Micro and nanofibers of polysaccharide based materials
View Patent ↗Described herein are apparatuses and methods of creating fibers, such as microfibers and nanofibers, that are composed of saccharides. The methods discussed herein employ centrifugal forces to transform saccharide material into fibers. Apparatuses that may be used to create saccharide fibers are also described. Fiber producing devices with features that enhance fiber production and adaptability to different types of fiber are described.
1. A method of producing microfibers and/or nanofibers, comprising:
placing a composition into a fiber producing device comprising one or more openings, wherein the composition comprises a polysaccharide, a carrier and a solvent capable of dissolving at least a portion of the polysaccharide and the carrier; and
rotating the fiber producing device about a spin axis such that rotation of the fiber producing device causes at least a portion of the composition disposed in the fiber producing device to be ejected through the one or more of the openings and form fibers comprising the polysaccharide as the ejected composition solidifies;
collecting at least a portion of the produced microfibers and/or nanofibers; and
wherein the weight % of polysaccharide/carrier to solvent ranges from 2% to about 30%.
2. The method of claim 1 , wherein the polysaccharide is a cellulose ester.
3. The method of claim 1 , wherein the polysaccharide is cellulose acetate.
4. The method of claim 1 , wherein the carrier is a polymer.
5. The method of claim 1 , wherein the carrier comprises polyethylene oxide.
6. The method of claim 1 , wherein the solvent comprises acetone.
7. The method of claim 1 , wherein the solvent is a mixture of acetone and dimethylacetamide.
8. The method of claim 1 , wherein the solvent is a mixture of two or more solvents.
9. The method of claim 1 , wherein the weight % ratio of polysaccharide to the carrier in the composition ranges from about 50:50 to about 99:1.
10. The method of claim 1 , further comprising:
forming a composition of the polysaccharide and a polyethylene oxide carrier in the solvent by mixing the components at a temperature of between about 25° C. and 100° C. for a time of about 1 hour to about 8 hours; and
filtering the formed composition through a wire mesh having micron rating of between about 2 microns to about 50 microns.
11. The method of claim 10 , further comprising conditioning the composition by heating the composition to a processing temperature and allowing the composition to remain at the processing temperature for a time of about 30 minutes to about 5 hours.
12. The method of claim 10 , further comprising conditioning the composition by heating the composition to a temperature of between about 25° C. and 100° C. for a time of about 30 minutes to about 5 hours prior to placing the composition into the fiber producing device.
13. The method of claim 1 , further comprising heating the fiber producing device to a temperature sufficient to maintain the temperature of the material disposed in the fiber producing device at a temperature above about 25° C.
14. The method of claim 1 , further comprising activating a substrate transfer system to move at least a portion of a substrate over a substrate support positioned below the fiber producing device.
15. The method of claim 1 , wherein the fibers produced have an average diameter ranging from about 300 nm to about 20 microns.
16. A method of producing microfiber and/or nanofibers, comprising:
placing a composition into a fiber producing device comprising one or more openings, wherein the composition comprises a polysaccharide, a carrier and a solvent capable of dissolving at least a portion of the polysaccharide and the carrier;
altering the viscosity of the composition to a preselected viscosity by altering the ratio of polysaccharide/carrier to solvent prior to placing the composition in the fiber producing device, wherein the preselected viscosity produces fibers having a predetermined average diameter;
rotating the fiber producing device about a spin axis such that rotation of the fiber producing device causes at least a portion of the composition disposed in the fiber producing device to be ejected though the one or more of the opening and from fibers comprising the polysaccharide as the ejected comprising solidifies:
activating a substrate transfer system to move at least a portion of the substrate over a substrate support positioned below the fiber producing device; and
collecting at least a portion of the produced microfibers and/or nanofibers.