Fluorescent lighting with aluminum nitride phosphors
View Patent ↗A fluorescent lamp includes a glass envelope; at least two electrodes connected to the glass envelope; mercury vapor and an inert gas within the glass envelope; and a phosphor within the glass envelope, wherein the phosphor blend includes aluminum nitride. The phosphor may be a wurtzite (hexagonal) crystalline structure Al (1-x) M x N phosphor, where M may be drawn from beryllium, magnesium, calcium, strontium, barium, zinc, scandium, yttrium, lanthanum, cerium, praseodymium, europium, gadolinium, terbium, ytterbium, bismuth, manganese, silicon, germanium, tin, boron, or gallium is synthesized to include dopants to control its luminescence under ultraviolet excitation. The disclosed Al (1-x) M x N:Mn phosphor provides bright orange-red emission, comparable in efficiency and spectrum to that of the standard orange-red phosphor used in fluorescent lighting, Y 2 O 3 :Eu. Furthermore, it offers excellent lumen maintenance in a fluorescent lamp, and does not utilize “critical rare earths,” minimizing sensitivity to fluctuating market prices for the rare earth elements.
1. A fluorescent lamp, comprising:
a glass envelope;
at least two electrodes connected to said glass envelope;
mercury vapor and an inert gas within said glass envelope; and
a phosphor blend within said glass envelope, wherein said phosphor blend includes Al (1-x) M x N, where M may be comprised of one or more dopants drawn from beryllium, magnesium, calcium, strontium, barium, zinc, scandium, yttrium, lanthanum, cerium, praseodymium, europium, gadolinium, terbium, ytterbium, bismuth, manganese, silicon, germanium, tin, boron, or gallium and x has a value of 0<x<0.1.
2. The fluorescent lamp of claim 1 wherein said Al (1-x) M x N is doped with at least M=manganese; wherein x has the value of 0<x<0.1.
3. The fluorescent lamp of claim 1 wherein said Al (1-x) M x N contains between about 0.001% and 10% manganese.
4. The fluorescent lamp of claim 1 wherein said Al (1-x) M x N is in the form of a powder with grains in the 0.1-50 micron range.
5. The fluorescent lamp of claim 4 wherein said powder is deposited onto the surface of the lamp envelope.
6. The fluorescent lamp of claim 1 wherein said Al (1-x) M x N phosphor is doped with carbon and/or oxygen, together with manganese by processing conditions or addition of dopants to induce an absorption at 254 nm and emission in at least a portion of the spectral region visible to the human eye.
7. The fluorescent lamp of claim 6 wherein said emission is in the orange-red, most preferably near 570-650 nm.
8. The fluorescent lamp of claim 6 wherein said emission has a quantum efficiency of at least 50% with respect to absorbed photons at 254 nm.
9. The fluorescent lamp of claim 1 wherein said phosphor is doped by using a starting material selected from a manganese oxide, a manganese halide, manganese carbonate, manganese nitrate, a manganese-containing salt, manganese nitride, manganese metal, an organo-manganese compound or a manganese-containing aluminum alloy.
10. The fluorescent lamp of claim 1 wherein said doping is incorporated in a reducing atmosphere or an oxygen-free atmosphere.
11. The fluorescent lamp of claim 1 wherein said phosphor is processed to reduce the surface's sensitivity to water in a fluorescent lamp.
12. The fluorescent lamp of claim 1 wherein said phosphor is processed by heating in an atmosphere of more than 90% nitrogen.
13. The fluorescent lamp of claim 1 wherein said phosphor is processed by heating in an atmosphere wherein gas pressure is more than 1 atmosphere.
14. The fluorescent lamp of claim 1 wherein said phosphor is processed at temperature of at least 1500° C.
15. The fluorescent lamp of claim 1 wherein said phosphor is processed at temperature above 1700° C.
16. The fluorescent lamp of claim 1 wherein said surface of said phosphor is post-processed in a reactive solution or vapor.
17. The fluorescent lamp of claim 1 wherein said surface of said phosphor is processed in an acidic solution, most preferably phosphoric acid.
18. The fluorescent lamp of claim 1 , wherein said phosphor has a CIE coordinate of about X=0.60±0.05 and Y=0.37±0.05.
19. The fluorescent lamp of claim 1 wherein said phosphor blend is combined with at least one additional phosphor to create another color of light.
20. The fluorescent lamp of claim 1 wherein said phosphor blend does not include rare earths.
21. A method of making a fluorescent lamp, comprising the steps of:
heating Al (1-x) M x N powder under flowing nitrogen gas;
adding a source of Mn, thereby producing an Al (1-x) M x N:Mn phosphor;
providing a glass envelope;
providing mercury vapor, an inert gas, and said Al (1-x) M x N:Mn phosphor within said glass envelope, and
providing at least two electrodes connected to said glass envelope to produce the fluorescent lamp.
22. The method of making a fluorescent lamp of claim 21 wherein said Al (1-x) M x N is doped with manganese.
23. The method of making a fluorescent lamp of claim 21 wherein said wherein said powder is deposited onto the surface of the glass envelope.
24. The method of making a fluorescent lamp of claim 21 wherein said phosphor is post-processed by heating in air or oxygen at a temperature above room temperature, preferably above 500° C.
25. The method of making a fluorescent lamp of claim 21 wherein said phosphor is combined with at least one additional phosphor to create another color of light.
26. The method of making a fluorescent lamp of claim 21 wherein the fluorescent lamp does not include rare earths.