Curable compositions

1. A room temperature curable cobalt-free resin composition comprising:

a) a copper containing complex;

b) a quaternary ammonium or phosphonium salt:

c) an arylalkyl tertiary amine;

d) optionally a transition metal salt; and

e) an uncured thermosetting resin.

2. The room temperature curable cobalt-free resin composition of claim 1 , wherein the copper containing complex is selected from the group consisting of one or more of:

i)

(Cu 2+ )(RCOO − ) 2

wherein R is H, substituted or unsubstituted linear alkyl, substituted or unsubstituted branched alkyl, substituted or unsubstituted linear alkenyl, substituted or unsubstituted branched alkenyl, substituted or unsubstituted linear alkynyl, substituted or unsubstituted branched alkynyl, substituted or unsubstituted aryl, or substituted or unsubstituted alkylaryl;

ii)

wherein m and n are each independently an integer of 0 or greater, and R′ and R″ are each independently H, substituted or unsubstituted linear alkyl, substituted or unsubstituted branched alkyl, substituted or unsubstituted linear alkenyl, substituted or unsubstituted branched alkenyl, substituted or unsubstituted aryl, or substituted or unsubstituted alkylaryl;

iii)

wherein R 1 , R 2 , R 3 and R 4 are each independently H, substituted or unsubstituted linear alkyl, substituted or unsubstituted branched alkyl, substituted or unsubstituted linear alkenyl, substituted or unsubstituted branched alkenyl, substituted or unsubstituted linear alkynyl, substituted or unsubstituted branched alkynyl, substituted or unsubstituted aryl, or substituted or unsubstituted alkylaryl; and

iv)

wherein R 5 and R 6 are each independently: a group containing a heteroatom capable of coordinating to a transition metal; a C 1 -C 22 substituted or unsubstituted alkyl; a C 6 -C 10 aryl, wherein at least one of R 5 and R 6 is a non-aromatic hydrocarbon group, the non-aromatic hydrocarbon group being a C 8 -C 22 alkyl chain, R 7 and R 8 are independently: H; C 1 -C 4 alkyl; phenyl; electron withdrawing groups; and reduced products and derivatives thereof, X is selected from: C═O; a ketal derivative of C═O; a thioketal derivative of C═O; and —[C(R 7 ) 2 ] y —, wherein y is 0 or 1 and R 7 are each independently selected from H, OH, O—C 1 -C 24 alkyl, O-benzyl, O—(C═O)—C 1 -C 24 alkyl and C 1 -C 24 alkyl, and wherein R are each independently C 1 -C 4 alkyl.

3. The room temperature curable cobalt-free resin composition of claim 1 , wherein the copper containing complex comprises:

(Cu 2+ )(RCOO − ) 2

wherein R is H, substituted or unsubstituted linear alkyl, substituted or unsubstituted branched alkyl, substituted or unsubstituted linear alkenyl, substituted or unsubstituted branched alkenyl, substituted or unsubstituted linear alkynyl, substituted or unsubstituted branched alkynyl, substituted or unsubstituted aryl, or substituted or unsubstituted alkylarl.

4. The room temperature curable cobalt-free resin composition of claim 1 , wherein the copper containing complex comprises:

wherein m and n are each independently an integer of 0 or greater, and R′ and R″ are each independently H, substituted or unsubstituted linear alkyl, substituted or unsubstituted branched alkyl, substituted or unsubstituted linear alkenyl, substituted or unsubstituted branched alkenyl, substituted or unsubstituted linear alkynyl, substituted or unsubstituted branched alkynyl, substituted or unsubstituted aryl, or substituted or unsubstituted alkylaryl.

5. The room temperature curable cobalt-free resin composition of claim 1 , wherein the copper containing complex comprises:

wherein R, R 2 , R 3 and are each independently H, substituted or unsubstituted linear alkyl, substituted or unsubstituted branched alkyl, substituted or unsubstituted linear alkenyl, substituted or unsubstituted branched alkenyl, substituted or unsubstituted aryl or substituted or unsubstituted alkylaryl.

6. The room temperature curable cobalt-free resin composition of claim 1 , wherein the copper containing complex comprises:

wherein R 5 and R 6 are each independently: a group containing a heteroatom capable of coordinating to a transition metal; a C 1 -C 22 substituted or unsubstituted alkyl; a C 6 -C 10 aryl, wherein at least one of R 5 and R 6 is a non-aromatic hydrocarbon group, the non-aromatic hydrocarbon group being a C 8 -C 22 alkyl chain, R 7 and R 8 are independently: H; C 1 -C 4 alkyl; phenyl; electron withdrawing groups; and reduced products and derivatives thereof, X is selected from: C═O; a ketal derivative of C═O; a thioketal derivative of C═O; and —[C(R 7 ) 2 ] y —, wherein y is 0 or 1 and R 7 are each independently selected from H, OH, O—C 1 -C 24 alkyl, O-benzyl, O—(C═O)—C 1 -C 24 alkyl and C 1 -C 24 alkyl, and wherein R is C 1 -C 4 alkyl.

7. The room temperature curable cobalt-free resin composition of claim 1 , further comprising a peroxide initiator, wherein the peroxide initiator is selected from the group consisting of cumene hydroperoxide, methyl ethyl ketone peroxide, benzoyl peroxide, 2,4-pentanedione peroxide, 2,5-dimethylhexane-2,5-dihydroperoxide, tert-butyl peroxybenzoate, di-tert-butyl perphthalate, dicumyl peroxide, 2,5-dimethyl-2,5-bix (tert-buty peroxide)hexane, 2,5-dimethyl-2,5-bis (tert-butylperoxy)hexyne, bis (tert-butylperoxyisopropyl) benzene, ditert-butyl peroxide, 1,1-di (tert-amylperoxy)-cyclohexane, 1,1-di-(tert-butylperoxy)-3,3,5-trimethylcyclohexane, 1,1-di-(tert-butylperoxy)-cyclohexane, 2,2-di-(tert-butylperoxy)butane; n-butyl-4,4-di(tert-butyl peroxy)valerate, ethyl-3,3-di-(tert-amylperoxy)butyrate, ethyl-3,3-di(tert-butylperoxy)-bury rate, t-butyl peroxy-neodecanoate, di-(4-5 butyl-cyclohexyl)-peroxydicarbonate, lauryl peroxide, 2,5-dimethyl-2,5-bis(2-ethyl-hexanoyl peroxy) hexane, t-amyl peroxy-2-ethylhexanoate; 2,2′-azobis(2-methylpropionitrile), 2,2′-azobis(2,4-methylbutanenitrile), and mixtures of any thereof.

8. The room temperature curable cobalt-free resin composition of claim 1 , wherein the quaternary ammonium or phosphonium salt is selected from the group consisting of tetramethylammonium chloride, tetramethylammonium hydroxide, tetramethylammonium bromide, tetramethylammonium hydrogensulfate, benzyltrimethylammonium chloride, benzyltrimethylammonium bromide, benzyltrimethylammonium hydrogen sulfate, benzyltributylammonium chloride, benzyltributyl ammonium bromide, tetrabutylphosphonium acetate, tetrabutylphosphonium bromide, tetrabutylphosphonium chloride, tetrabutylphosphonium fluoride, tetrabutylphosphonium iodide, tetraphenylphosphonium chloride, tetraphenylphosphonium bromide, tetraphenylphosphonium acetate.

9. The room temperature curable cobalt-free resin composition of claim 1 , wherein the uncured thermosetting resin is selected from the group consisting of a polyester resin, a vinyl ester resin, a urethane acrylate resin, and a vinyl hybrid resin.

10. The composition of claim 1 , wherein the composition comprises the transition metal salt.