IP Library Granted Patent US 9,938,181
Granted Patent B2
US 9,938,181 · App. 14/811,178 · Granted Apr 10, 2018

White glass

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Quick Facts
Patent No.
US 9,938,181
App. No.
14/811,178
Granted
Apr 10, 2018
Kind
B2
Abstract

A white glass includes, in terms of mole percentage on the basis of oxides, from 50% to 74% of SiO 2 , from 0 to 8% of B 2 O 3 , from 1% to 8% of Al 2 O 3 , from 0 to 18% of MgO, from 0 to 7% of CaO, from 0 to 10% of SrO, from 0 to 12% of BaO, from 0 to 5% of ZrO 2 , from 5% to 15% of Na 2 O and from 2% to 10% of P 2 O 5 . In the white glass, a total content of CaO, SrO and BaO is from 1% to 22%, a total content RO of MgO, CaO, SrO and BaO is from 5% to 25% and a ratio CaO/RO of a content of CaO to the RO is 0.7 or less.

Claims (26)

1. A white glass comprising: in terms of mole percentage on the basis of oxides, from 50% to 65% of SiO 2 ; from 0 to 8% of B 2 O 3 ; from 4.0% to 8% of Al 2 O 3 ; from 6.0 to 18% of MgO; from 0 to 5% of CaO; from 0 to 10% of SrO; from 0 to 12% of BaO; from 0 to 5% of ZrO 2 ; from 5% to 15% of Na 2 O; and from 2% to 10% of P 2 O 5 , wherein a total content of CaO, SrO and BaO is from 1% to 22%, a total content RO, which is a total content of MgO, CaO, SrO and BaO, is from 7% to 25%, a ratio CaO/RO, which is a ratio of a content of CaO to the total content RO, is 0.7 or less, and a ratio CaO/P 2 O 5 , which is a ratio of the content of CaO to a content of P 2 O 5 , is 0.59 or less.

2. The white glass according to claim 1 , wherein the white glass comprises: in terms of mole percentage on the basis of oxides, from 50% to 65% of SiO 2 ; from 0 to 8% of B 2 O 3 ; from 4.0% to 8% of Al 2 O 3 ; from 6.0 to 18% of MgO; from 0 to 5% of CaO; from 0 to 10% of SrO; from 0 to 12% of BaO; from 0 to 5% of ZrO 2 ; from 5% to 15% of Na 2 O; and from 2% to 10% of P 2 O 5 , wherein the total content of CaO, SrO and BaO is from 1% to 15%, the total content RO is from 10% to 25%, the ratio CaO/RO is 0.7 or less, and the ratio CaO/P 2 O 5 is 0.59 or less.

3. The white glass according to claim 1 , wherein the white glass comprises 6.0% less than 11% of MgO.

4. The white glass according to claim 1 , wherein the white glass comprises: from 55% to 62% of SiO 2 ; from 4.0% to 7% of Al 2 O 3 ; from 6.0% to 10% of MgO; from 8% to 12% of Na 2 O; and from 3% to 7% P 2 O 5 .

5. The white glass according to claim 1 , wherein the white glass comprises 9% or more of Na 2 O.

6. The white glass according to claim 1 , wherein the white glass comprises 0.5% or more of ZrO 2 .

7. The white glass according to claim 1 , wherein the white glass comprises 1% or more of BaO.

8. The white glass according to claim 1 , wherein the white glass comprises from 50% to 62.3% of SiO 2 .

9. The white glass according to claim 1 , wherein a crystal is not precipitated in the white glass.

10. The white glass according to claim 1 , wherein a linear transmittance of light having a wavelength of 600 nm of the white glass at a thickness of 1 mm is 2% or less.

11. The white glass according to claim 1 , wherein the white glass is for use in a building material.

12. The white glass according to claim 11 , wherein the white glass which is for an interior use of a gallery or tunnel.

13. A housing comprising the white glass according to claim 1 .

14. An electronic device, comprising the housing according to claim 13 .

15. The electronic device according to claim 14 , wherein the electronic device is a portable communication device or portable information device.

16. A white glass comprising: in terms of mole percentage on the basis of oxides, from 50% to 65% of SiO 2 ; from 0 to 8% of B 2 O 3 ; from 4.0% to 8% of Al 2 O 3 ; from 6.0 to 18% of MgO; from 0 to 5% of CaO; from 0 to 10% of SrO; from 0 to 12% of BaO; from 0 to 5% of ZrO 2 ; from 5% to 15% of Na 2 O; and from 2% to 10% of P 2 O 5 , wherein a total content of CaO, SrO and BaO is from 1% to 22%, a total content RO, which is a total content of MgO, CaO, SrO and BaO, is from 7% to 25%, a ratio CaO/RO, which is a ratio of a content of CaO to the total content RO, is 0.7 or less, a ratio CaO/P 2 O 5 , which is a ratio of the content of CaO to a content of P 2 O 5 , is 0.59 or less, and the white glass has a compressive stress layer in a surface thereof.

17. The white glass according to claim 16 , wherein the white glass comprises: in terms of mole percentage on the basis of oxides, from 50% to 65% of SiO 2 ; from 0 to 8% of B 2 O 3 ; from 4.0% to 8% of Al 2 O 3 ; from 6.0 to 18% of MgO; from 0 to 5% of CaO; from 0 to 10% of SrO; from 0 to 12% of BaO; from 0 to 5% of ZrO 2 ; from 5% to 15% of Na 2 O; and from 2% to 10% of P 2 O 5 , wherein the total content of CaO, SrO and BaO is from 1% to 20%, the total content RO is from 6% to 25%, the ratio CaO/RO is 0.7 or less, the ratio CaO/P 2 O 5 is 0.59 or less, and the white glass has the compressive stress layer in the surface thereof.

18. The white glass according to claim 16 , wherein the white glass comprises: in terms of mole percentage on the basis of oxides, from 50% to 65% of SiO 2 ; from 0 to 8% of B 2 O 3 ; from 4.0% to 8% of Al 2 O 3 ; from 6.0 to 18% of MgO; from 0 to 5% of CaO; from 0 to 10% of SrO; from 0 to 12% of BaO; from 0 to 5% of ZrO 2 ; from 5% to 15% of Na 2 O; and from 2% to 10% of P 2 O 5 , wherein the total content of CaO, SrO and BaO is from 1% to 15%, and the total content RO is from 10% to 25%.

19. The white glass according to claim 16 , wherein the white glass comprises from 50% to 62.3% of SiO 2 .

20. The white glass according to claim 16 , wherein the compressive stress layer has a thickness of 10 μm or more and a surface compressive stress of the compressive stress layer is 300 MPa or more.

21. The white glass according to claim 16 , wherein a total light reflectance of light having a wavelength of 600 nm of the white glass is 45% or more.

22. The white glass according to claim 16 , wherein the white glass is for use in a building material.

23. The white glass according to claim 22 , wherein the white glass is for an interior use of a gallery or tunnel.

24. A housing comprising the white glass according to claim 16 .

25. An electronic device, comprising the housing according to claim 24 .

26. The electronic device according to claim 25 , wherein the electronic device is a portable communication device or portable information device.

Assignments (2)
CHANGE OF NAME Recorded Aug 7, 2018
From: ASAHI GLASS COMPANY, LIMITED
To: AGC INC.
Reel/Frame 046730/0786 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 28, 2015
From: MIYASAKA, JUNKO; OHARA, SEIKI; KITAOKA, KENJI
To: ASAHI GLASS COMPANY, LIMITED
Reel/Frame 036197/0677 →