nematoda, Arthropoda, and/or Mollusca, processes to produce such molecules and intermediates used in such processes, compositions containing such molecules, and processes of using such molecules against such pests. These molecules may be used, for example, as nematicides, acaricides, insecticides, miticides, and/or molluscicides. This document discloses molecules having the following formula (“Formula One”).

Claims (36)

1. A process comprising applying a molecule of Formula One to a locus to control a pest, in a sufficient amount to control said pest, wherein said pest is Beet Armyworm ( Spodoptera exigua ), Cabbage Looper ( Trichoplusia ni ), Green Peach Aphid ( Myzus persicae ) or Yellow Fever Mosquito ( Aedes aegypti );

wherein

(A) R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 9 , R 10 , R 14 , R 15 , and R 16 is each independently selected from a group consisting of H, F, Cl, Br, I, CN, NO z , OH, C 1 -C 4 alkyl, C 2 -C 4 alkenyl, C 2 -C 4 alkenyloxy, C 2 -C 4 alkynyl, C 2 -C 4 alkynyloxy, C 1 -C 4 haloalkyl, C 1 -C 4 alkoxy, C 1 -C 4 haloalkoxy, C 3 -C 6 cycloalkyl, C 3 -C 6 cycloalkoxy, C 3 -C 6 cycloalkenyl, or C 3 -C 5 cycloalkenyloxy,

wherein each alkyl, alkenyl, alkenyloxy, alkynyl, alkynyloxy, haloalkyl, alkoxy, haloalkoxy, cycloalkyl, cycloalkoxy, cycloalkenyl, or cycloalkenyloxy, are optionally substituted with one or more substituents independently selected from a group consisting of H, F, Cl, Br, I, CN, NO 2 , OH, C 1 -C 4 alkyl, C 2 -C 4 alkenyl, C 2 -C 4 alkenyloxy, C 2 -C 4 alkynyl, C 1 -C 4 alkynyloxy, C 1 -C 4 haloalkyl, C 1 -C 4 alkoxy, C 1 -C 4 haloalkoxy, C 3 -C 6 cycloalkyl, C 3 -C 6 cycloalkoxy, C 3 -C 6 cycloalkenyl, or C 3 -C 6 cycloalkenyloxy;

(B) R 8 is H;

(D) R 11 is selected from H, (C 1 -C 4 )alkyl, (C 2 -C 4 )alkenyl, (C 2 -C 4 )alkenyloxy, (C 2 -C 4 )alkynyl, (C 2 -C 4 )alkynyloxy, (C 1 -C 4 )haloalkyl, (C 1 -C 4 )alkoxy, (C 1 -C 4 )haloalkoxy, (C 1 -C 4 )alkyl (C 1 -C 4 )alkoxy, (C 3 -C 6 )cycloalkyl, (C 3 -C 6 )cycloalkoxy, (C 3 -C 6 )cycloalkenyl, (C 3 -C 6 )cycloalkenyloxy, ((C 1 -C 4 )alkyl)) (C 3 -C 6 )cycloalkyl), C(O)(C 1 -C 4 )alkyl, C(O)phenyl, ((C 1 -C 4 )alkyl)C(O)(C 1 -C 4 )alkyl, and ((C 1 -C 4 )alkyl)C(O)O((C 1 -C 4 )alkyl),

wherein each alkyl, alkenyl, alkenyloxy, alkynyl, alkynyloxy, haloalkyl, alkoxy, haloalkoxy, cycloalkyl, cycloalkoxy, cycloalkenyl, cycloalkenyloxy, and phenyl, are optionally substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, NO 2 , OH, oxo, and OC(O)(C 1 -C 4 )alkyl;

(E) X is selected from N or CR 12 , wherein R 12 is selected from a group consisting of H, F, Cl, Br, I, CN, NO 2 , OH, C 1 -C 4 alkyl, C 2 -C 4 alkenyl, C 2 -C 4 alkenyloxy, C 2 -C 4 alkynyl, C 2 -C 4 alkynyloxy, C 1 -C 4 haloalkyl, C 1 -C 4 alkoxy, C 1 -C 4 haloalkoxy, C 3 -C 6 cycloalkyl, C 3 -C 6 cycloalkoxy, C 3 -C 6 cycloalkenyl, or C 3 -C 6 cycloalkenyloxy;

(F) R 13 is selected from a group consisting of H, phenyl, or substituted phenyl,

wherein said substituted phenyl is substituted with one or more substituents independently selected from a group consisting of H, F, Cl, Br, I, CN, NO 2 , OH, C 1 -C 4 alkyl, C 2 -C 4 alkenyl, C 2 -C 4 alkenyloxy, C 2 -C 4 alkynyl, C 2 -C 4 alkynyloxy, C 1 -C 4 haloalkyl, C 1 -C 4 alkoxy, C 1 -C 4 haloalkoxy, C 3 -C 6 cycloalkyl, C 3 -C 6 cycloalkoxy, C 3 -C 6 cycloalkenyl, C 3 -C 6 cycloalkenyloxy, OC 1 -C 4 alkylphenyl, C(O)C 1 -C 4 alkyl, or N(C 1 -C 4 alkyl)(C 1 -C 4 alkyl); and

(G) Q is selected from O or S.

2. A molecule having a structure of Formula One wherein said molecule is in the form of an agriculturally acceptable acid addition salt, a salt derivative, a solvate, or an ester derivative;

wherein

(A) R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 9 , R 10 , R 14 , R 15 , and R 16 is each independently selected from a group consisting of H, F, Cl, Br, I, CN, NO 2 , OH, C 1 -C 4 alkyl, C 2 -C 4 alkenyl, C 2 -C 4 alkenyloxy, C 2 -C 4 alkynyl, C 2 -C 4 alkynyloxy, C 1 -C 4 haloalkyl, C 1 -C 4 alkoxy, C 1 -C 4 haloalkoxy, C 3 -C 6 cycloalkyl, C 3 -C 6 cycloalkoxy, C 3 -C 6 cycloalkenyl, or C 3 -C 6 cycloalkenyloxy,

wherein each alkyl, alkenyl, alkenyloxy, alkynyl, alkynyloxy, haloalkyl, alkoxy, haloalkoxy, cycloalkyl, cycloalkoxy, cycloalkenyl, or cycloalkenyloxy, are optionally substituted with one or more substituents independently selected from a group consisting of H, F, Cl, Br, I, CN, NO 2 , OH, C 1 -C 4 alkyl, C 2 -C 4 alkenyl, C 2 -C 4 alkenyloxy, C 2 -C 4 alkynyl, C 2 -C 4 alkynyloxy, C 1 -C 4 haloalkyl, C 1 -C 4 alkoxy, C 1 -C 4 haloalkoxy, C 3 -C 6 cycloalkyl, C 3 -C 6 cycloalkoxy, C 3 -C 6 cycloalkenyl, or C 3 -C 6 cycloalkenyloxy;

(B) R 8 is H;

(E) X is selected from N or CR 12 , wherein R 12 is selected from a group consisting of H, F, Cl, Br, I, CN, NO 2 , OH, C 1 -C 4 alkyl, C 2 -C 4 alkenyl, C 2 -C 4 alkenyloxy, C 2 -C 4 alkynyl, C 2- C 4 alkynyloxy, C 1 -C 4 haloalkyl, C 1 -C 4 alkoxy, C 1 -C 4 haloalkoxy, C 3 -C 6 cycloalkyl, C 3 -C 6 cycloalkoxy, C 3 -C 6 cycloalkenyl, or C 3 -C 6 cycloalkenyloxy;

(F) R 13 is selected from a group consisting of H, phenyl, or substituted phenyl,

wherein said substituted phenyl is substituted with one or more substituents independently selected from a group consisting of H, F, Cl, Br, I, CN, NO 2 , OH, C 1 -C 4 alkyl, C 2- C 4 alkenyl, C 2 -C 4 alkenyloxy, C 2 -C 4 alkynyl, C 2 -C 4 alkynyloxy, C 1 -C 4 haloalkyl, C 1 -C 4 alkoxy, C 1 -C 4 haloalkoxy, C 3 -C 6 cycloalkyl, C 3 -C 6 cycloalkoxy, C 3 -C 6 cycloalkenyl, C 3 -C 6 cycloalkenyloxy, OC 1 -C 4 alkylphenyl, C(O)C 1 -C 4 alkyl, or N(C 1 -C 4 alkyl)(C 1 -C 4 alkyl); and

(G) Q is selected from O or S.

3. A pesticidal composition comprising a molecule of Formula One and a carrier in the form of a seed dressing;

wherein

wherein each alkyl, alkenyl, alkenyloxy, alkynyl, alkynyloxy, haloalkyl, alkoxy, haloalkoxy, cycloalkyl, cycloalkoxy, cycloalkenyl, or cycloalkenyloxy, are optionally substituted with one or more substituents independently selected from a group consisting of H, F, Cl, Br, I, CN, NO 2 , OH, C 1 -C 4 alkyl, C 2 -C 4 alkenyl, C 2 -C 4 alkenyloxy, C 2 -C 4 alkynyl, C 2 -C 4 alkynyloxy, C 1 -C 4 haloalkyl, C 1 -C 4 alkoxy, C 1 -C 4 haloalkoxy, C 3 -C 6 cycloalkyl, C 3 -C 6 cycloalkoxy, C 3 -C 6 cycloalkenyl, or C 3 -C 6 cycloalkenyloxy;

(B) R 8 is H;

(E) X is selected from N or CR 12 , wherein R 12 is selected from a group consisting of H, F, Cl, Br, I, CN, NO 2 , OH, C 2 -C 4 alkyl, C 2 -C 4 alkenyl, C 2 -C 4 alkenyloxy, C 2 -C 4 alkynyl, C 2- C 4 alkynyloxy, C 1 -C 4 haloalkyl, C 1 -C 4 alkoxy, C 1 -C 4 haloalkoxy, C 3 -C 6 cycloalkyl, C 3 -C 6 cycloalkoxy, C 3 -C 6 cycloalkenyl, or C 3 -C 6 cycloalkenyloxy;

(F) R 13 is selected from a group consisting of H, phenyl, or substituted phenyl,

(G) Q is selected from O or S.

Assignments (1)

CHANGE OF NAME Recorded Nov 8, 2021

From: DOW AGROSCIENCES LLC

To: CORTEVA AGRISCIENCE LLC

Reel/Frame 058044/0184 →