Reaction products and methods for making and using same
View Patent ↗Reaction products and methods for making and using the same are provided. The reaction products particularly may include adducts of two or more reactants. The adducts particularly can incorporate a nitrification inhibitor, such as DCD. In particular embodiments, reaction products may be formed from the reaction of formaldehyde, DCD, urea, and an ammonia source. The adducts may be included in agricultural products, including fertilizer compositions and nitrification inhibitor systems. Fertilizer compositions including the adducts can be beneficial for reducing leaching of nitrification inhibitors applied to soil.
1. An agricultural composition comprising:
A) a material selected from the group consisting of urea, DCD, urea-formaldehyde polymer (UFP), ammonia, and combinations thereof; and
B) at least one adduct according to the structure of Formula 4
wherein:
X is O or
R 1 , R 2 , R 3 , and R 4 are independently selected from the group consisting of:
and
wherein, if X═O,
at least one of R 1 , R 2 , R 3 , and R 4 is
2. The composition according to claim 1 , wherein the at least one adduct includes an adduct according to the structure of Formula 5 or Formula 6:
3. The composition according to claim 2 , wherein the adduct according to the structure of Formula 5 or Formula 6 is present at a concentration of about 0.1 to about 10 wt. % based on the total weight of the composition.
4. The composition according to claim 2 , wherein the adduct according to Formula 5 and the adduct according to Formula 6 are both present in the composition.
5. The composition according to claim 1 , wherein the composition is an aqueous mixture.
6. The composition according to claim 5 , wherein the aqueous mixture has a pH of 7 or greater.
7. The composition according to claim 5 , wherein the aqueous mixture comprises 2-cyano-1-(4-oxo-1,3,5-triazinan-1-yl)methyl)guanidine, 1-((2-cyanoguanidino)methyl)urea, and DCD.
8. The composition according to claim 7 , wherein the aqueous mixture further comprises urea.
9. The composition according to claim 7 , wherein the aqueous mixture further comprises ammonia.
10. The composition according to claim 7 , wherein the aqueous mixture further comprises 2-cyano-1-((2-cyanoguanidino)methyl)guanidine.
11. The composition according to claim 1 , wherein the ammonia source excludes ammonium chloride.
12. A nitrification inhibitor system comprising a mixture of:
a. a triazonyl-formaldehyde-DCD adduct; and
b. a urea-formaldehyde-DCD adduct.
13. The nitrification inhibitor system according to claim 12 , comprising about 0.1 to 10 wt. % of the triazonyl-formaldehyde-DCD adduct based upon the weight of the nitrification inhibitor system.
14. The nitrification inhibitor system according to claim 12 , comprising about 0.1 to 10 wt. % of the urea-formaldehyde-DCD adduct based upon the weight of the nitrification inhibitor system.
15. The nitrification inhibitor system according to claim 12 , further comprising about 0.1 to 10 wt. % of a DCD-formaldehyde-oligomer adduct based upon the weight of the nitrification inhibitor system.
16. The nitrification inhibitor system according to claim 12 , wherein the mixture further comprises water.
17. The nitrification inhibitor system according to claim 12 , wherein the mixture further comprises free DCD.
18. The nitrification inhibitor system according to claim 12 , wherein the mixture comprises 2-cyano-1-((4-oxo-1,3,5-triazinan-1-yl)methyl)guanidine and 1-((2-cyanoguanidino)methyl)urea.
19. The nitrification inhibitor system according to claim 18 , further comprising 2-cyano-1-((2-cyanoguanidino)methyl)guanidine.
20. A method for reducing nitrification in soil, the method comprising applying the agricultural composition of claim 1 to the soil such that nitrification of a nitrogen source in the soil is reduced.
21. The method according to claim 20 , wherein the nitrogen source is combined with the agricultural composition prior to applying the agricultural composition to the soil.
22. The method according to claim 20 , wherein any one of the following conditions is met:
the amount of the agricultural composition applied to the soil ranges from about 1 kg/ha to about 50 kg/ha;
the method comprises applying the nitrogen source to the soil prior to applying the agricultural composition to the soil;
the agricultural composition is applied to the soil before a nitrogen source is applied to the soil.