Micro-Porous Battery Substrate
This disclosure relates to a battery and a method for its manufacture. An example method includes forming a substrate having a first surface, the first surface having a plurality of pores. The pores may be configured to house lithium metal. The method includes incorporating lithium metal into at least a portion of the plurality of pores. The lithium metal may be incorporated into the pores via a pre-lithiation process, which may include electroplating of lithium metal into the porous substrate. The method also includes forming an electrolyte disposed between the first surface of the substrate and a cathode. The electrolyte is configured to reversibly transport lithium ions via diffusion between the substrate and the cathode. The method also includes forming the cathode. Some embodiments may provide the substrate to jointly serve as an anode and electrically-conductive current collector.
1 . A battery comprising:
a substrate comprising a first surface having a plurality of pores, wherein the plurality of pores is configured to house lithium metal;
a cathode; and
an electrolyte disposed between the first surface of the substrate and the cathode, wherein the electrolyte is configured to reversibly transport lithium ions via diffusion between the plurality of pores and the cathode.
2 . The battery of claim 1 , wherein the plurality of pores comprises a multi-layer, square lattice arrangement of pores, wherein the pores have a center-to-center spacing of 100 microns.
3 . The battery of claim 1 , wherein at least a portion of the plurality of pores have a pore diameter within a range between one and ten microns.
4 . The battery of claim 1 , wherein at least a portion of the plurality of pores are disposed in a random or pseudo-random sponge-like arrangement.
5 . The battery of claim 1 , wherein the substrate comprises an electrically-conductive material, wherein the electrically-conductive material comprises at least one of: copper (Cu) or nickel (Ni).
6 . The battery of claim 1 , wherein the substrate comprises a mesh, wherein the mesh comprises at least one of copper (Cu) or nickel (Ni).
7 . The battery of claim 1 , wherein the cathode comprises lithium cobalt oxide (LiCoO 2 ).
8 . The battery of claim 1 , wherein the battery comprises at least one of a jelly roll-type battery or a thin film-type battery.
9 . A method of manufacturing a battery, the method comprising:
forming a substrate having a first surface, the first surface having a plurality of pores, wherein the plurality of pores is configured to house lithium metal;
incorporating lithium metal into at least a portion of the plurality of pores;
forming an electrolyte disposed between the first surface of the substrate and a cathode, wherein the electrolyte is configured to reversibly transport lithium ions via diffusion between the substrate and the cathode; and
forming the cathode.
10 . The method of claim 9 , wherein the plurality of pores comprises a multi-layer, square lattice arrangement of pores, wherein the pores have a center-to-center spacing of 100 microns.
11 . The method of claim 9 , wherein at least a portion of the plurality of pores have a pore diameter within a range between one and ten microns.
12 . The method of claim 9 , wherein at least a portion of the plurality of pores are disposed in a random or pseudo-random sponge-like arrangement.
13 . The method of claim 9 , wherein the substrate comprises an electrically-conductive material, wherein the electrically-conductive material comprises at least one of: copper (Cu) or nickel (Ni).
14 . The method of claim 9 , wherein the substrate comprises a mesh, wherein the mesh comprises at least one of copper (Cu) or nickel (Ni).
15 . The method of claim 9 , wherein the cathode comprises lithium cobalt oxide (LiCoO 2 ).
16 . The method of claim 9 , further comprising forming a separator, wherein the separator comprises an electrically-insulating material, and wherein the separator is disposed proximate to at least one of the cathode or the substrate.
17 . The method of claim 9 , wherein forming the substrate comprises etching the substrate via a wet chemical etch.
18 . The method of claim 9 , wherein forming the substrate comprises forming the plurality of pores via electrochemical plating.
19 . The method of claim 9 , wherein incorporating the lithium metal comprises incorporating the lithium metal via an electrochemical plating process.
20 . The method of claim 9 , further comprising forming a jelly roll from a combination of at least the substrate, the electrolyte, and the cathode.