Separator having porous coating layer, and electrochemical device containing the same
View Patent ↗A separator includes a monolayer-type polyolefin-based micro-porous film having a porosity of 40 to 60%, an average pore diameter of 60 nm or less, and an air permeability of 350 s/100 mL or less; and a porous coating layer formed on at least one surface of the micro-porous film and made of a mixture of a plurality of inorganic particles and a binder polymer. An electrochemical device having the above separator has excellent thermal stability and allows a high power while minimizing the occurrence of leak current.
1. A separator, comprising:
a monolayer-type polyolefin-based micro-porous film having an air permeability of 350 s/100 mL or less; and
a porous coating layer formed on at least one surface of the micro-porous film and made of a mixture of a plurality of inorganic particles and a binder polymer,
wherein a weight ratio of the inorganic particles to the binder polymer in the porous coating layer is 50:50 to 99:1, and the air permeability of the separator is 500 s/100 mL or less, and
wherein the monolayer-type polyolefin-based micro-porous film has a porosity of 50-60% and an average pore diameter of 30 to 40 nm.
2. The separator according to claim 1 , wherein the porosity is 55 to 60%.
3. The separator according to claim 1 , wherein the separator has an ion conductivity of 1.4×10 −3 S/cm or above.
4. The separator according to claim 1 , wherein the polyolefin-based micro-porous film is made of a polymer selected from the group consisting of high-density polyethylene, low-density polyethylene, linear low-density polyethylene, ultrahigh molecular weight polyethylene, polypropylene, and mixtures thereof.
5. The separator according to claim 1 , wherein a loading weight of the porous coating layer to the polyolefin-based micro-porous film is 10 to 20 g/m 2 .
6. The separator according to claim 1 , wherein the porous coating layer has a pore size of 0.001 to 10 μm and a porosity of 10 to 90%.
7. The separator according to claim 1 , wherein the inorganic particles have an average diameter of 0.001 to 10 μm.
8. The separator according to claim 1 , wherein the binder polymer has a solubility parameter of 15 to 45 Mpa 1/2 .
9. The separator according to claim 1 , wherein the binder polymer is a binder polymer selected from the group consisting of polyvinylidene fluoride-co-hexafluoropropylene, polyvinylidene fluoride-co-trichloroethylene, polymethyl methacrylate, polyacrylonitrile, polyvinyl pyrrolidone, polyvinyl acetate, polyethylene-co-vinyl acetate, polyethylene oxide, cellulose acetate, cellulose acetate butyrate, cellulose acetate propionate, cyanoethyl pullulan, cyanoethyl polyvinyl alcohol, cyanoethyl cellulose, cyanoethyl sucrose, pullulan, carboxylmethyl cellulose, and mixtures thereof.
10. The separator according to claim 1 , wherein, when the polyolefin-based micro-porous film alone and the separator comprising the monolayer-type polyolefin-based film and the porous coating layer are kept in an oven at 150° C. for 30 minutes, a reduction ratio of the thermal shrinkage of the separator to the thermal shrinkage of the polyolefin-based micro-porous film is 40% or above.
11. The separator according to claim 1 , wherein, when the polyolefin-based micro-porous film alone and the separator comprising the monolayer-type polyolefin-based film and the porous coating layer are kept in an oven at 150° C. for 30 minutes, a reduction ratio of the thermal shrinkage of the separator to the thermal shrinkage of the polyolefin-based micro-porous film is 55% or above.
12. An electrochemical device, which includes a cathode, an anode, and a separator interposed between the cathode and the anode,
wherein the separator is a separator defined in the claim 1 .
13. The electrochemical device according to claim 12 , wherein the electrochemical device is a lithium secondary battery.
14. The electrochemical device according to claim 13 , wherein the lithium secondary battery is a lithium secondary battery for vehicles.