Curable acrylate or methacrylate compositions
A curable composition based on a curable acrylate or methacrylate component; an organoborane initiator component; a vinyl ether component; and an activator for the organoborane component. The composition exhibits good storage stability and good bonding properties when used to bond low surface energy substrates.
1. A curable composition comprising:
a curable (meth)acrylate component comprising the combination of at least two (meth)acrylate monomers, at least one of which is tetrahydrofurfuryl (meth)acrylate;
an organoborane:triethylene diamine complex;
an initiator component for the organoborane component comprising a vinyl ether component; and
an activator for the organoborane component, wherein the vinyl ether component is present in an amount of 0.25 to 5% weight based on the total composition and is a member selected from the group consisting of bis[4-(vinyloxy)butyl]isophthalate, ethyl vinyl ether, n-butyl vinyl ether, iso-butyl vinyl ether, t-butyl vinyl ether, cyclohexyl vinyl ether, 1,4-cyclohexanedimethanol divinyl ether, 1,4-cyclohexanedimethanol mono vinyl ether, 2-ethylhexyl vinyl ether, dodecyl vinyl ether, octadecyl vinyl ether, 1,4-butanediol divinyl ether, diethyleneglycol divinyl ether, triethyleneglycol divinyl ether, hydroxybutyl vinyl ether,
and combinations thereof, wherein the curable composition is in a two-part form with the curable (meth)acrylate component present in at least one of Part A or Part B, wherein
Part A comprises the organoborane:triethylene diamine complex and the vinyl ether initiator component; and Part B comprises the activator for the organoborane component and wherein the curable composition is substantially free of added anti-oxidants, free radical stabilizers or organo aluminum compounds.
2. A composition according to claim 1 wherein the organoborane:triethylene diamine complex is present in an amount from about 0.1 to about 10% weight percentage based on the total weight of the composition.
3. A composition according to claim 1 wherein the activator for the organoborane compound is selected from the group consisting of Lewis acids, carboxylic acids, phosphoric acids, anhydrides and isocyanates and combinations thereof.
4. A composition according to claim 1 wherein the activator is present in an amount from about 1 to about 40% weight percentage based on the total weight of the composition.
5. A composition according to claim 1 wherein the (meth)acrylate component is present in an amount from about 10 to about 95% weight percentage based on the total weight of the composition.
6. A composition according to claim 1 wherein the second part comprises a curable maleate, fumarate or maleimide component.
7. A composition according to claim 6 wherein the maleate, fumarate or maleimide component is present in an amount from about 1 to about 20% weight percentage based on the total weight of the composition.
8. A composition according to claim 1 further comprising a toughener component.
9. A composition according to claim 8 wherein the toughener component is present in an amount from about 5 to about 50% weight percentage based on the total weight of the composition.
10. A curable composition consisting of:
a curable (meth)acrylate component comprising the combination of at least two (meth)acrylate monomers, at least one of which is tetrahydrofurfuryl (meth)acrylate;
an organoborane:triethylene diamine complex;
an initiator component for the organoborane component comprising a vinyl ether component; and
an activator for the organoborane component, wherein the vinyl ether component is present in an amount of 0.25 to 5% weight based on the total composition and is a member selected from the group consisting of bis[4-(vinyloxy)butyl]isophthalate, ethyl vinyl ether, n-butyl vinyl ether, iso-butyl vinyl ether, t-butyl vinyl ether, cyclohexyl vinyl ether, 1,4-cyclohexanedimethanol divinyl ether, 1,4-cyclohexanedimethanol mono vinyl ether, 2-ethylhexyl vinyl ether, dodecyl vinyl ether, octadecyl vinyl ether, 1,4-butanediol divinyl ether, diethyleneglycol divinyl ether, triethyleneglycol divinyl ether, hydroxybutyl vinyl ether,
and combinations thereof, wherein the curable composition is in a two-part form with the curable (meth)acrylate component present in at least one of Part A or Part B, wherein
Part A comprises the organoborane:triethylene diamine complex and the vinyl ether initiator component; and Part B comprises the activator for the organoborane component and wherein the curable composition is substantially free of added anti-oxidants, free radical stabilizers or organo aluminum compounds.