Electrically-conductive proppant and methods for making and using same
View Patent ↗Methods for manufacturing electrically-conductive proppant particles are disclosed. The methods can include preparing a slurry containing water, a binder, and a raw material having an alumina content, atomizing the slurry into droplets, and coating seeds containing alumina with the droplets to form a plurality of green pellets. The green pellets can be contacted with an activation solution containing at least one catalytically active material to provide activated green pellets including the at least one catalytically active material. The method can include sintering the activated green pellets to provide a plurality of proppant particles. The plurality of proppant particles can be contacted with a plating solution containing one or more electrically-conductive material to provide electrically-conductive proppant particles.
1. A method of manufacturing electrically-conductive proppant particles, comprising:
preparing a slurry comprising water, a binder, and a raw material having an alumina content;
atomizing the slurry into droplets;
coating seeds comprising alumina with the droplets to form a plurality of green pellets;
contacting the plurality of green pellets with an activation solution comprising at least one catalytically active material to provide activated green pellets comprising the at least one catalytically active material;
sintering the activated green pellets to provide a plurality of proppant particles, wherein the sintering oxidizes the catalytically active material; and
contacting the plurality of proppant particles with a plating solution comprising one or more electrically-conductive material to provide electrically-conductive proppant particles.
2. The method of claim 1 , wherein the electrically conductive proppant particles comprise a coating of the electrically-conductive material having a thickness of at least 10 nm formed on the outer surface of each said proppant particles.
3. The method of claim 1 , wherein the at least one catalytically active material comprises palladium.
4. The method of claim 3 , wherein the contacting of the plurality of green pellets with the activation solution comprises spraying the green pellets with the activation solution, wherein the activation solution is an aqueous solution.
5. The method of claim 1 , wherein the plurality of green pellets are contacted with an alkaline solution having a pH greater than 8 prior to contacting the activation solution.
6. The method of claim 1 , wherein the electrically-conductive material comprises nickel.
7. The method of claim 6 , wherein the plating solution is an alkaline solution comprising nickel.
8. The method of claim 1 , wherein the electrically-conductive material comprises nickel and the electrically conductive proppant particles comprise a coating of the electrically-conductive material having a thickness of from about 10 nm to about 1,500 nm formed on the outer surface of each said proppant particles.
9. The method of claim 8 , wherein the electrically-conductive material has a thickness of from about 10 nm to about 700 nm.
10. The method of claim 1 , wherein the activation solution is substantially free of reducing agent.
11. A method of manufacturing electrically-conductive proppant particles, comprising:
preparing a slurry comprising water, a binder, and a raw material having an alumina content;
atomizing the slurry into droplets;
coating seeds comprising alumina with the droplets to form a plurality of green pellets;
sintering the green pellets to provide a plurality of proppant particles;
contacting the plurality of proppant particles with an activation solution comprising at least one catalytically active material and drying the activation solution on the particles to provide activated proppant particles comprising the at least one catalytically active material; and
contacting the plurality of activated proppant particles with a plating solution comprising one or more electrically-conductive material to provide electrically-conductive proppant particles.
12. The method of claim 11 , wherein the electrically conductive proppant particles comprise a coating of the electrically-conductive material having a thickness of at least 10 nm formed on the outer surface of each said proppant particles.
13. The method of claim 11 , wherein the at least one catalytically active material comprises palladium.
14. The method of claim 13 , wherein the contacting of the plurality of proppant particles with the activation solution comprises spraying the green pellets with the activation solution, wherein the activation solution is an aqueous solution.
15. The method of claim 11 , wherein the plurality of green pellets are contacted with an alkaline solution having a pH greater than 8 prior to sintering.
16. The method of claim 11 , wherein the electrically-conductive material comprises nickel.
17. The method of claim 16 , wherein the plating solution is an alkaline solution comprising nickel.
18. The method of claim 11 , wherein contacting the plurality of proppant particles with an activation solution is performed while drying the activation solution.
19. The method of claim 11 , wherein the activation solution is substantially free of reducing agent.