Positive active material for secondary lithium battery, method for preparing the same and secondary lithium battery containing the positive active material
The present invention provides a positive active material for use in a secondary lithium battery, a method for preparing the positive active material and a secondary lithium battery containing the positive active material. The positive active material includes a core of lithium transition metal oxide represented by Formula Li x M y N 1-y O 2-α A β and a coating layer of lithium transition metal silicate represented by Formula x′Li 2 O.y′N′O a .SiO 2-λ B ζ which in-situ formed on the core, wherein 0.8≤x≤1.3, 0.6≤y≤1.0, 0.01≤x′≤2.1, 0.2≤y′≤1.5, 0.1≤a≤3.0, 0≤α≤0.2, 0≤β≤0.4, 0≤λ≤0.5, 0≤ζ≤0.5. The positive active material according to the present invention has high capacity, desirable cycling performance and safety performance, as well as desirable thermal stability.
1. A positive active material for a secondary lithium battery, comprising:
a core of lithium transition metal oxide represented by Formula Li x M y N 1-y O 2-α A β and a coating layer of lithium transition metal silicate represented by Formula x′Li 2 O.y′N′O a .SiO 2-λ B ζ which in-situ formed on the core,
wherein element represented by M is at least one of Ni, Co and Mn; element represented by N and N′ each is at least one of Na, K, Rb, Cs, Be, Mg, Ca, Sr, Ba, Ra, Al, Ga, In, Ge, Sn, Sc, Ti, B, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Y, Zr, Nb, Mo, W, Ru, Rh, Pd, Ag, Cd, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu; element represented by A and B each is at least one of N, F, P, 5, Cl, Se; and 0.8≤x≤1.3, 0.6≤y≤1.0, 0.01≤x′≤2.1, 0.2≤y′≤1.5, 0.1≤a≤3.0, 0≤α≤0.2, 0≤β≤0.4, 0≤λ≤0.5, 0≤ζ≤0.5.
2. The positive active material of claim 1 , wherein in the lithium transition metal oxide represented by Formula Li x M y N 1-y O 2-α A β , the element represented by M is combination of elements Ni, Co, Mn; and the element represented by N is at least one of Mg, Al, Ti, B, V, Mo, W, Ni, Co, Mn, Y, Ce; 0.7≤y≤1.0.
3. The positive active material of claim 2 , wherein the element represented by M in the lithium transition metal oxide represented by Formula Li x M y N 1-y O 2-α A β is Co, Ni 0.5 Co 0.5 , Ni 0.7 Co 0.3 , Ni 0.8 Co 0.2 , Ni 0.9 Co 0.1 , Ni 1/3 Co 1/3 Mn 1/3 , Ni 0.5 Co 0.2 Mn 0.3 , Ni 0.6 Co 0.2 Mn 0.2 , Ni 0.8 Co 0.01 Mn 0.1 or combinations thereof.
4. The positive active material of claim 1 , wherein the element represented by N in Formula Li x M y N 1-y O 2-α A β is at least one of Mg, Al, Ti, B, Mo, Zr, V, Ce, W, and 0.95≤y≤1.0.
5. The positive active material of claim 1 , wherein the element represented by A in the lithium transition metal oxide represented by Formula Li x M y N 1-y O 2-α A β is N and/or F, and 0≤β≤0.1.
6. The positive active material of claim 1 , wherein the element represented by B in the lithium transition metal silicate represented by Formula x′Li 2 O.y′N′O a .SiO 2-λ B ζ is N and/or F, and 0≤ζ≤0.2.
7. The positive active material of claim 1 , wherein in the lithium transition metal silicate represented by Formula x′Li 2 O.y′N′O a .SiO 2-λ B ζ , 0.1≤x′≤1, 0.2≤y′≤1.0.
8. The positive active material of claim 1 , wherein the coating layer of lithium transition metal silicate represented by Formula x′Li 2 O.y′N′O a .SiO 2-λ B ζ is Li 2 O.N′O.SiO 2-λ B ζ , 0.5Li 2 O.N′O 1.5 .Si 2-λ B ζ ,Li 2 O.N′O 2 .SiO 2-λ B ζ or combinations thereof.
9. The positive active material of claim 1 , wherein the weight content of the coating layer of lithium transition metal silicate represented by Formula x′Li 2 O.y′N′O a .SiO 2-λ B ζ in the positive active material is 0.01%-30%.
10. A secondary lithium battery, comprising a positive electrode, a negative electrode and a separator between the positive electrode and the negative electrode, wherein the positive electrode comprises the positive active material of claim 1 .
11. The positive active material of claim 1 , wherein in the lithium transition metal oxide represented by Formula Li x M y N 1-y O 2-α A β ,the element represented by M is one or two of Ni, Co, and the element represented by N is one or more of the Mg, Al, Ti, B, V, Mo, W, Ni, Co, Mn, Y, Ce; 0.7≤y≤1.0.
12. The positive active material of claim 1 , wherein the element represented by N in Formula Li x M y N 1-y O 2-α A β is at least one of Mg, Al, Ti, B, Mo, Zr, V, Ce, W, and 0.99≤y≤1.0.
13. The positive active material of claim 1 , wherein the weight content of the coating layer of the lithium transition metal silicate represented by Formula x′Li 2 O.y′N′O a .SiO 2-λ B ζ in the positive active material is 0.01%-5.0%.