Magnesium phosphate cement based bipolar plate composite material
View Patent ↗This invention provides a composite material for bipolar plates for fuel cells including cemented by a MPC binder and electrically conductive fillers, and a method of manufacturing the same. The resulting bipolar plate achieves low gas permeability, high electrical conductivity, high flexural strength and good corrosion resistance. The flexural strength and corrosion resistance can further be enhanced by the incorporation of macro-reinforcement and a polymer based surface treatment, respectively.
1. A bipolar plate composite material comprising:
an inorganic cement based binder with grains; and
an electrically conductive filler selected from a group consisting of graphite powder, carbon black, carbon nanotubes, carbon fibers, and any combination thereof;
wherein a particle size of said electrically conductive filler is at least one order of magnitude smaller than a particle size of said grains in said inorganic cement based binder such that a distribution of particles of said electrically conductive filler are restricted in a space that is limited by particles of said inorganic cement based binder to form a percolated conductive pathway with an electrical conductivity greater than 100 S/cm,
wherein said inorganic cement based binder has a pH value of 6-8 and a flexural strength greater than 10 MPa.
2. The bipolar plate composite material of claim 1 , wherein said inorganic cement based binder is magnesium phosphate cement based binder that includes magnesia, potassium di-hydrogen phosphate, borax and water; the magnesia-to-potassium di-hydrogen phosphate molar ratio of said inorganic cement based binder is 6-12:1.
3. The bipolar plate composite material of claim 2 , wherein said magnesia is dead burnt magnesia.
4. The bipolar plate composite material of claim 2 , wherein in said inorganic cement based binder, said borax is 5% of the weight of said magnesia; and water-to-cement ratio by weight is 0.2-0.3.
5. The bipolar plate composite material of claim 2 , wherein said inorganic cement based binder further comprises fly ash replacing 20-40% of mass of said magnesia in said inorganic cement based binder.
6. The bipolar plate composite material of claim 1 , wherein said electrically conductive filler is loaded at 40-56% of a total volume of said inorganic cement based binder.
7. The bipolar plate composite material of claim 2 further comprising:
a composition of 52% by volume of said inorganic cement based binder and 48% by volume of said electrically conductive filler;
wherein said electrically conductive filler comprises 45% by volume of said graphite powder; 1% by volume of said carbon fibers; and 2% by volume of said carbon nanotubes,
wherein said inorganic cement based binder comprises a composition of 38.05% by weight of said magnesia; 22.93% by weight of said potassium di-hydrogen phosphate; 2.72% by weight of said borax; 16.3% by weight of fly ash; and 20% by weight of said water.
8. A bipolar plate composite material comprising:
a magnesium phosphate cement based binder; and
electrically conductive fillers;
wherein said binder is a multi-component inorganic binder comprising magnesia, potassium di-hydrogen phosphate, borax and water; the magnesia-to-potassium di-hydrogen phosphate molar ratio of said binder is 6-12:1;
wherein said fillers are selected from a group consisting of graphite powder, carbon black, carbon nanotubes, carbon fibers, and any combination thereof.
9. The bipolar plate composite material of claim 8 , wherein said binder further comprises fly ash replacing 20-40% of weight of said magnesia in said binder.
10. The bipolar plate composite material of claim 9 further comprising:
a composition of 52% by volume of said binder and 48% by volume of said filler;
wherein said fillers comprise 45% by volume of said graphite powder; 1% by volume of said carbon fibers; and 2% by volume of said carbon nanotubes,
wherein said binder comprises a composition of 38.05% by weight of said magnesia; 22.93% by weight of said potassium di-hydrogen phosphate; 2. 72% by weight of said borax; 16.3% by weight of said fly ash; and 20% by weight of said water.