Polarizing plate and liquid crystal display comprising the same
A polarizing plate includes a polarizer, and a polyester film formed on one or both surfaces of the polarizer. The polyester film has a tensile strength ratio of about 3 or greater, as calculated by Equation 4, and an orientation displacement (°) of about −5° to about +5° with respect to a transverse direction (slow axis) of the polyester film at a wavelength of 550 nm. A liquid crystal display apparatus includes the polarizing plate Tensile strength ratio=TD tensile strength/MD tensile strength Equation 4.
1. A polarizing plate, comprising:
a polarizer; and
a polyester film on a surface of the polarizer,
wherein the polyester film has a tensile strength ratio of 3 or greater, as calculated by Equation 4, and an orientation displacement) (°) of about −5° to about +5°, the orientation displacement being an angle at which a transverse direction (TD) of the polyester film is displaced with respect to a transverse direction of the polyester film at a wavelength of 550 nm:
Tensile strength ratio=TD tensile strength/MD tensile strength, Equation 4
In Equation 4, TD tensile strength is a tensile strength of the polyester film in the transverse direction, and MD tensile strength is a tensile strength of the polyester film in the machine direction; and
wherein the TD tensile strength of the polyester film is 200 MPa to 400 MPa, and the MD tensile strength of the polyester film is 60 MPa to 120 MPa.
2. The polarizing plate according to claim 1 , wherein the polarizing plate has an angle (Θr−p) between an absorption axis (Θp) of the polarizer and an optical axis (Θr) of the polyester film of about −0.3° to about +0.3°.
3. The polarizing plate according to claim 1 , wherein the polyester film has an in-plane retardation (Ro) at a wavelength of 550 nm of about 5,000 nm to about 15,000 nm.
4. The polarizing plate according to claim 1 , wherein the polyester film has a degree of biaxiality (NZ) at a wavelength of 550 nm of about 1.8 or lower, as calculated by Equation 1:
NZ =( nx−nz )/( nx−ny ), Equation 1
wherein nx, ny and nz are indices of refraction at a wavelength of 550 nm in x-, y- and z-axis directions of the polyester film, respectively.
5. The polarizing plate according to claim 1 , wherein the polyester film comprises at least one of polyethylene terephthalate, polybutylene terephthalate, polyethylene naphthalate, and/or polybutylene naphthalate.
6. The polarizing plate according to claim 1 , further comprising:
at least one of an optical film, a coating layer and/or an adhesive layer formed on an other surface of the polarizer.
7. The polarizing plate according to claim 6 , wherein the optical film has an in-plane retardation (Ro) at a wavelength of 550 nm of about 40 to about 60 nm.
8. The polarizing plate according to claim 6 , wherein the optical film comprises at least one of a cellulose resin, a polyester resin, a cyclic polyolefin resin, a polycarbonate resin, a polyethersulfone resin, a polysulfone resin, a polyamide resin, a polyimide resin, a polyolefin resin, a polyarylate resin, a polyvinyl alcohol resin, a polyvinyl chloride resin, and/or a polyvinylidene chloride resin.
9. The polarizing plate according to claim 1 , wherein the polarizing plate has a variation rate of a polarization degree of about 0.00 to about 0.05%, as calculated by Equation 3:
Variation rate of polarization degree=| P 2− P 1|/ P 1×100 Equation 3
wherein P1 is an initial degree of polarization of the polarizing plate, and P2 is a degree of polarization of the polarizing plate after being left at about 85° C. for about 500 hours.
10. A liquid crystal display comprising the polarizing plate according to claim 1 .
11. The liquid crystal display according to claim 10 , wherein the polarizing plate has an angle (Θr−p) between an absorption axis (Θp) of the polarizer and an optical axis (Θr) of the polyester film of about −0.3° to about +0.3°.
12. The liquid crystal display according to claim 10 , wherein the polyester film has in-plane retardation (Ro) at a wavelength of 550 nm of about 5,000 nm to about 15,000 nm.
13. The liquid crystal display according to claim 10 , wherein the polyester film has a degree of biaxiality (NZ) at a wavelength of 550 nm of about 1.8 or lower, as calculated by Equation 1:
NZ =( nx−nz )/( nx−ny ), Equation 1
wherein nx, ny and nz are indices of refraction at a wavelength of 550 nm in x-, y- and z-axis directions of the polyester film, respectively.
14. The liquid crystal display according to claim 10 , wherein the polyester film comprises at least one of polyethylene terephthalate, polybutylene terephthalate, polyethylene naphthalate, and/or polybutylene naphthalate.
15. The liquid crystal display according to claim 10 , wherein the polarizing plate further comprises:
at least one of an optical film, a coating layer and/or an adhesive layer formed on an other surface of the polarizer.
16. The liquid crystal display according to claim 15 , wherein the optical film has an in-plane retardation (Ro) at a wavelength of 550 nm of about 40 to about 60 nm.
17. The liquid crystal display according to claim 15 , wherein the optical film comprises at least one of a cellulose resin, a polyester resin, a cyclic polyolefin resin, a polycarbonate resin, a polyethersulfone resin, a polysulfone resin, a polyamide resin, a polyimide resin, a polyolefin resin, a polyarylate resin, a polyvinyl alcohol resin, a polyvinyl chloride resin, and/or a polyvinylidene chloride resin.
18. The liquid crystal display according to claim 10 , wherein the polarizing plate has a variation rate of a polarization degree of about 0.00 to about 0.05%, as calculated by Equation 3:
Variation rate of polarization degree=| P 2− P 1|/ P 1×100 Equation 3
wherein P1 is an initial degree of polarization of the polarizing plate, and P2 is a degree of polarization of the polarizing plate after being left at about 85° C. for about 500 hours.