IP Library Granted Patent US 10,105,677
Granted Patent B2
US 10,105,677 · App. 14/854,241 · Granted Oct 23, 2018

Sorbent

Inventors: Andrew Fish (Stockton-on-Tees, GB); Lucy Jane Challis (Bishop Auckland, GB); Matthew John Cousins (Darlington, GB); Mark Robert Feaviour (Reading, GB); Alison Mary Wagland (Oxford, GB); Stephen David Pollington (Washington, GB); Edmund Hugh Stitt (Billingham, GB)
Assignee: Johnson Matthey PLC
B01J20/0237B01D15/20B01D53/64B01J20/0222B01J20/0229B01J20/0285B01J20/06B01J20/08B01J20/2803B01J20/28004B01J20/28014B01J20/28045B01J20/28057B01J20/28059B01J20/28071B01J20/28073B01J20/28083B01J20/28085B01J20/3021B01J20/3042B01J20/3078B01J20/3204B01J20/3236B01J20/3433B01J20/3458B05D1/02B05D1/18C02F1/281C07C7/12C10G25/00C10L3/101B01D2253/1128B01D2253/342B01D2255/20761B01D2257/602B01J20/32B01J2220/56C02F2101/20C10L2290/542
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Quick Facts
Patent No.
US 10,105,677
App. No.
14/854,241
Granted
Oct 23, 2018
Kind
B2
Abstract

A method for preparing a sorbent composition includes the steps of: applying, from a solution or a slurry, a layer of a copper compound on the surface of a support material, and drying the coated support material, wherein the thickness of the copper compound layer on the dried support is in the range 1-200 μm. The precursor may be converted to a sorbent suitable for removing heavy metals from liquids or gases by applying one or more sulphur compounds to sulphide the copper compound and form CuS.

Claims (27)

1. A sorbent composition comprising an eggshell layer consisting of at least one copper compound and a binder material of alumina or hydrated alumina on the exterior surface of a support material, wherein:

the support material is in the form of a shaped particulate unit with a diameter or width in the range of 1-10 mm,

the eggshell layer has a thickness in the range of 1-200 μm, and

the sorbent composition comprises 0.5 to 20% by weight of copper.

2. The sorbent composition according to claim 1 , wherein the at least one copper compound comprises copper (II) sulphide.

3. The sorbent composition according to claim 1 , wherein the at least one copper compound is basic copper carbonate or copper (II) oxide.

4. The sorbent composition according to claim 1 , wherein the support material comprises an alumina, hydrated alumina, titania, zirconia, silica or aluminosilicate, or a mixture of two or more of these.

5. The sorbent composition according to claim 1 , wherein the support material is an alumina.

6. The sorbent composition according to claim 1 wherein the support material is in the form of shaped particulate unit that is a sphere, ring, trilobe, quadralobe, or cylinder.

7. The sorbent composition according to claim 6 , wherein the support material has between 2 and 10 holes extending therethrough.

8. The sorbent composition according to claim 1 , wherein the support material has a BET surface area in the range of 10-330 m 2 ·g −1 and a pore volume in the range of 0.3-0.9 cm 3 ·g −1 .

9. The sorbent composition according to claim 1 , wherein the thickness of the layer is in the range of 1 to 150 μm.

10. The sorbent composition according to claim 1 , wherein the sorbent comprises 0.75-10% by weight of copper.

11. A process for removing a heavy metal from a process fluid comprising contacting said fluid with a sorbent of claim 2 .

12. A process for removing a heavy metal from a fluid comprising contacting said fluid with a sorbent composition of claim 3 wherein the fluid further comprises one or more sulphur compounds.

13. The process according to claim 11 wherein the heavy metal is mercury and/or arsenic.

14. The process according to claim 11 wherein the fluid is a hydrocarbon stream.

15. The process according to claim 12 wherein the heavy metal is mercury and/or arsenic.

16. The process according to claim 12 wherein the fluid is a hydrocarbon stream.

17. A sorbent composition comprising a layer on the exterior surface of a support material, the layer consisting of at least one copper compound and a binder material of alumina or hydrated alumina and having a thickness in the range 1-200 μm, wherein the support material is in the form of a shaped particulate unit with a diameter or width in the range 1-10 mm, the sorbent composition comprises 0.5 to 20% by weight of copper, and wherein the sorbent composition is obtained by

(i) forming a slurry of basic copper carbonate and a dispersible alumina binder material and milling the slurry,

(ii) applying the slurry on an exterior surface of the support material by dipping or spraying to form a coated support material, and

(iii) drying the coated support material to form the sorbent composition.

18. The sorbent composition of claim 1 , wherein the support material is in the form of a shaped particulate unit with a diameter or width in the range of 3-10 mm.

19. The sorbent composition of claim 17 , wherein the support material is in the form of a shaped particulate unit with a diameter or width in the range of 3-10 mm.

20. The sorbent composition of claim 17 , wherein the layer has a thickness in a range of 1-150 μm.

21. The sorbent composition of claim 1 , wherein the binder material is alumina.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 26, 2025
From: JOHNSON MATTHEY PLC
To: JOHNSON MATTHEY DAVY TECHNOLOGIES LIMITED
Reel/Frame 072941/0488 →
Priority Claims (1)
GB 0914272.0 · Aug 17, 2009 · national
Continuity (2)
Continuation 13390816
Related Publication 20160001258A1 · Jan 7, 2016